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Selenium dioxide information


Selenium dioxide
Selenium dioxide
Ball-and-stick model of a chain in crystalline selenium dioxide
Crystals of selenium dioxide
Names
Other names
Selenium(IV) oxide
Selenous anhydride
Identifiers
CAS Number
  • 7446-08-4 checkY
3D model (JSmol)
  • monomer: Interactive image
  • polymer: Interactive image
ChEMBL
  • ChEMBL3183452
ChemSpider
  • 22440 checkY
ECHA InfoCard 100.028.358 Edit this at Wikidata
EC Number
  • 231-194-7
PubChem CID
  • 24007
RTECS number
  • VS8575000
UNII
  • 9N3UK29E57 checkY
UN number 3283
CompTox Dashboard (EPA)
  • DTXSID4021264 Edit this at Wikidata
InChI
  • InChI=1S/O2Se/c1-3-2 checkY
    Key: JPJALAQPGMAKDF-UHFFFAOYSA-N checkY
  • InChI=1/O2Se/c1-3-2
    Key: JPJALAQPGMAKDF-UHFFFAOYAQ
SMILES
  • monomer: O=[Se]=O
  • polymer: O[Se](=O)O[Se](=O)O[Se](=O)O[Se](=O)O[Se](=O)O[Se](=O)O[Se](=O)O[Se](=O)O[Se](=O)O[Se](=O)O[Se](=O)O[Se](=O)O[Se](=O)O[Se](=O)O[Se](=O)O
Properties
Chemical formula
SeO2
Molar mass 110.96 g/mol
Appearance White crystals, turn slightly pink with trace decomposition[1]
Odor rotten radishes
Density 3.954 g/cm3, solid
Melting point 340 °C (644 °F; 613 K) (sealed tube)
Boiling point 350 °C (662 °F; 623 K) subl.
Solubility in water
38.4 g/100 mL (20 °C)
39.5 g/100 ml (25 °C)
82.5 g/100 mL (65 °C)
Solubility soluble in benzene
Solubility in ethanol 6.7 g/100 mL (15 °C)
Solubility in acetone 4.4 g/100 mL (15 °C)
Solubility in acetic acid 1.11 g/100 mL (14 °C)
Solubility in methanol 10.16 g/100 mL (12 °C)
Vapor pressure 1.65 kPa (70 °C)
Acidity (pKa) 2.62; 8.32
Magnetic susceptibility (χ)
−27.2·10−6 cm3/mol
Refractive index (nD)
> 1.76
Structure
Crystal structure
see text
Coordination geometry
trigonal (Se)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Toxic by ingestion and inhalation[2]
GHS labelling:
Pictograms
GHS06: ToxicGHS08: Health hazardGHS09: Environmental hazard
Signal word
Danger
Hazard statements
H301, H331, H373, H410
Precautionary statements
P260, P261, P264, P270, P271, P273, P301+P310, P304+P340, P311, P314, P321, P330, P391, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
3
0
0
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
LCLo (lowest published)
5890 mg/m3 (rabbit, 20 min)
6590 mg/m3 (goat, 10 min)
6590 mg/m3 (sheep, 10 min)[3]
Safety data sheet (SDS) ICSC 0946
Related compounds
Other anions
Selenium disulfide
Other cations
Sulfur dioxide
Tellurium dioxide
Related selenium oxides
Selenium trioxide
Related compounds
Selenous acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Selenium dioxide is the chemical compound with the formula SeO2. This colorless solid is one of the most frequently encountered compounds of selenium. It is used in making specialized glasses as well as a reagent in organic chemistry.[4]

  1. ^ "Safety data sheet: Selenium dioxide" (PDF). integrachem.com. 27 March 2015. Retrieved 2022-12-02.
  2. ^ "Selenium dioxide safety and hazards". pubchem.ncbi.nlm.nih.gov. Retrieved 2022-12-02.
  3. ^ "Selenium compounds (as Se)". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).
  4. ^ Hoekstra, William J.; Fairlamb, Ian J. S.; Giroux, Simon; Chen, Yuzhong (2017). "Selenium(IV) Oxide". Encyclopedia of Reagents for Organic Synthesis. pp. 1–12. doi:10.1002/047084289X.rs008.pub3. ISBN 978-0-470-84289-8.

