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Triazane information


Triazane
Names
Systematic IUPAC name
Triazane[1]
Identifiers
CAS Number
  • 14451-01-5
3D model (JSmol)
  • Interactive image
ChemSpider
  • 394177 checkY
PubChem CID
  • 446953
CompTox Dashboard (EPA)
  • DTXSID60332238 Edit this at Wikidata
InChI
  • InChI=1S/H5N3/c1-3-2/h3H,1-2H2
    Key: PYHOFAHZHOBVGV-UHFFFAOYSA-N
SMILES
  • NNN
Properties
Chemical formula
N3H5
Molar mass 47.061 g·mol−1
Related compounds
Related compounds
  • Ammonia
  • Hydrazine
  • Diazene
  • Triazene
  • Tetrazene
  • Pentazole
  • Hexazine
  • Phosphine
  • Diphosphane
  • Triphosphane
  • Diphosphene
  • Hexaphosphabenzene
  • Arsine
  • Diarsane
  • Triarsane
  • Stibine
  • Bismuthine
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Triazane is an inorganic compound with the chemical formula NH2NHNH2 or N3H5.[2] Triazane is the third simplest acyclic azane after ammonia and hydrazine. It can be synthesized from hydrazine but is unstable and cannot be isolated in the free base form, only as salt forms such as triazanium sulfate. Attempts to convert triazanium salts to the free base release only diazene and ammonia.[3] Triazane was first synthesized as a ligand of the silver complex ion: tris(μ2-triazane-κ2N1,N3)disilver(2+).[clarification needed] Triazane has also been synthesized in electron-irradiated ammonia ices and detected as a stable gas-phase product after sublimation.[4]

  1. ^ "triazane - PubChem Public Chemical Database". The PubChem Project. USA: National Center for Biotechnology Information.
  2. ^ IUPAC Goldbook
  3. ^ Wiberg, Holleman & Wiberg. Inorganic Chemistry. p 627. ISBN 9780123526519
  4. ^ Förstel, Maksyutenko, Jones, Sun, Chen, Chang, & Kaiser. "Detection of the Elusive Triazane Molecule ([N
    3
    H
    5
    ]
    ) in the Gas Phase", ChemPhysChem, 2015, 16, 3139.

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Triazane

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stable at room temperature. Some examples of which are solid nitrogen, triazane, azide anion and triazoles. Even longer series with eight nitrogen atoms...

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tetraiodide Other cations Organic hydrazines Related Binary azanes Ammonia Triazane Related compounds Diazene Triazene Tetrazene Diphosphene Except where otherwise...

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hydrogen diazane (or hydrazine), N 2H 4 - two nitrogen and four hydrogen triazane, N 3H 5 - three nitrogen and five hydrogen Azanes with three or more nitrogen...

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Tetrazene

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060 g·mol−1 Related compounds Related binary azanes Ammonia Hydrazine Triazane Related compounds Diazene Triazene Except where otherwise noted, data are...

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Related Binary azenes triazene tetrazene Related compounds ammonia diazane triazane Except where otherwise noted, data are given for materials in their standard...

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Diimide

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difluoride Other cations azo compounds Related Binary azanes ammonia diazane triazane Related compounds isodiazene triazene tetrazene Except where otherwise...

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