Global Information Lookup Global Information

Tetrarhodium dodecacarbonyl information


Tetrarhodium dodecacarbonyl
Names
IUPAC name
tri-μ-carbonyl-1:2κ2C;1:3κ2C;2:3κ2C-nonacarbonyl- 1κ2C,2κ2C,3κ2C,4κ3C-[Td-(13)-Δ4-closo]-tetrarhodium(6 RhRh)
Other names
rhodium(0) carbonyl; rhodium carbonyl; rhodium dodecacarbonyl
Identifiers
CAS Number
  • 19584-30-6 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 8115932
ECHA InfoCard 100.039.232 Edit this at Wikidata
EC Number
  • 243-171-9
PubChem CID
  • 9940312
CompTox Dashboard (EPA)
  • DTXSID90941352 Edit this at Wikidata
InChI
  • InChI=1S/12CO.4Rh/c12*1-2;;;;
    Key: LVGLLYVYRZMJIN-UHFFFAOYSA-N
SMILES
  • [Rh-2]1235(C#[O+])(C#[O+])C(=O)[Rh-2]246(C#[O+])(C#[O+])C(=O)[Rh-2]34(C#[O+])(C#[O+])(C1=O)[Rh-3]56(C#[O+])(C#[O+])C#[O+]
Properties
Chemical formula
Rh4(CO)12
Molar mass 747.743 g/mol
Appearance Red crystals
Solubility Chlorocarbons, toluene, tetrahydrofuran
Hazards
GHS labelling:
Pictograms
GHS07: Exclamation mark
Signal word
Warning
Hazard statements
H302, H312, H332
Precautionary statements
P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P312, P322, P330, P363, P501
Related compounds
Other cations
Tetracobalt dodecacarbonyl, Tetrairidium dodecacarbonyl
Related compounds
Rhodium(III) chloride, Rh6(CO)16, Rh2(CO)4Cl2
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Tetrarhodium dodecacarbonyl is the chemical compound with the formula Rh4(CO)12. This dark-red crystalline solid is the smallest binary rhodium carbonyl that can be handled as a solid under ambient conditions. It is used as a catalyst in organic synthesis.

and 10 Related for: Tetrarhodium dodecacarbonyl information

Request time (Page generated in 0.8315 seconds.)

Tetrarhodium dodecacarbonyl

Last Update:

Tetrarhodium dodecacarbonyl is the chemical compound with the formula Rh4(CO)12. This dark-red crystalline solid is the smallest binary rhodium carbonyl...

Word Count : 529

Tetracobalt dodecacarbonyl

Last Update:

C. H. (1969). "Structural analyses of tetracobalt dodecacarbonyl and tetrarhodium dodecacarbonyl. Crystallographic treatments of a disordered structure...

Word Count : 378

Nickel tetracarbonyl

Last Update:

nonacarbonyl Triruthenium dodecacarbonyl Triosmium dodecacarbonyl Dicobalt octacarbonyl Tetrarhodium dodecacarbonyl Tetrairidium dodecacarbonyl Except where otherwise...

Word Count : 1641

Tetrairidium dodecacarbonyl

Last Update:

Tetrairidium dodecacarbonyl is the chemical compound with the formula Ir4(CO)12. This tetrahedral cluster is the most common and most stable "binary" carbonyl...

Word Count : 310

Chromium hexacarbonyl

Last Update:

nonacarbonyl Triruthenium dodecacarbonyl Triosmium dodecacarbonyl Dicobalt octacarbonyl Tetrarhodium dodecacarbonyl Tetrairidium dodecacarbonyl Nickel tetracarbonyl...

Word Count : 1488

Hexadecacarbonylhexarhodium

Last Update:

It also arises quantitatively by thermal decomposition of tetrarhodium dodecacarbonyl in boiling hexane: 3 Rh4(CO)12 → 2 Rh6(CO)16 + 4 CO At least...

Word Count : 399

Tetrahedrane

Last Update:

metal carbonyl clusters are referred to as tetrahedranes, e.g. tetrarhodium dodecacarbonyl. Metallatetrahedranes with a single metal (or phosphorus atom)...

Word Count : 1643

Vanadium hexacarbonyl

Last Update:

nonacarbonyl Triruthenium dodecacarbonyl Triosmium dodecacarbonyl Dicobalt octacarbonyl Tetrarhodium dodecacarbonyl Tetrairidium dodecacarbonyl Nickel tetracarbonyl...

Word Count : 425

Iron pentacarbonyl

Last Update:

nonacarbonyl Triruthenium dodecacarbonyl Triosmium dodecacarbonyl Dicobalt octacarbonyl Tetrarhodium dodecacarbonyl Tetrairidium dodecacarbonyl Nickel tetracarbonyl...

Word Count : 1656

Organorhodium chemistry

Last Update:

complexes are binary carbonyls, the principal examples being tetrarhodium dodecacarbonyl, Rh4(CO)12, and hexadecacarbonylhexarhodium, Rh6(CO)16. These...

Word Count : 1125

PDF Search Engine © AllGlobal.net