Reacts with amines and alcohols, soluble in polar organic solvents
Magnetic susceptibility (χ)
-50.6·10−6 cm3/mol
Refractive index (nD)
1.558
Structure
Molecular shape
planar, sp2, C2v
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Highly toxic
Flash point
62 °C (144 °F; 335 K)
Related compounds
Related compounds
Phosgene
Thiocarbonyl fluoride
Thiocarbonyl bromide
Sulfur dichloride
Thionyl chloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
Chemical compound
Thiophosgene is a red liquid with the formula CSCl2. It is a molecule with trigonal planar geometry. There are two reactive C–Cl bonds that allow it to be used in diverse organic syntheses.[1]
^Manchiu D. S. Lay, Mitchell W. Sauerhoff And Donald R. Saunders "Carbon Disulfide" in Ullmann's Encyclopedia Of Industrial Chemistry, 2000, Wiley-VCH, Weinheim.
doi:10.1002/14356007.a05_185
Thiophosgene is a red liquid with the formula CSCl2. It is a molecule with trigonal planar geometry. There are two reactive C–Cl bonds that allow it to...
commercially available but can also be prepared via the reaction of thiophosgene with two equivalents of imidazole. The imidazole groups on TCDI can be...
S2Cl2 also arises from the chlorination of CS2 as in the synthesis of thiophosgene or carbon tetrachloride. S2Cl2 hydrolyzes to sulfur dioxide and elemental...
Cl2 → CCl4 + S2Cl2 This conversion proceeds via the intermediacy of thiophosgene, CSCl2. CS2 is a ligand for many metal complexes, forming pi complexes...
include the important compounds carbon disulfide, carbonyl sulfide, and thiophosgene. Thioketones (RC(=S)R′) are uncommon with alkyl substituents, but one...
+ COCl2 → PhC(S)Cl + HCl + COS The most common thioacyl chloride is thiophosgene. Hermann Staudinger; Siegwart, J. (1920). "Ueber Thiobenzoylchlorid"...
4,4-tetrachloro-1,3-dithietane, the photochemically-formed dimer of thiophosgene, and tetrakis(trifluoromethyl)-1,3-dithietane, [(CF3)2CS]2. Oxidized...
of trithiocarbonic acid with methanethiol. One synthesis starts from thiophosgene as described in this simplified equation: CSCl2 + 2 CH3SH → CS(SCH3)2...
which has C2v symmetry. Monothiocarbonate arises by the hydrolysis of thiophosgene or the reaction of base with carbonyl sulfide: COS + 2 NaOH → Na2CO2S...
N′-disubstituted thioureas can be prepared by coupling two amines with thiophosgene: HNR2 + S=CCl2 → 2 S=C(NR2)2 + 2 HCl Amines also condense with organic...
2,6-diisopropyl-4-phenoxyaniline will then undergo a reaction with thiophosgene and form N-(2,6-diisopropyl-4-phenoxyphenyl)isothiocyanate. This in turn...
silver acetylide derivative of sodium propiolate (AgC≡CCOONa), and then thiophosgene. AgC≡CCOONa in turn is made from silver ions and sodium propiolate. The...
truxillic acid. Many photodimers are now recognized, e.g. pyrimidine dimer, thiophosgene, diamantane. Another example was uncovered by Egbert Havinga in 1956...
indirect routes, such as the reaction of disodium tetracarbonylferrate with thiophosgene: Na2Fe(CO)4 + CSCl2 → Fe(CO)4CS + 2 NaCl Complexes of CSe and CTe have...
performing the reaction in the presence of diketones. Another byproduct is thiophosgene. The more volatile byproducts such as carbon tetrachloride and sulfur...
(UN No. no longer in use) UN 2473 6.1 Sodium arsanilate UN 2474 6.1 Thiophosgene UN 2475 8 Vanadium trichloride UN 2476 ? (UN No. no longer in use) Warfarin...
[83763-22-8] (2). The reaction of the terminal amino group with thiophosgene [463-71-8] leads to the corresponding isothiocyanate derivative, 4-fluorophenyl...
dinitrogen tetrafluoride are disulfur decafluoride or sulfur dioxide or thiophosgene in an electric discharge. A corona discharge in a sulfur hexafluoride...
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