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Thiourea dioxide information


Thiourea dioxide
Names
Preferred IUPAC name
Amino(imino)methanesulfinic acid
Other names
Thiourea dioxide, DegaFAS, Reducing Agent F, Depilor, Formamidine Sulfinic Acid
Identifiers
CAS Number
  • 1758-73-2 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 55213
ECHA InfoCard 100.015.598 Edit this at Wikidata
PubChem CID
  • 61274
UNII
  • 42BWR07L73 checkY
CompTox Dashboard (EPA)
  • DTXSID4029224 Edit this at Wikidata
InChI
  • InChI=1S/CH4N2O2S/c2-1(3)6(4)5/h(H3,2,3)(H,4,5)
    Key: FYOWZTWVYZOZSI-UHFFFAOYSA-N
SMILES
  • C(=N)(N)S(=O)O
Properties
Chemical formula
CH4N2O2S
Molar mass 108.12 g·mol−1
Appearance White powder
Melting point 126 °C (259 °F; 399 K)
Solubility in water
3.0 g/100 mL
Hazards
GHS labelling:
Pictograms
GHS02: FlammableGHS05: CorrosiveGHS07: Exclamation markGHS08: Health hazard
Signal word
Danger
Hazard statements
H252, H302, H315, H318, H332, H335, H373
Precautionary statements
P235+P410, P270, P280, P305+P351+P338, P310, P407, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N (what is checkY☒N ?)
Infobox references

Thiourea dioxide or thiox is an organosulfur compound that is used in the textile industry.[1] It functions as a reducing agent.[2] It is a white solid, and exhibits tautomerism.[citation needed]

  1. ^ Fischer, Klaus (2003). "Textile Auxiliaries". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a26_227. ISBN 9783527303854. OCLC 55738480. Archived from the original on 2022-06-18. Retrieved 2022-06-18.
  2. ^ Milne, George W. A. (11 July 2005). Gardner's Commercially Important Chemicals: Synonyms, Trade Names, and Properties. Hoboken, New Jersey, USA: Wiley-Interscience. doi:10.1002/0471736627.ch1. ISBN 9780471735182. OCLC 57392953. Archived from the original on 18 June 2022. Retrieved 18 June 2022.

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Thiourea dioxide

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Thiourea dioxide or thiox is an organosulfur compound that is used in the textile industry. It functions as a reducing agent. It is a white solid, and...

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Thiourea

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mainly consumed as a precursor to thiourea dioxide, which is a common reducing agent in textile processing. Recently thiourea has been investigated for its...

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Sulfoxylic acid

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Sulfoxylate ions can be made by decomposing thiourea dioxide in an alkaline solution. To do this, thiourea dioxide first forms an amidine-sulfinic acid tautomer...

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Paper chemicals

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eliminates the use of hypochlorite and replaces chlorine with chlorine dioxide or sodium chlorate. Totally chlorine-free bleaching utilizes oxygen and...

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Sulfinic acid

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A commercially important sulfinic acid is thiourea dioxide, which is prepared by the oxidation of thiourea with hydrogen peroxide. (NH2)2CS + 2H2O2 →...

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Sulfene

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amido substituents on the alkylidene substituent. The extreme case is thiourea dioxide, which features planar amido groups. Sulfenes react with enamines,...

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List of UN numbers 3301 to 3400

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Refrigerant gas R407B UN 3340 2.2 Refrigerant gas R407C UN 3341 4.2 Thiourea dioxide UN 3342 4.2 Xanthates UN 3343 3 Nitroglycerin mixture, desensitized...

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Urea

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accounts for 80% of the liquid fertilizers in the US. Wöhler urea synthesis Thiourea Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred...

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Cleaning agent

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silver sulfide, which is removable via silver-specific complexants such as thiourea. Stainless steel, nickel, and chromium cleaners contain lactic, citric...

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EPA list of extremely hazardous substances

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Thiocarbazide Thiofanox Thionazin Thiophenol Thiosemicarbazide Thiourea, (2-chlorophenyl)- Thiourea, (2-methylphenyl)- Titanium tetrachloride Toluene 2,4-diisocyanate...

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Catalysis

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application of covalent (e.g., proline, DMAP) and non-covalent (e.g., thiourea organocatalysis) organocatalysts referring to the preferred catalyst-substrate...

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Calcium cyanamide

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aqueous solution. Thiourea can be produced by the reaction of hydrogen sulfide with calcium cyanamide in the presence of carbon dioxide. Calcium cyanamide...

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Carbodiimide

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cyanamide. A classic route to carbodiimides involves dehydrosulfurization of thioureas. A typical reagent for this process is mercuric oxide: (R(H)N)2CS + HgO...

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Sulfamic acid

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label on the consumer product, the silver cleaning product TarnX contains thiourea, a detergent, and sulfamic acid. Candlin, J. P.; Wilkins, R. G. (1960)...

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Carbonyldiimidazole

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of asymmetric bis alkyl carbonates Thiocarbonyldiimidazole (TCDI) the thiourea analogue H.A. Staab (1962). "Syntheses Using Heterocyclic Amides (Azolides)"...

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Methanethiol

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impractical, it can be prepared by the reaction of methyl iodide with thiourea. Methanethiol is mainly used to produce the essential amino acid methionine...

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Polyethylene glycol

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Gholinejad M (January 2010). "One-Pot Thioetherification of Aryl Halides Using Thiourea and Alkyl Bromides Catalyzed by Copper(I) Iodide Free from Foul-Smelling...

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Tritellurium dichloride

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They are prepared by treating tellurium dioxide with hydrochloric acid in the presence of thioureas. The thiourea serves both as a ligand and as a reductant...

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Pyrimidine

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with diamines for instance the synthesis of 2-thio-6-methyluracil from thiourea and ethyl acetoacetate or the synthesis of 4-methylpyrimidine with 4...

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Selenium

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and +6. Selenium forms two oxides: selenium dioxide (SeO2) and selenium trioxide (SeO3). Selenium dioxide is formed by combustion of elemental selenium:...

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Clathrate compound

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Other hydrogen-bonded networks are derived from hydroquinone, urea, and thiourea. A much studied host molecule is Dianin's compound. Hofmann clathrates...

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Corrosion inhibitors for the petroleum industry

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inhibitors in the oil industry are nitriles, amides, oximes, ureas and, thioureas, and phosphonate salts. Inorganic inhibitors such as lanthanides, molybdates...

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Nitrification

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compounds with strong inhibitory effects such as carbon disulfide and thiourea. In particular, thiophosphoryl triamide has been a notable addition where...

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Pyrithione

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acid. Another approach involves treating the same starting N-oxide with thiourea to afford pyridyl-2-isothiouronium chloride N-oxide which undergoes base...

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Cyanamide

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hydrogen sulfide, and hydrogen selenide react with cyanamide to give urea, thiourea, and selenourea, respectively: H2NCN + H2E → H2NC(E)NH2 (E = O, S, Se)...

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Ethylene oxide

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to reverse the ethylene oxide synthesis reaction. Thiocyanate ions or thiourea transform ethylene oxide into thiirane (ethylene sulfide): (CH2CH2)O +...

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Epoxide

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reactions, illustrated by the insertion of carbon dioxide to give cyclic carbonates. When treated with thiourea, epoxides convert to the episulfide, which are...

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