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Chloroiodomethane information


Chloroiodomethane
Stereo, skeletal formula of chloroiodomethane with all explicit hydrogens added
Spacefill model of chloroiodomethane
Names
Preferred IUPAC name
Chloro(iodo)methane
Other names
  • Chloroiodomethane
  • Chloroiodomethane
  • Chloromethyl iodide
Identifiers
CAS Number
  • 593-71-5 checkY
3D model (JSmol)
  • Interactive image
Beilstein Reference
1730802
ChemSpider
  • 11154 checkY
ECHA InfoCard 100.008.915 Edit this at Wikidata
EC Number
  • 209-804-8
PubChem CID
  • 11644
UNII
  • X7AF9WG7CX checkY
CompTox Dashboard (EPA)
  • DTXSID50208034 Edit this at Wikidata
InChI
  • InChI=1S/CH2ClI/c2-1-3/h1H2 checkY
    Key: PJGJQVRXEUVAFT-UHFFFAOYSA-N checkY
SMILES
  • ClCI
Properties
Chemical formula
CH2ClI
Molar mass 176.38 g·mol−1
Appearance Colorless liquid
Density 2.422 g mL−1
Boiling point 108 to 109 °C (226 to 228 °F; 381 to 382 K)
Henry's law
constant (kH)
8.9 μmol Pa−1 kg−1
Refractive index (nD)
1.582
Hazards
GHS labelling:
Pictograms
GHS07: Exclamation mark
Signal word
Warning
Hazard statements
H315, H319, H335
Precautionary statements
P261, P305+P351+P338
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
1
0
Related compounds
Related alkanes
  • Chloromethane
  • Bromochloromethane
  • Dibromochloromethane
Related compounds
2-Chloroethanol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Chloroiodomethane is the halomethane with the formula is CH
2
ClI
. It is a colorless liquid of use in organic synthesis.[1] Together with other iodomethanes, chloroiodomethane is produced by some microorganisms.[2]

  1. ^ Miyano, Sotaro; Friestad, Gregory K. (2008). "Chloroiodomethane". E-EROS Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rc110.pub2. ISBN 978-0471936237.
  2. ^ Fuse, Hiroyuki; Inoue, Hiroyuki; Murakami, Katsuji; Takimura, Osamu; Yamaoka, Yukiho (2003). "Production of free and organic iodine by Roseovarius spp.". FEMS Microbiology Letters. 229 (2): 189–94. doi:10.1016/S0378-1097(03)00839-5. PMID 14680698.

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Chloroiodomethane

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List of compounds with carbon number 1

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Bromoiodomethane

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cyclopropanation by the Simmons-Smith reaction, but diiodomethane and chloroiodomethane are preferred. It also occurs naturally as the result of microbial...

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