The Thorpe reaction is a chemical reaction described as a self-condensation of aliphatic nitriles catalyzed by base to form enamines.[1][2][3] The reaction was discovered by Jocelyn Field Thorpe.
The Thorpe reaction
^Baron, Harold; Remfry, Frederick George Percy; Thorpe, Jocelyn Field (1904). "CLXXV.—The formation and reactions of imino-compounds. Part I. Condensation of ethyl cyanoacetate with its sodium derivative". Journal of the Chemical Society, Transactions. 85: 1726–1761. doi:10.1039/CT9048501726. ISSN 0368-1645.
^Ziegler, K.; Eberle, H.; Ohlinger, H. (1933). "Über vielgliedrige Ringsysteme. I. Die präparativ ergiebige Synthese der Polymethylenketone mit mehr als 6 Ringgliedern". Justus Liebig's Annalen der Chemie (in German). 504 (1): 94–130. doi:10.1002/jlac.19335040109. ISSN 0075-4617.
^Schaefer, John P.; Bloomfield, Jordan J. (2011). "The Dieckmann Condensation (Including the Thorpe-Ziegler Condensation)". Organic Reactions. pp. 1–203. doi:10.1002/0471264180.or015.01. ISBN 978-0471264187.
The Thorpereaction is a chemical reaction described as a self-condensation of aliphatic nitriles catalyzed by base to form enamines. The reaction was...
text goes beyond simply recording the events, and includes many of Thorpe'sreactions to the proceedings and dialogues with Arundel. Although it suggests...
Blaise reaction alcohols in the Pinner reaction. the (same) nitrile α-carbon in the Thorpereaction. The intramolecular version is called the Thorpe–Ziegler...
decarboxylates to a dimer. Nitriles self-react in presence of base in the Thorpereaction in a nucleophilic addition In organometallic chemistry nitriles are...
three named reactions. Thorpe was born in Clapham, London on 1 December 1872, one of nine children and the sixth son, of Mr. and Mrs. W.G. Thorpe of the Middle...
reduced by placing isopropyl groups on the silicon atom via the Thorpe–Ingold effect. No reaction takes place when these bulky groups are replaced by smaller...
Lorraine Thorpe (born 1994) is a British woman who is Britain's youngest female double murderer. Over the space of nine days in August 2009, Thorpe tortured...
"ω-Methoxyacetophenone". Organic Syntheses. 21: 79. doi:10.15227/orgsyn.021.0079. Thorpe, J. F.; Kon, G. A. R. (1925). "Cyclopentanone". Organic Syntheses. 5: 37...
described Scott as "erratic", stating that his reactions to both book and television series are inconsistent. Thorpe's biographer Michael Bloch described Josiffe...
amination reaction to produce his high purity methamphetamine, relying on phenyl-2-propanone and methylamine. Forster–Decker method Leuckart reactionThorpe, Thomas...
Greek: μεταβολή metabolē, "change") is the set of life-sustaining chemical reactions in organisms. The three main functions of metabolism are: the conversion...
is a chemical reaction that removes a carboxyl group and releases carbon dioxide (CO2). Usually, decarboxylation refers to a reaction of carboxylic acids...
occurring as a result of a medication, it is also known as an infusion reaction. The term cytokine storm is often used interchangeably with CRS but, despite...
and starboard red and green lenses. National Post. [Toronto Edition] DT7. Thorpe, Dave (2005). Carbide Light: The Last Flame in American Mines. Bergamot...
997–999. Thorpe 2001, pp. 8–9. Thorpe 2006, pp. 1010–1012, 1016. Thorpe 2006, pp. 1013–1014. Thorpe 2001, pp. 14–15; Thorpe 2010a, pp. 23–24. Thorpe 2001...
the University of London. He then joined the laboratory of Jocelyn Field Thorpe at Imperial College, London, with a brief hiatus from 1918-1920 during which...
from the original (PDF) on September 14, 2012. Retrieved January 15, 2013. Thorpe, Thomas Edward, ed., A Dictionary of Applied Chemistry (London, England:...
Ben and Eve McFarren, Diane Ballard, Dr. Sara McIntyre, Adam Thorpe, Barbara Norris Thorpe, Justin Marler and Steve Jackson. Actress Lenore Kasdorf quit...
Bay Area. The band was conceived by founder and guitarist/vocalist Geoff Thorpe, and has been actively recording and touring worldwide since their full-length...
Hitchcock Hour (1963) (Season 1 Episode 23: "The Lonely Hours") as Grace Thorpe Lukanic, Steven A (1993). Film Actors Guide. p. 403. Monush, Barry (2003)...
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