Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
Barium ruthenate is an inorganic compound, with the chemical formula of BaRuO3. It can be obtained from the stoichiometric reaction of barium oxide and ruthenium(IV) oxide at temperatures below 1200 °C,[3] or from the thermal decomposition of Ba[Ru(NO)(NO2)4(OH)]·xH2O.[4] It reacts with ruthenium and ruthenium(IV) oxide at 1250 °C to obtain black needle-like crystal BaRu6O12.[5] Hydrogen or zirconium can reduce it when heated to produce metal ruthenium.[1]
^ abJohn B. Wiley; Kenneth R. Poeppelmeier (1991-11-01). "Reduction chemistry of platinum group metal perovskites". Materials Research Bulletin. 26 (11): 1201–1210. doi:10.1016/0025-5408(91)90127-8. Archived from the original on 2018-06-30. Retrieved 2022-08-31.
^Popova, T. L.; Kisel, N. G.; Krivobok, V. I.; Karlov, V. P. Reactions in the barium oxide-ruthenium(IV) oxide system(in Russian). Ukrainskii Khimicheskii Zhurnal (Russian Edition), 1982. 48 (5): 457-460. ISSN 0041-6045.
^Sinitsyn, N. M.; Kokunova, V. N. Preparation of double ruthenium oxides from coordination compounds(in Russian). Zhurnal Neorganicheskoi Khimii, 1990. 35 (12): 3120-3123. ISSN 0044-457X.
^C.C. Torardi (1985-06-01). "Synthesis and crystal structure of BaRu6O12: An ordered stoichiometric hollandite". Materials Research Bulletin. 20 (6): 705–713. doi:10.1016/0025-5408(85)90149-7. Archived from the original on 2018-06-04. Retrieved 2022-08-31.
Bariumruthenate is an inorganic compound, with the chemical formula of BaRuO3. It can be obtained from the stoichiometric reaction of barium oxide and...
potassium ruthenate, K2RuO4, with chlorine gas. The perruthenate ion is unstable and is reduced by water to form the orange ruthenate. Potassium ruthenate may...
rare-earth manganites, titanates, lanthanum aluminate (LaAlO3), strontium ruthenate (SrRuO3) and many others. Oxygen vacancies are fairly common in SrTiO3...
Gingras, Olivier (Sep 2021). La supraconductivité non-conventionnelle du ruthénate de strontium: corrélations électroniques et couplage spin-orbite (in French)...
some that do not superconduct at high temperatures, such as strontium ruthenate Sr2RuO4, but that, like high-temperature superconductors, are unconventional...
by oxidation of ruthenium(VI) in acid, readily undergoes reduction to ruthenate(VI), RuO2− 4. Oxidation of ruthenium metal in air forms the dioxide, RuO2...