Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Aluminium borohydride, also known as aluminium tetrahydroborate, is the chemical compound with the formula Al(BH4)3. It is a volatile pyrophoric liquid which is used as a reducing agent in laboratories. Unlike most other metal–borohydrides, which are ionic structures, aluminium borohydride is a covalent compound.[2][3]
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Lide, David R. (1998). Handbook of Chemistry and Physics (87 ed.). Boca Raton, Florida: CRC Press. pp. 4–39. ISBN 0-8493-0594-2.
^Cite error: The named reference kollonitsch was invoked but never defined (see the help page).
^Miwa, K.; Ohba, N.; Towata, S.; Nakamori, Y.; Züttel, A.; Orimo, S. (2007). "First-principles study on thermodynamical stability of metal borohydrides: Aluminum borohydride Al(BH4)3". J. Alloys Compd. 446–447: 310–314. arXiv:cond-mat/0610853. doi:10.1016/j.jallcom.2006.11.140. S2CID 97032806.
and 27 Related for: Aluminium borohydride information
Unlike most other metal–borohydrides, which are ionic structures, aluminiumborohydride is a covalent compound. Aluminiumborohydride is formed by the reaction...
in ethers, whilst remaining safer to handle than lithium aluminium hydride. Lithium borohydride may be prepared by the metathesis reaction, which occurs...
Sodium borohydride, also known as sodium tetrahydridoborate and sodium tetrahydroborate, is an inorganic compound with the formula NaBH4 (sometimes written...
Lithium aluminium hydride (LAH) is widely used in organic chemistry as a reducing agent. It is more powerful than the related reagent sodium borohydride owing...
compound was first prepared by treating uranium tetrafluoride with aluminiumborohydride: UF4 + 2 Al(BH4)3 → U(BH4)4 + 2 Al(BH4)F2 It may also be prepared...
Prominent among these reagents are the alkali metal salts of borohydrides and aluminium hydrides. In terms of reaction mechanism, metal hydrides effect...
from boron trichloride with lithium aluminium hydride or from boron trifluoride ether solution with sodium borohydride. Both methods result in as much as...
effected using stoichiometric hydride reagents such as sodium borohydride or lithium aluminium hydride. Oxidizing agent Reducing agent Transfer hydrogenation...
sodium borohydride due to the weaker and more polar Al-H bond compared to the B-H bond. Like LAH, it reduces esters to alcohols. Sodium aluminium hydride...
the non-catalytic conversion to amines include lithium aluminium hydride, lithium borohydride, diborane, or elemental sodium in alcohol solvents. Nitriles...
solutions. LiBHEt3 is a stronger reducing agent than lithium borohydride and lithium aluminium hydride. LiBHEt3 is prepared by the reaction of lithium hydride...
Compounds susceptible to hydrolysis often undergo protonolysis. The borohydride anion is susceptible to reaction with even weak acids, resulting protonolysis...
hydrogen-atom donors and act as acids. Hydrides such as sodium borohydride, lithium aluminium hydride, diisobutylaluminium hydride (DIBAL) and super hydride...
especially boron and aluminium including sodium aluminium hydride, NaAlH4 ), lithium aluminium hydride, LiAlH4, and lithium borohydride, (LiBH4). Complex...
Note: There are elements for which spellings may differ, such as aluminum/aluminium, sulfur/sulphur, and caesium/cesium. Contents A B C Ca–Cu D E F G H I...
Iron metal Lithium aluminium hydride (Note: Hydroxylamines and oximes are typical impurities.) Lithium borohydride or sodium borohydride and trimethylsilyl...
include the greater relative chemoselectivity of sodium borohydride versus lithium aluminium hydride for the organic reduction of 4-nitro-2-chlorobenzonitrile...
accomplish this task include lithium aluminium hydride, sodium borohydride, alkoxy borohydrides, alkoxy aluminium hydrides, and boranes. Although stoichiometric...
the use of reducing sugars, citrate reduction, reduction via sodium borohydride, the silver mirror reaction, the polyol process, seed-mediated growth...
carboxylic acid 25, Diazomethane treatment gave methyl ester 26 and sodium borohydride the allyl alcohol 27. Chiral resolution of this racemic compound with...
chemical syntheses, lithium aluminium hydride is used to reduce esters to two primary alcohols. The related reagent sodium borohydride is slow in this reaction...
For example, Na[BH3(CN)] is less reducing than its counterpart sodium borohydride, containing [BH4]−. Sodium cyanoborohydride is a mild reducing agent...
phenethyl alcohol by the reduction of phenylacetic acid using sodium borohydride and iodine in THF. Phenethyl alcohol is found in extract of rose, carnation...
amalgam (Zn(Hg)) (reagent for Clemmensen reduction) Diborane Sodium borohydride (Na BH4) Ferrous compounds that contain the Fe2+ ion, such as iron(II)...
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