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Biuret information


Biuret
Freshly recrystallised biuret
Skeletal formula of biuret
Names
Preferred IUPAC name
2-Imidodicarbonic diamide[1]
Other names
  • Biuret[1]
  • Allophanamide[2]
  • Carbamylurea[2]
  • Allophanic acid amide[2]
  • Allophanimidic acid[2]
  • N-carbamoylaminomethanamide[citation needed]
  • Ureidoformamide[2]
  • Imidodicarbonic diamide[citation needed]
  • Diurea[citation needed]
Identifiers
CAS Number
  • 108-19-0 checkY
3D model (JSmol)
  • Interactive image
3DMet
  • B00969
Beilstein Reference
1703510
ChEBI
  • CHEBI:18138 checkY
ChemSpider
  • 7625 checkY
ECHA InfoCard 100.003.236 Edit this at Wikidata
EC Number
  • 203-559-0
Gmelin Reference
49702
KEGG
  • C06555 checkY
MeSH Biuret
PubChem CID
  • 7913
UNII
  • 89LJ369D1H ☒N
CompTox Dashboard (EPA)
  • DTXSID2026783 Edit this at Wikidata
InChI
  • InChI=1S/C2H5N3O2/c3-1(6)5-2(4)7/h(H5,3,4,5,6,7) checkY
    Key: OHJMTUPIZMNBFR-UHFFFAOYSA-N checkY
SMILES
  • NC(=O)NC(N)=O
Properties
Chemical formula
HN(CONH2)2
Molar mass 103.081 g·mol−1
Appearance White crystals
Odor Odourless
Density 1.467 g/cm3
Melting point 190 °C (decomposes)
Thermochemistry
Heat capacity (C)
131.3 J/(mol·K)
Std molar
entropy (S298)
146.1 J/(mol·K)
Std enthalpy of
formation fH298)
(−565.8) – (−561.6) kJ/mol
Std enthalpy of
combustion cH298)
(−940.1) – (−935.9) kJ/mol
Hazards
GHS labelling:
Pictograms
GHS07: Exclamation mark
Signal word
Warning
Hazard statements
H315, H319, H335
Precautionary statements
P261, P305+P351+P338
Related compounds
Related compounds
  • urea
  • triuret
  • cyanuric acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Biuret (/ˈbjurɛt/ BYUR-ret) is a chemical compound with the chemical formula HN(CONH2)2. It is a white solid that is soluble in hot water. A variety of organic derivatives are known. The term "biuret" also describes a family of organic compounds with the chemical formula R1R2N−C(=O)−N(R3)−C(=O)−NR4R5, where R1, R2, R3, R4 and R5 are hydrogen, organyl or other groups. Also known as carbamylurea, it results from the condensation of two equivalents of urea. It is a common undesirable impurity in urea-based fertilizers, as biuret is toxic to plants.

  1. ^ a b Favre, Henri A.; Powell, Warren H. (2014). Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge: The Royal Society of Chemistry. p. 866. doi:10.1039/9781849733069. ISBN 978-0-85404-182-4.
  2. ^ a b c d e Scifinder, version 2007.1; Chemical Abstracts Service: Columbus, OH; RN 108-19-0 (accessed June 15, 2012)

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streams. Intermediates in the dehydration include both isocyanic acid, biuret, and triuret: H2N-CO-NH2 → HNCO + NH3 H2N-CO-NH2 + HNCO → H2N-CO-NH-CO-NH2...

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protein type. The traditional method for measuring total protein uses the biuret reagent, but other chemical methods such as dye-binding and refractometry...

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reactions of copper ions with the peptide bonds under alkaline conditions (the Biuret test) with the oxidation of aromatic protein residues. The Lowry method...

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160 °C: CO(NH2)2 → [NH4]+[OCN]− → NH3 + HNCO Heating above 160 °C yields biuret NH2CONHCONH2 and triuret NH2CONHCONHCONH2 via reaction with isocyanic acid:...

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detect the presence of cuprous ions, due to its purple coloration via a biuret reaction. In this assay, two molecules of bicinchoninic acid chelate a single...

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+ R'NCO → R2NC(O)N(H)R' The addition of an isocyanate to a urea gives a biuret: R2NC(O)N(H)R' + R''NCO → R2NC(O)NR'C(O)NHR'' Reaction between a di-isocyanate...

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quantitation compared to previous methods: the Lowry procedure and the biuret assay. Unlike the previous methods, the Bradford assay is not susceptible...

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Hofmeister made the proposal in the morning, based on his observations of the biuret reaction in proteins. Hofmeister was followed a few hours later by Emil...

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Alternative protein assays include: Ultraviolet–visible spectroscopy RGBradford Biuret protein assay Lowry protein assay BCA protein assay Amido black protein...

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H2NC(O)NHCO2H. It is a carbamic acid, the carboxylated derivative of urea. Biuret can be viewed as the amide of allophanic acid. The compound can be prepared...

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Emil Fischer

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responses to tests for proteins used by physiological chemists - a positive Biuret test, precipitation by inorganic salts and cleavage by proteolytic enzymes...

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Retrieved 19 December 2017.[permanent dead link] Mikkelsen, R.L. (2007). "Biuret in Urea Fertilizers" (PDF). Better Crops. 91 (3): 6–7. Archived from the...

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Cyanuric acid amidohydrolase

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\rightleftharpoons } biuret + CO2 Thus, the two substrates of this enzyme are cyanuric acid and H2O, whereas its two products are biuret and CO2. This enzyme...

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the condensation reaction among 2 moles of dicyandiamide and 1 mole of biuret. 2 C2H4N4 + C2H5N3O2 → 2C3H5N5O + NH3 Ammeline is weakly acidic with pKa...

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reduction Bischler–Möhlau indole synthesis Bischler–Napieralski reaction Biuret test Blaise ketone synthesis Blaise reaction Blanc reaction Blanc chloromethylation...

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