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Vanadium oxytrichloride information


Vanadium oxytrichloride
Ball and stick model of vanadium oxytrichloride
Vanadium oxytrichloride in an ampoule
Names
IUPAC name
Vanadium trichloride oxide
Other names
  • Vanadyl chloride
  • Vanadyl trichloride
Identifiers
CAS Number
  • 7727-18-6 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 10613097 checkY
ECHA InfoCard 100.028.892 Edit this at Wikidata
EC Number
  • 231-780-2
MeSH trichlorooxo+vanadium
PubChem CID
  • 24410
RTECS number
  • YW2975000
UNII
  • 839N4FR2H0 checkY
UN number 2443
CompTox Dashboard (EPA)
  • DTXSID7064784 Edit this at Wikidata
InChI
  • InChI=1S/3ClH.O.V/h3*1H;;/q;;;;+3/p-3 ☒N
    Key: JBIQAPKSNFTACH-UHFFFAOYSA-K ☒N
SMILES
  • Cl[V](Cl)(Cl)=O
Properties
Chemical formula
VOCl
3
Molar mass 173.300 g mol−1
Appearance yellow liquid
Density 1.826 g mL−1
Melting point −76.5 °C (−105.7 °F; 196.7 K)
Boiling point 126.7 °C (260.1 °F; 399.8 K)
Solubility in water
Decomposes
Vapor pressure 1.84 kPa (at 20 °C)
Structure
Molecular shape
Tetrahedral
Hazards
GHS labelling:
Pictograms
GHS05: CorrosiveGHS06: ToxicGHS09: Environmental hazard
Signal word
Danger
Hazard statements
H301, H314
Precautionary statements
P280, P301+P310, P305+P351+P338, P310
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 3: Capable of detonation or explosive decomposition but requires a strong initiating source, must be heated under confinement before initiation, reacts explosively with water, or will detonate if severely shocked. E.g. hydrogen peroxideSpecial hazards (white): no code
3
1
3
Lethal dose or concentration (LD, LC):
LD50 (median dose)
140 mg kg−1 (oral, rat)
Related compounds
Related vanadiums
  • Vanadium(V) oxytrifluoride
  • Vanadium(V) oxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Vanadium oxytrichloride is the inorganic compound with the formula VOCl3. This yellow distillable liquid hydrolyzes readily in air. It is an oxidizing agent. It is used as a reagent in organic synthesis.[1] Samples often appear red or orange owing to an impurity of vanadium tetrachloride.[2]

  1. ^ O'Brien, Michael K.; Vanasse, Benoit (2001). "Vanadyl Trichloride". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rv004. ISBN 0-471-93623-5.
  2. ^ F. E. Brown; F. A. Griffitts (1939). "Hypovanadous Oxide and Vanadium Oxytrichloride". Inorganic Syntheses. Vol. I. pp. 106–108. doi:10.1002/9780470132326.ch38. ISBN 978-0-470-13232-6. {{cite book}}: |journal= ignored (help)

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Vanadium oxytrichloride

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Vanadium oxytrichloride is the inorganic compound with the formula VOCl3. This yellow distillable liquid hydrolyzes readily in air. It is an oxidizing...

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Vanadium

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D.; Svec, Harry J. (1 August 1975). "Thermochemistry of vanadium oxytrichloride and vanadium oxytrifluoride by mass spectrometry". Inorganic Chemistry...

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Group 5 element

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VXnL6−n (X= halide; L= other ligand). Many vanadium oxyhalides (formula VOmXn) are known. The oxytrichloride and oxytrifluoride (VOCl3 and VOF3) are the...

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List of inorganic compounds

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oxide – V2O5 Vanadium carbide – VC Vanadium oxytrichloride (Vanadium(V) oxide trichloride) – VOCl3 Vanadium pentafluoride – VF5 Vanadium tetrachloride...

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Phosphine oxide

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has been claimed as the product of a reaction of phosphine with vanadium oxytrichloride as well as with chromyl chloride. The product was obtained by matrix...

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Vanadium compounds

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VXnL6−n (X= halide; L= other ligand). Many vanadium oxyhalides (formula VOmXn) are known. The oxytrichloride and oxytrifluoride (VOCl3 and VOF3) are the...

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Organovanadium chemistry

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is the chemistry of organometallic compounds containing a carbon (C) to vanadium (V) chemical bond. Organovanadium compounds find only minor use as reagents...

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Chloride process

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chlorides as well, but most are less volatile than TiCl4. Vanadium tetrachloride and vanadium oxytrichloride codistill with TiCl4, but these impurities can be...

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Sodium decavanadate

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varying chemical shifts around −425, −506, and −523 ppm relative to vanadium oxytrichloride; suggesting that rapid proton exchange occurs resulting in equally...

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List of UN numbers 2401 to 2500

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pyrophoric UN 2442 8 Trichloroacetyl chloride UN 2443 8 Vanadium oxytrichloride UN 2444 8 Vanadium tetrachloride UN 2445 4.2 (UN No. no longer in use) Lithium...

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List of CAS numbers by chemical compound

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vanadium(II) oxide 12035–98–2 VOCl3 vanadium(V) oxytrichloride 7727–18–6 VOF3 vanadium(V) oxytrifluoride 13709–31–4 VO2 vanadium(IV) oxide 12036–21–4 VOSO4 vanadyl...

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Glossary of chemical formulae

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vanadium(II) bromide VBr3 vanadium(III) bromide 13470-26-3 VCl2 vanadium(II) chloride 10580-52-6 VCl3 vanadium(III) chloride 7718-98-1 VI3 vanadium(III)...

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