91 to 93 °C (196 to 199 °F; 364 to 366 K) (monohydrate)
Magnetic susceptibility (χ)
-99.20·10−6 cm3/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Nverify (what is YN ?)
Infobox references
Chemical compound
Rhamnose (Rha, Rham) is a naturally occurring deoxy sugar. It can be classified as either a methyl-pentose or a 6-deoxy-hexose. Rhamnose predominantly occurs in nature in its L-form as L-rhamnose (6-deoxy-L-mannose). This is unusual, since most of the naturally occurring sugars are in D-form. Exceptions are the methyl pentoses L-fucose and L-rhamnose and the pentose L-arabinose. However, examples of naturally-occurring D-rhamnose include some species of bacteria, such as Pseudomonas aeruginosa and Helicobacter pylori.[2]
Rhamnose can be isolated from buckthorn (Rhamnus), poison sumac, and plants in the genus Uncaria. Rhamnose is also produced by microalgae belonging to class Bacillariophyceae (diatoms).[3]
Rhamnose is commonly bound to other sugars in nature. It is a common glycone component of glycosides from many plants. Rhamnose is also a component of the outer cell membrane of acid-fast bacteria in the Mycobacterium genus, which includes the organism that causes tuberculosis.[4] Natural antibodies against L-rhamnose are present in human serum,[5] and the majority of people seem to possess IgM, IgG or both of these types of immunoglobulins capable of binding this glycan.[6]
An interesting particularity of rhamnose is the presence of formaldehyde production when reacted with periodates in the vicinal diol cleavage reaction, that makes it very useful to remove excess periodate in glycerol or other vicinal diol analysis, that would otherwise give colored blank issues.[7]
^Merck Index, 11th Edition, 8171.
^Melamed J, Kocev A, Torgov V, Veselovsky V, Brockhausen I (2022). "Biosynthesis of the Pseudomonas aeruginosa common polysaccharide antigen by D‐Rhamnosyltransferases WbpX and WbpY". Glycoconjugate Journal. doi:10.1007/s10719-022-10040-4. PMC 8853325. PMID 35166992.
^Brown, M. R. (1991). "The amino-acid and sugar composition of 16 species of microalgae used in mariculture". Journal of Experimental Marine Biology and Ecology. 145: 79. doi:10.1016/0022-0981(91)90007-J.
^Golan, David E., ed. (2005). "Chapter 35 - Pharmacology of the Bacterial Cell Wall". Principles of Pharmacology: The Pathophysiologic Basis of Drug Therapy. Armen H. Tashjian Jr., Ehrin J. Armstrong, Joshua N. Galanter, April Wang Armstrong, Ramy A. Arnaout, Harris S. Rose. Lippincott Williams and Wilkins. p. 569. ISBN 0-7817-4678-7.
^Oyelaran O, McShane LM, Dodd L, Gildersleeve JC (2009). "Profiling Human Serum Antibodies with a Carbohydrate Antigen Microarray". J. Proteome Res. 8 (9): 4301–10. doi:10.1021/pr900515y. PMC 2738755. PMID 19624168.
^Wang X, Chen H, Chiodo F, Tefsen B (2019). "Detection of human IgM and IgG antibodies by means of galactofuranose-coated and rhamnose-coated gold nanoparticles". Matters. https://sciencematters.io/articles/201908000004
^Ashworth, M. R. F., ed. (1979). "Chapter 3". Analytical methods for glycerol. Academic Press.
Rhamnose (Rha, Rham) is a naturally occurring deoxy sugar. It can be classified as either a methyl-pentose or a 6-deoxy-hexose. Rhamnose predominantly...
bacterial surfactants. They have a glycosyl head group, in this case a rhamnose moiety, and a 3-(hydroxyalkanoyloxy)alkanoic acid (HAA) fatty acid tail...
gum karaya is an acid polysaccharide composed of the sugars galactose, rhamnose and galacturonic acid. It is used as a thickener and emulsifier in foods...
systematic name UDP-rhamnose:soyasaponin III rhamnosyltransferase. This enzyme catalyses the following chemical reaction: UDP-rhamnose + soyasaponin III...
onions. Quercetin forms the glycosides quercitrin and rutin together with rhamnose and rutinose, respectively. Likewise guaijaverin is the 3-O-arabinoside...
"hexose" sometimes is assumed to include deoxyhexoses, such as fucose and rhamnose: compounds with general formula C 6H 12O 6-y that can be described as derived...
6-deoxy-L-tagatose, one of the important components of avian influenza virus particles Rhamnose, or 6-deoxy-L-mannose, present in plant glycosides In Escherichia coli...
quercetin, glycone: rutinose) Quercitrin (aglycone: quercetin, glycone: rhamnose) Among the important effects of flavonoids are their antioxidant effect...
the most common sugar present in glucosides, many are known which yield rhamnose or iso-dulcite; these may be termed pentosides. Much attention has been...
attached to an amino sugar (D-forosamine) and a neutral sugar (tri-Ο-methyl-L-rhamnose). Spinosad is relatively nonpolar and not easily dissolved in water. Spinosad...
Morrell (1894) "Ueber die Configuration der Rhamnose und Galactose" (On the configuration of rhamnose and galactose), Berichte der Deutschen chemischen...
Rha may refer to: Rha, Netherlands, a population center in Steenderen Rhamnose, a monosaccharide Volga River (the ancient name of the river in Latin,...
galactose and one fructose β(1→4) Rutinose One rhamnose and one glucose α(1→6) Rutinulose One rhamnose and one fructose β(1→6) Xylobiose Two xylopyranoses...
dilactone, monogalloyl glucose, digalloyl glucose, trigalloyl glucose, rhamnose, quercitrin and ellagic acid are phenolic compounds found in Q. robur....
substituting sugar in strawberry anthocyanins, rutinose, arabinose, and rhamnose conjugates have been found in some strawberry cultivars. Purple minor pigments...