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Simple aromatic ring information


Simple aromatic rings, also known as simple arenes or simple aromatics, are aromatic organic compounds that consist only of a conjugated planar ring system. Many simple aromatic rings have trivial names. They are usually found as substructures of more complex molecules ("substituted aromatics"). Typical simple aromatic compounds are benzene, indole, and pyridine.[1][2]

Simple aromatic rings can be heterocyclic if they contain non-carbon ring atoms, for example, oxygen, nitrogen, or sulfur. They can be monocyclic as in benzene, bicyclic as in naphthalene, or polycyclic as in anthracene. Simple monocyclic aromatic rings are usually five-membered rings like pyrrole or six-membered rings like pyridine. Fused/condensed[3] aromatic rings consist of monocyclic rings that share their connecting bonds.

  1. ^ Clayden, J.; Greeves, N.; Warren, S.; Wothers, P. (2001). Organic Chemistry. Oxford, Oxfordshire: Oxford University Press. ISBN 0-19-850346-6.
  2. ^ Eicher, T.; Hauptmann, S. (2003). The Chemistry of Heterocycles: Structure, Reactions, Syntheses, and Applications (2nd ed.). Wiley-VCH. ISBN 3-527-30720-6.
  3. ^ "Aromatic Hydrocarbon - an overview | ScienceDirect Topics". www.sciencedirect.com. Retrieved 2021-05-06.

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Simple aromatic ring

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Aromatic compound

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Basic aromatic ring

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Basic aromatic rings are aromatic rings in which the lone pair of electrons of a ring-nitrogen atom is not part of the aromatic system and extends in...

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Cyclic compound

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but simpler than the paclitaxel that follows, which displays a complex ring structure including 3-, 5-, and 7-membered non-aromatic, carbocyclic rings. Cycloalkanes...

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Naphthalene

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low as 0.08 ppm by mass. As an aromatic hydrocarbon, naphthalene's structure consists of a fused pair of benzene rings. It is the main ingredient of traditional...

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Thiophene

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compound with the formula C4H4S. Consisting of a planar five-membered ring, it is aromatic as indicated by its extensive substitution reactions. It is a colorless...

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Imidazole

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highly soluble in water. The compound is classified as aromatic due to the presence of a planar ring containing 6 π-electrons (a pair of electrons from the...

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Nucleophilic aromatic substitution

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leaving group, such as a halide, on an aromatic ring. Aromatic rings are usually nucleophilic, but some aromatic compounds do undergo nucleophilic substitution...

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Benzene

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contained multiple double bonds or multiple rings, but in these years very little was known about aromatic chemistry, and so chemists were unable to adduce...

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Pyrimidine

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established starting from simple atmospheric or volcanic molecules. ANRORC mechanism Purine Pyrimidine metabolism Simple aromatic rings Transition Transversion...

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Furan

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consisting of a five-membered aromatic ring with four carbon atoms and one oxygen atom. Chemical compounds containing such rings are also referred to as furans...

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Benzimidazole

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Benzimidazole is a heterocyclic aromatic organic compound. This bicyclic compound may be viewed as fused rings of the aromatic compounds benzene and imidazole...

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Indole

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classified as an aromatic heterocycle. It has a bicyclic structure, consisting of a six-membered benzene ring fused to a five-membered pyrrole ring. Indoles are...

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Purine

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Purine is a heterocyclic aromatic organic compound that consists of two rings (pyrimidine and imidazole) fused together. It is water-soluble. Purine also...

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Pyridine

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electrons that are delocalized over the ring. The molecule is planar and, thus, follows the Hückel criteria for aromatic systems. In contrast to benzene, the...

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Borazine

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carbon based explosives such as CL-20. (C 2H 2B 2N 2) is a six-membered aromatic ring with two carbon atoms, two nitrogen atoms, and two boron atoms in opposing...

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Polycyclic aromatic hydrocarbon

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A polycyclic aromatic hydrocarbon (PAH) is a class of organic compounds that is composed of multiple aromatic rings. The simplest representative is naphthalene...

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Pyrazine

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Pyrimidine, an analog with the second nitrogen atom in position 3 Simple aromatic rings International Union of Pure and Applied Chemistry (2014). Nomenclature...

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Isoquinoline

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alkaloids such as papaverine. The isoquinoline ring in these natural compound derives from the aromatic amino acid tyrosine. Isoquinoline is a colorless...

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Quinoline

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Similar simple aromatic rings Isoquinoline, an analog with the nitrogen atom in position 2 Pyridine, an analog without the fused benzene ring Naphthalene...

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Diazine

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Fateley, William G.; Grasselli, Jeanette G. (1991-01-01). "Aromatic and Heteroaromatic Rings". The Handbook of Infrared and Raman Characteristic Frequencies...

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Cyclopentadienyl anion

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fulfills Hückel's rule of aromaticity. Each double bond and lone pair provides 2 π-electrons, which are delocalized into the ring. The cyclopentadienyl anion...

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Aromatic amino acid

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An aromatic amino acid is an amino acid that includes an aromatic ring. Among the 20 standard amino acids, histidine, phenylalanine, tryptophan, tyrosine...

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Delocalized electron

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several adjacent atoms. In the simple aromatic ring of benzene, the delocalization of six π electrons over the C6 ring is often graphically indicated...

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Aromatic ring current

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An aromatic ring current is an effect observed in aromatic molecules such as benzene and naphthalene. If a magnetic field is directed perpendicular to...

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Triazine

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5-triazine. Other aromatic nitrogen heterocycles are pyridines with one ring nitrogen atom, diazines with 2 nitrogen atoms in the ring, triazoles with 3...

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Tropylium cation

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The tropylium ion or cycloheptatrienyl cation is an aromatic species with a formula of [C7H7]+. Its name derives from the molecule tropine from which cycloheptatriene...

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Electrophilic aromatic substitution

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of the most important electrophilic aromatic substitutions are aromatic nitration, aromatic halogenation, aromatic sulfonation, alkylation Friedel–Crafts...

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