Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Tungsten hexachloride is an inorganic chemical compound of tungsten and chlorine with the chemical formula WCl6. This dark violet blue compound exists as volatile crystals under standard conditions. It is an important starting reagent in the preparation of tungsten compounds.[1] Other examples of charge-neutral hexachlorides are rhenium(VI) chloride and molybdenum(VI) chloride. The highly volatile tungsten hexafluoride is also known.
As a d0 atom, tungsten hexachloride is diamagnetic.
^J. W. Herndon; M. E. Jung (2007). "Tungsten(VI) Chloride". Encyclopedia of Reagents for Organic Synthesis. Wiley. doi:10.1002/9780470842898.rt430.pub2. ISBN 978-0-471-93623-7..
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Tungstenhexachloride is an inorganic chemical compound of tungsten and chlorine with the chemical formula WCl6. This dark violet blue compound exists...
chemical attack, although it reacts strongly with chlorine to form tungstenhexachloride (WCl6). In aqueous solution, tungstate gives the heteropoly acids...
deposition methods that have been investigated include: reacting tungstenhexachloride with hydrogen (as a reducing agent) and methane (as the source of...
be produced by the metathesis reaction of boron tribromide and tungstenhexachloride. WBr6 is reduced with elemental antimony at elevated temperatrues...
Uranium hexachloride (UCl6) is an inorganic chemical compound of uranium in the +6 oxidation state. UCl6 is a metal halide composed of uranium and chlorine...
such as uranium tetrachloride, anhydrous niobium pentachloride and tungstenhexachloride. Hexachlorpropen Gangolli, S.; Royal Society of Chemistry (1999)...
novel catalyst system for the metathesis of 2-pentene based on tungstenhexachloride, ethanol, and the organoaluminum compound EtAlMe2. The researchers...
can also be formed by the reaction of arsenic or arsine and tungstenhexachloride. Tungsten diarsenide is a black solid. It forms crystals in the monoclinic...
proceed with loss or retention of configuration. The combination of tungstenhexachloride and n-butyllithium gives the alkene. Reduction of an epoxide with...
synthesis of linear PDCPD have been run successfully using tungstenhexachloride, tungsten(VI) oxytetrachloride, and organosilicon compounds. The reacting...
the preparation of derivatives of molybdenum and tungsten oxyhalides, converting a tungstenhexachloride suspension in dichloroethane solution quantitatively...
intermediates. For example, WOCl4 results from the partial hydrolysis of tungstenhexachloride. Hydroxide-containing intermediates are rarely observed for oxophilic...
described its preparation by the reaction of methyllithium with tungstenhexachloride in diethyl ether. The synthesis was motivated in part by previous...
experiments have confirmed that seaborgium behaves as the heavier homologue to tungsten in group 6. The chemical properties of seaborgium are characterized only...
deoxygenated using the oxophilic reagent produced by combining tungstenhexachloride and n-butyllithium generates the alkene. This reaction can proceed...
The latter cation is formed by the reaction of tellurium with tungstenhexachloride: 8 Te + 2 WCl 6 → Te2+ 8(WCl− 6) 2 Interchalcogen cations also exist...
is a Diels–Alder reaction. The reagents for de-epoxidation are tungstenhexachloride and butyllithium. The second elimination reaction takes place with...
bound to highly electrophilic metal halides. Thus treatment of tungstenhexachloride with one equivalent of thf gives 1,4-dichlorobutane: WCl6 + OC4H8...
WO2Cl2 is prepared by ligand redistribution reaction from tungsten trioxide and tungstenhexachloride: 2 WO3 + WCl6 → 3 WO2Cl2 Using a two-zone tube furnace...
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