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Tetrahydroxydiboron information


Tetrahydroxydiboron
Names
IUPAC name
Hypoboric acid[1]
Other names
(Dihydroxyboranyl)boronic acid
Hypoboric acid
Hypodiboric acid
Sub-boric acid (Unterborsäure in German)
1,1,2,2-Tetrahydroxydiborane
Identifiers
CAS Number
  • 13675-18-8 checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:38289
ChemSpider
  • 9161351
ECHA InfoCard 100.222.662 Edit this at Wikidata
PubChem CID
  • 10986154
UNII
  • D0Q7FO865W checkY
CompTox Dashboard (EPA)
  • DTXSID40450702 Edit this at Wikidata
InChI
  • InChI=1S/B2H4O4/c3-1(4)2(5)6/h3-6H
    Key: SKOWZLGOFVSKLB-UHFFFAOYSA-N
SMILES
  • B(B(O)O)(O)O
Properties
Chemical formula
B2H4O4
Molar mass 89.65 g·mol−1
Appearance White powder
Density 1.657
Melting point 143–148 °C (289–298 °F; 416–421 K)
Solubility in water
very soluble
Solubility ethanol, DMF, DMSO, DMA
Structure
Crystal structure
monoclinic P21/c
Thermochemistry
Std molar
entropy (S298)
125.46 J K−1 mol−1
Std enthalpy of
formation fH298)
−1410.43 kJ mol−1
Hazards
GHS labelling:
Hazard statements
H302, H315, H319, H332, H335
Precautionary statements
P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P403+P233, P405, P501
Related compounds
Related compounds
Diborane
Diboron tetrafluoride
Bis(pinacolato)diboron
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Tetrahydroxydiboron is a chemical reagent which can be used to prepare boronic acids.[2]

  1. ^ "Hypodiboric acid". IUPAC.
  2. ^ Little, Sarah; Trice, Jane (2001). "Tetrahydroxydiboron". Encyclopedia of Reagents for Organic Synthesis. John Wiley & Sons. doi:10.1002/047084289x.rn01181. ISBN 9780470842898.

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Tetrahydroxydiboron

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Tetrahydroxydiboron is a chemical reagent which can be used to prepare boronic acids. The reaction of boron trichloride with alcohols was reported in...

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Miyaura borylation

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shown to work for: Alkyl halides, aryl halides, aryl halides using tetrahydroxydiboron, aryl halides using bis-boronic acid, aryl triflates, aryl mesylates...

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Boronic acid

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alternative to esters in this method is the use of diboronic acid or tetrahydroxydiboron ([B(OH2)]2). Boronic esters are esters formed between a boronic acid...

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Boron monoxide

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Boron monoxide is typically produced through the condensation of tetrahydroxydiboron (chemical formula; B2(OH)4) at temperatures of 200–500°C. The use...

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