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Benzyl fluoride information


Benzyl fluoride
Names
Preferred IUPAC name
(Fluoromethyl)benzene
Other names
α-Fluorotoluene, BnF
Identifiers
CAS Number
  • 350-50-5 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 9215 checkY
ECHA InfoCard 100.005.913 Edit this at Wikidata
PubChem CID
  • 9591
UNII
  • T7KNE39EHS checkY
CompTox Dashboard (EPA)
  • DTXSID8059847 Edit this at Wikidata
InChI
  • InChI=1S/C7H7F/c8-6-7-4-2-1-3-5-7/h1-5H,6H2 checkY
    Key: MBXXQYJBFRRFCK-UHFFFAOYSA-N checkY
  • InChI=1/C7H7F/c8-6-7-4-2-1-3-5-7/h1-5H,6H2
    Key: MBXXQYJBFRRFCK-UHFFFAOYAU
SMILES
  • FCc1ccccc1
Properties
Chemical formula
C7H7F
Molar mass 110.129 g/mol
Appearance Colorless liquid
Density 1.0228 g/cm3[1]
Melting point −35 °C (−31 °F; 238 K)[1]
Boiling point 140 °C (284 °F; 413 K)[1]
Hazards
Safety data sheet (SDS) "External MSDS"
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Benzyl fluoride is an organic compound consisting of a benzene ring substituted with a fluoromethyl group.

  1. ^ a b c CRC Handbook of Chemistry and Physics, 90. Edition, CRC Press, Boca Raton, Florida, 2009, ISBN 978-1-4200-9084-0, Section 3, Physical Constants of Organic Compounds, p. 3-260.

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Benzyl fluoride

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Benzyl fluoride is an organic compound consisting of a benzene ring substituted with a fluoromethyl group. Benzyl chloride Benzyl bromide Benzyl iodide...

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Benzyl bromide

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Benzyl chloride Benzyl fluoride Benzyl iodide Xylyl bromide Merck Index (11th ed.). p. 1142. "Benzyl bromide_msds". William E. Bauta (2001). "Benzyl Bromide"...

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Benzyl chloride

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which produce, store, or use it in significant quantities. Benzyl bromide Benzyl fluoride Benzyl iodide List of highly toxic gases NIOSH Pocket Guide to...

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Benzyl iodide

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refractive index of 1.6334. Benzyl iodide is also a powerful lachrymator. Benzyl bromide Benzyl chloride Benzyl fluoride "BENZYL IODIDE". chemicalbook.com...

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Topical fluoride

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Topical fluorides are fluoride-containing drugs indicated in prevention and treatment of dental caries, particularly in children's primary dentitions....

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EPA list of extremely hazardous substances

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Benzimidazole, 4,5-dichloro-2-(trifluoromethyl)- Benzotrichloride Benzyl chloride Benzyl cyanide Bicyclo(2.2.1)heptane-2-carbonitrile Bis(chloromethyl) ketone...

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Protecting group

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a benzyl ester on the carboxyl group, a fluorenylmethylenoxy carbamate on the amine group, and a tert-butyl ether on the phenol group. The benzyl ester...

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Finkelstein reaction

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acid to the iodide: EtO2C(CH2)4Br + NaI → EtO2C(CH2)4I + NaBr Potassium fluoride is used for the conversion of chlorocarbons into fluorocarbons. Such reactions...

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Sulfonyl halide

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decreases in the order fluorides > chlorides > bromides > iodides, all four types being well known. The sulfonyl chlorides and fluorides are of dominant importance...

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Elimination reaction

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halogens, iodide and bromide being favored. Fluoride is not a good leaving group, so eliminations with fluoride as the leaving group have slower rates than...

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IARC group 2A

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Chloramphenicol α-Chlorinated toluenes (benzal chloride, benzotrichloride, benzyl chloride) and benzoyl chloride (combined exposures) CCNU...

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Ester

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reacts with sodium benzyloxide (generated from sodium and benzyl alcohol) to generate benzyl benzoate. The method is used in the production of ethyl acetate...

