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Hexadecacarbonylhexarhodium information


Hexadecacarbonylhexarhodium
Names
IUPAC name
Hexadecacarbonylhexarhodium
Other names
Hexarhodium hexadecacarbonyl
Identifiers
CAS Number
  • 28407-51-4 checkY[ECHA]
3D model (JSmol)
  • Interactive image
ChemSpider
  • 9041327
ECHA InfoCard 100.044.539 Edit this at Wikidata
EC Number
  • 249-009-3
PubChem CID
  • 10866043
CompTox Dashboard (EPA)
  • DTXSID10951074 Edit this at Wikidata
InChI
  • InChI=1S/16CO.6Rh/c16*1-2;;;;;;
    Key: SZQABOJVTZVBHE-UHFFFAOYSA-N
SMILES
  • [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Rh].[Rh].[Rh].[Rh].[Rh].[Rh]
Properties
Chemical formula
C16O16Rh6
Molar mass 1065.62 g/mol
Appearance purple-brown solid
Melting point 235 °C (455 °F; 508 K)
Hazards
GHS labelling:
Pictograms
GHS07: Exclamation mark
Signal word
Warning
Hazard statements
H302, H312, H332
Precautionary statements
P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P312, P322, P330, P363, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Hexadecacarbonylhexarhodium is a metal carbonyl cluster with the formula Rh6(CO)16. It exists as purple-brown crystals that are slightly soluble in dichloromethane and chloroform.[1] It is the principal binary carbonyl of rhodium.

  1. ^ Cite error: The named reference IS was invoked but never defined (see the help page).

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Hexadecacarbonylhexarhodium

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Hexadecacarbonylhexarhodium is a metal carbonyl cluster with the formula Rh6(CO)16. It exists as purple-brown crystals that are slightly soluble in dichloromethane...

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List of inorganic compounds

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HfO2 Hafnium(IV) silicate – HfSiO4 Hafnium(IV) sulfide – HfS2 Hexadecacarbonylhexarhodium – Rh6(CO)16 Holmium(III) carbonate – Ho2(CO3)3 Holmium(III) chloride...

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Tetrarhodium dodecacarbonyl

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dodecacarbonyl quantitatively decomposes in boiling hexane to afford hexadecacarbonylhexarhodium: 3 Rh4(CO)12 → 2 Rh6(CO)16 + 4 CO Because of their relevance...

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Organorhodium chemistry

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principal examples being tetrarhodium dodecacarbonyl, Rh4(CO)12, and hexadecacarbonylhexarhodium, Rh6(CO)16. These compounds are obtained by reductive carbonylation...

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