Abbreviated structure of titanium(IV) ethoxide tetramer. The ethoxide ligands are represented by O's. The terminal ethoxide ligands are designated by Oa, the doubly bridging ligands by Ob, and the triply bridging ligands by Oc.
Names
IUPAC name
ethanolate; titanium(4+)
Preferred IUPAC name
Titanium(IV) ethoxide
Systematic IUPAC name
titanium(4+) tetraethanolate
Other names
Ethyl titanate, tetraethyl titanate
Identifiers
CAS Number
3087-36-3Y
3D model (JSmol)
Interactive image
ChemSpider
68993
ECHA InfoCard
100.019.464
EC Number
221-410-8
PubChem CID
76524
UNII
98L0R4158BY
CompTox Dashboard (EPA)
DTXSID3044417
InChI
InChI=1S/4C2H5O.Ti/c4*1-2-3;/h4*2H2,1H3;/q4*-1;+4
Key: JMXKSZRRTHPKDL-UHFFFAOYSA-N
SMILES
CC[O-].CC[O-].CC[O-].CC[O-].[Ti+4]
Properties
Chemical formula
C32H80O16Ti4
Molar mass
228.109 g/mol
Appearance
colorless liquid
Density
1.088
Melting point
54 °C (129 °F; 327 K)[original research?]
Boiling point
150–152 °C (302–306 °F; 423–425 K) (@10 mmHg)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
Titanium ethoxide is a chemical compound with the formula Ti4(OCH2CH3)16. It is a commercially available colorless liquid that is soluble in organic solvents but hydrolyzes readily. Its structure is more complex than suggested by its empirical formula. Like other alkoxides of titanium(IV) and zirconium(IV), it finds used in organic synthesis and materials science.[1]
^Ram C. Mehrotra; Singh, Anirudh (1997). "Recent Trends in Metal Alkoxide Chemistry". In Kenneth D. Karlin (ed.). Progress in Inorganic Chemistry. Vol. 46. John Wiley & Sons. pp. 239–454. doi:10.1002/9780470166475.ch4. ISBN 978-0-470-16704-5.
Titaniumethoxide is a chemical compound with the formula Ti4(OCH2CH3)16. It is a commercially available colorless liquid that is soluble in organic solvents...
chemistries. Sol-gel routes involve the hydrolysis of titanium alkoxides, such as titaniumethoxide: Ti(OEt)4 + 2 H2O → TiO2 + 4 EtOH This technology is...
cluster (see titaniumethoxide). Nonetheless it is often depicted as a simple monomer.[citation needed] It is produced by treating titanium tetrachloride...
Titanium isopropoxide, also commonly referred to as titanium tetraisopropoxide or TTIP, is a chemical compound with the formula Ti{OCH(CH3)2}4. This alkoxide...
stabilizers are widely used in polymers. Titanium isopropoxide is a monomer, the corresponding titaniumethoxide is a tetramer. An isolable selenenic acid...
as Tris(2,2,2-trifluoroethyl)borate [B(OCH2CF3)3], pyrrolidine or titaniumethoxide [Ti(OEt)4] have been shown to catalyse imine formation. Rarer than...
(Si(OCH2CH3)4) could be classified as an ester of orthosilicic acid, and titaniumethoxide (Ti(OCH2CH3)4) could be classified as an ester of orthotitanic acid)...
by selectively evaporating the more volatile component. In this way, ethoxides can be converted to butoxides, since ethanol (b.p. 78 °C) is more volatile...
This might be done through controlled hydrolysis of titanium tetrachloride (TiCl4) or titaniumethoxide. Often dopants are included in such synthesis processes...
oxide layers can be produced by the thermal decomposition of niobium(V) ethoxide with the loss of diethyl ether according to the equation: 2 Nb(OC2H5)5...
transition metal. Pure niobium has a Mohs hardness rating similar to pure titanium, and it has similar ductility to iron. Niobium oxidizes in Earth's atmosphere...
00. Ethanol can be quantitatively converted to its conjugate base, the ethoxide ion (CH3CH2O−), by reaction with an alkali metal such as sodium: 2 CH3CH2OH...
C. (1973). "Organic Derivatives of Tin. III. Reactions of Trialkyltin Ethoxide with Alkanolamines". Zeitschrift für Anorganische und Allgemeine Chemie...
motif throughout its solid structure. The metalorganic compound thallium ethoxide (TlOEt, TlOC2H5) is a heavy liquid (ρ 3.49 g·cm−3, m.p. −3 °C), often used...
catalysis uses nickel as a catalyst. In addition it uses diethylaluminum ethoxide, phenylacetylene and triethylaluminium It converts ethylene into 1-butene...
to lithium aluminium titanium phosphate (LATP), which is another phosphate-based lithium solid conductor, the absence of titanium in LAGP improves its...
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