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Peptide synthesis

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Permanent side-chain protecting groups used during Boc/benzyl SPPS are typically benzyl or benzyl-based groups. Final removal of the peptide from the solid...

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Benzyltrimethylammonium fluoride

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Benzyltrimethylammonium fluoride is a quaternary ammonium salt. It is commercially available as the hydrate. The compound is a source of organic-soluble fluoride to removal...

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Sodium cyanide

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including pharmaceuticals. Illustrative is the synthesis of benzyl cyanide by the reaction of benzyl chloride and sodium cyanide. Being highly toxic, sodium...

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Vinyl group

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example Example of resulting polymer Vinyl chloride Polyvinyl chloride (PVC) Vinyl fluoride Polyvinyl fluoride (PVF) Vinyl acetate Polyvinyl acetate (PVAc)...

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Polyvinyl chloride

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between allergies in children and indoor air levels of DEHP and BBzP (butyl benzyl phthalate), which is used in vinyl flooring. In December 2006, the European...

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Ojima lactam

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synthesis starts from glycolic acid. The hydroxyl group is protected by a benzyl group and the carboxylic acid is activated by reaction with thionyl chloride...

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Electrosynthesis

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nitrile to a primary amine in a divided cell; the cathodic reduction of benzyl cyanide to phenethylamine is shown: Cathodic reduction of a nitroalkene...

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Nicolaou Taxol total synthesis

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giving triol 5.5. This alcohol was monoacetylated, to give acetate 5.6. The benzyl group was removed and replaced with a triethylsilyl group. Diol 5.7 was...

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Quaternary ammonium cation

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synthesis is for benzalkonium chloride from a long-chain alkyldimethylamine and benzyl chloride: CH 3 ( CH 2 ) n N ( CH 3 ) 2 + ClCH 2 C 6 H 5 ⟶ [ CH 3 ( CH 2...

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IARC group 3

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Benzo[ghi]perylene Benzo[e]pyrene p-Benzoquinone dioxime Benzoyl peroxide Benzyl acetate Bis(1-aziridinyl)morpholinophosphine sulfide Bis(2-chloroethyl)ether...

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Mukaiyama aldol addition

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(1): 121–161. doi:10.1002/(SICI)1521-3765(19990104)5:1<121::AID-CHEM121>3.0.CO;2-O. TBS = t-butyldimethylsilyl, Bn = benzyl, PMB = p-methoxybenzyl ether...

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Sulfolene

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reusable. As a model reaction, the reaction of benzyl azide with 4-toluenesulfonic acid cyanide forming 1-benzyl-5-(4-toluenesulfonyl)tetrazole was investigated...

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Stille reaction

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{Blue}{\ce {R^1}}}\!,\ {\color {Red}{\ce {R^2}}}}: Allyl, alkenyl, aryl, benzyl, acyl X{\displaystyle {\color {Red}{\ce {X}}}}: halides (Cl, Br, I), pseudohalides...

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List of UN numbers 1701 to 1800

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Benzoyl chloride UN 1737 6.1 Benzyl bromide UN 1738 6.1 Benzyl chloride or Benzyl chloride unstabilized UN 1739 8 Benzyl chloroformate UN 1740 8 Hydrogen...

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Photolabile protecting group

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rate-determining step. Barltrop and Schofield first demonstrated the use of a benzyl-based PPG, structural variations have focused on substitution to the benzene...

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Danishefsky Taxol total synthesis

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anchoring points for fusion with the A ring. Alcohol 12 was protected by a benzyl group. The acetonide protecting group was removed from the ketone. Ketone...

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Xylitol

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effect in reducing tooth decay of xylitol-containing fluoride toothpastes when compared to fluoride-only toothpaste, but there was insufficient evidence...

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Methyl group

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is the photochemical chlorination of the methyl group in toluene to give benzyl chloride. In the special case where one hydrogen is replaced by deuterium...

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