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organoselenium compounds, chemical compounds containing carbon-to-selenium chemical bonds. Selenium belongs with oxygen and sulfur to the group 16 elements or...

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forms two oxides: selenium dioxide (SeO2) and selenium trioxide (SeO3). Selenium dioxide is formed by the reaction of elemental selenium with oxygen: Se...

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pyramidal molecule. Selenium oxydichloride can be prepared by several methods, and a common one involves the conversion of selenium dioxide to dichloroselenious...

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Selenium trioxide

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precursor to Se(VI) compounds. Selenium trioxide is difficult to prepare because it is unstable with respect to the dioxide: 2 SeO3 → 2 SeO2 + O2 It has...

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Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula SO 2. It is...

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Selenium oxide

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Selenium oxide may refer to either of the following compounds: Selenium dioxide, SeO2 Selenium trioxide, SeO3 Diselenium pentoxide, Se2O5 This set index...

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Selenium hexafluoride

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It also forms by the reaction of bromine trifluoride (BrF3) with selenium dioxide. The crude product can be purified by sublimation. The relative reactivity...

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Camphorquinone

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composites. Camphorquinone is produced by the oxidation of camphor with selenium dioxide. Polymerization is induced very slowly by camphorquinone, so amines...

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Selenium tetrafluoride

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involving more easily handled reagents entails the fluorination of selenium dioxide with sulfur tetrafluoride: SF4 + SeO2 → SeF4 + SO2 An intermediate...

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Tellurium dioxide

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Tellurium dioxide (TeO2) is a solid oxide of tellurium. It is encountered in two different forms, the yellow orthorhombic mineral tellurite, β-TeO2, and...

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Selenic acid

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is prepared by oxidising selenium compounds in lower oxidation states. One method involves the oxidation of selenium dioxide with hydrogen peroxide: SeO2...

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Sodium hydrogen selenite

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providing the essential trace element selenium. Its preparation involves reacting sodium hydroxide with selenium dioxide. "Sodium hydrogen selenite". pubchem...

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Interchalcogen

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Disulfur dioxide, S2O2 Sulfur monoxide, SO Sulfur dioxide, SO2 Sulfur trioxide, SO3 Higher sulfur oxides, SOx where x > 3 Selenium dioxide, SeO2 Selenium trioxide...

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Selenium tetrachloride

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acids:[page needed] SeCl4 + 3 H2O → H2SeO3 + 4 HCl Upon treatment with selenium dioxide, it gives selenium oxychloride:[page needed] SeCl4 + SeO2 → 2SeOCl2 Lide, David...

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Selenium monochloride

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involved chlorination of elemental selenium. An improved method involves the reaction of a mixture of selenium, selenium dioxide, and hydrochloric acid: 3 Se...

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Sodium selenite

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the most common water-soluble selenium compound. Sodium selenite usually is prepared by the reaction of selenium dioxide with sodium hydroxide: SeO2 +...

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Mill scale

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through the metallurgical use of phosphoric acid or in conjunction with selenium dioxide can create a high contrast visual substrate onto which other compositional...

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Selenium oxybromide

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Selenium oxybromide (SeOBr2) is a selenium oxohalide chemical compound. Selenium oxybromide can be prepared through the reaction of selenium dioxide and...

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Allyl group

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available sesquiterpenoid: In the synthesis of some fine chemicals, selenium dioxide is used to convert alkenes to allylic alcohols: R2C=CR'-CHR"2 + [O]...

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Glass

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materials, e.g., sodium selenite may be preferred over easily evaporating selenium dioxide (SeO2). Also, more readily reacting raw materials may be preferred...

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Permethrin

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yield m-phenoxytoluene. Second, oxidation of m-phenoxytoluene over selenium dioxide provides m-phenoxybenzaldehyde. Third, a Cannizzaro reaction of the...

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Tetrahydroisoquinoline

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to the corresponding nitrone using hydrogen peroxide, catalyzed by selenium dioxide. Tetrahydroisoquinoline derivatives may be formed in the body as metabolites...

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Allyl alcohol

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general are prepared by allylic oxidation of allyl compounds, using selenium dioxide or organic peroxides. Other methods include carbon-carbon bond-forming...

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