Sulfinyl halide have the general formula R−S(O)−X, where X is a halogen. They are intermediate in oxidation level between sulfenyl halides, R−S−X, and sulfonyl halides, R−SO2−X. The best known examples are sulfinyl chlorides, thermolabile, moisture-sensitive compounds, which are useful intermediates for preparation of other sufinyl derivatives such as sulfinamides, sulfinates, sulfoxides, and thiosulfinates.[1] Unlike the sulfur atom in sulfonyl halides and sulfenyl halides, the sulfur atom in sulfinyl halides is chiral,[2] as shown for methanesulfinyl chloride.
^Braverman, S; Cherkinsky, M.; Levinger, S. (2008). "Alkanesulfinyl Halides". Sci. Synth. 39: 188–196. ISBN 9781588905307.{{cite journal}}: CS1 maint: multiple names: authors list (link)
^Gilles Hanquet*, Françoise Colobert, Steve Lanners, and Guy Solladié. "Recent developments in chiral non-racemic sulfinyl-group chemistry in asymmetric synthesis" (PDF). Retrieved 13 May 2012.{{cite web}}: CS1 maint: multiple names: authors list (link)
Sulfinylhalide have the general formula R−S(O)−X, where X is a halogen. They are intermediate in oxidation level between sulfenyl halides, R−S−X, and...
HCl}}} Sulfenyl chlorides can be converted to sulfinyl chlorides (RS(O)Cl). In one approach, the sulfinyl chloride is generated in two steps starting with...
bonded to a single sulfur atom, e.g.: sulfenyl halides, RSX; sulfinylhalides, RS(O)X; sulfonyl halides, RSO2X; alkyl and arylsulfur trichlorides, RSCl3...
conveniently isolated. One route is a variant of ketene synthesis, in which a sulfinylhalide reacts with a hindered base. For example, syn-propanethial-S-oxide...
rearrangement of oximes. Thionyl chloride will transform sulfinic acids into sulfinyl chlorides Sulfonic acids react with thionyl chloride to produce sulfonyl...
sulfoxide, also called a sulphoxide, is an organosulfur compound containing a sulfinyl (>SO) functional group attached to two carbon atoms. It is a polar functional...
refer to: So.cl, a social networking website by Microsoft. Sulfinyl chloride, sulfinylhalides with the general formula R-S(O)-Cl. This disambiguation page...
sulfinamides (R(S=O)NHR) are amides of sulfinic acids (R(S=O)OH) (see sulfinyl). Chiral sulfinamides such as tert-butanesulfinamide, p-toluenesulfinamide...
derivatives are sometimes referred to as imines. N-Sulfinyl imines are a special class of imines having a sulfinyl group attached to the nitrogen atom. Imines...
Ottorino; Miotti, Umberto; Modena, Giorgio (1991). The Pummerer Reaction of Sulfinyl Compounds. Vol. 40. pp. 157–184. doi:10.1002/0471264180.or040.03. ISBN 978-0471264187...
moieties themselves or to radical species, and also to form the names of halides and substituents in larger molecules. When the parent hydrocarbon is unsaturated...
thiols or disulfides into their corresponding sulfenyl chlorides, though sulfinyl chlorides result from thiols in some cases. SO2Cl2 can also convert alcohols...
[2+2]-Cycloaddition of Sulfenes and Aldehydes: A Versatile Entry to Chiral Sulfonyl and Sulfinyl Derivatives". Chem. Eur. J. 17 (13): 3679–3692. doi:10.1002/chem.201003542...
proceeds in high yield and affords only the (E)-isomer of the corresponding N-sulfinyl imines. Condensation of tert-butanesulfinamide with aldehydes and ketones...
family include thiosulfonates (R-SO2-S-R), α-disulfoxides (R-S(O)-S(O)-R), sulfinyl sulfones (R-S(O)-SO2-R), and α-disulfones (R-SO2-SO2-R), of which all (except...
organic chemistry, the thionyl group is known as a sulfoxide group or sulfinyl group, and has the general structure RS(=O)R'. Sulfuryl Greenwood, Norman...
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