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Zinc carbonate information


Zinc carbonate
Identifiers
CAS Number
  • 3486-35-9
  • basic: 5263-02-5
3D model (JSmol)
  • Interactive image
ChemSpider
  • 17943
  • monohydrate: 11570234
  • basic: 10129674
ECHA InfoCard 100.020.435 Edit this at Wikidata
EC Number
  • 222-477-6
  • basic: 226-076-7
PubChem CID
  • 19005
  • basic: 11955398
UNII
  • K8290PTQ4F
UN number 9157
CompTox Dashboard (EPA)
  • DTXSID5049817 Edit this at Wikidata
InChI
  • InChI=1S/CH2O3.Zn/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2
    Key: FMRLDPWIRHBCCC-UHFFFAOYSA-L
SMILES
  • C(=O)([O-])[O-].[Zn+2]
Properties
Chemical formula
ZnCO3
Molar mass 125.4
Appearance white solid
Density 4.434 g/cm3[1]
Melting point 140 °C (284 °F; 413 K)[1] (decomposes)
Solubility in water
0.91 mg/L[1]
Solubility product (Ksp)
1.46×10−10[2]
Magnetic susceptibility (χ)
-34×10−6 cm3/mol[3]
Refractive index (nD)
n1=1.621, n2=1.848[4]
Structure[5]
Crystal structure
Calcite, hR30, No. 167
Space group
R3c
Lattice constant
a = 4.6528 Å, c = 15.025 Å
Formula units (Z)
6
Hazards
GHS labelling:
Pictograms
GHS09: Environmental hazard
Signal word
Warning
Hazard statements
H319, H410, H411
Precautionary statements
P264, P273, P280, P302+P352, P305+P351+P338, P321, P332+P313, P337+P313, P362, P391, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Zinc carbonate is the inorganic compound with the formula ZnCO3. It is a white solid that is insoluble in water. It exists in nature as the mineral smithsonite. It is prepared by treating cold solutions of zinc sulfate with potassium bicarbonate. Upon warming, it converts to basic zinc carbonate (Zn5(CO3)2(OH)6).[6]

Zinc carbonate adopts the same structure as calcium carbonate (calcite).[7] Zinc is octahedral and each carbonate is bonded to six Zn centers such that oxygen atoms are three-coordinate.

  1. ^ a b c Haynes, p. 4.95
  2. ^ Haynes, p. 5.178
  3. ^ Haynes, p. 4.131
  4. ^ Haynes, p. 4.137
  5. ^ Haynes, p. 4.144
  6. ^ Wagenknecht, F.; Juza, R. (1963). "Zinc carbonate". In G. Brauer (ed.). Handbook of Preparative Inorganic Chemistry, 2nd Ed. Vol. 2. NY, NY: Academic Press. p. 1086.
  7. ^ Effenberger, H.; Mereiter, K.; Zemann, J. (1981). "Crystal structure refinements of magnesite, calcite, rhodochrosite, siderite, smithonite, and dolomite, with discussion of some aspects of the stereochemistry of calcite type carbonates". Zeitschrift für Kristallographie - Crystalline Materials. 156 (3–4): 233–243. Bibcode:1981ZK....156..233E. doi:10.1524/zkri.1981.156.3-4.233.

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