Process to excite an atom beyond its ionization potential to form an ion
Photon beams from a tunable laser are used to selectively excite and promote cloud of atoms or molecules from ground state to higher excited states in resonance ionization.
Resonance ionization is a process in optical physics used to excite a specific atom (or molecule) beyond its ionization potential to form an ion using a beam of photons irradiated from a pulsed laser light.[1] In resonance ionization, the absorption or emission properties of the emitted photons are not considered, rather only the resulting excited ions are mass-selected, detected and measured.[2] Depending on the laser light source used, one electron can be removed from each atom so that resonance ionization produces an efficient selectivity in two ways: elemental selectivity in ionization and isotopic selectivity in measurement.[2][3][4]
During resonance ionization, an ion gun creates a cloud of atoms and molecules from a gas-phase sample surface and a tunable laser is used to fire a beam of photons at the cloud of particles emanating from the sample (analyte).
An initial photon from this beam is absorbed by one of the sample atoms, exciting one of the atom's electrons to an intermediate excited state. A second photon then ionizes the same atom from the intermediate state such that its high energy level causes it to be ejected from its orbital; the result is a packet of positively charged ions which are then delivered to a mass analyzer.[5][6]
Resonance ionization contrasts with resonance-enhanced multiphoton ionization (REMPI) in that the latter is neither selective nor efficient since resonances are seldom used to prevent interference. Also, resonance ionization is used for an atomic (elemental) analyte, whereas REMPI is used for a molecular analyte.[7]
The analytical technique on which the process of resonance ionization is based is termed resonance ionization mass spectrometry (RIMS). RIMS is derived from the original method, resonance ionization spectroscopy (RIS), which was initially being used to detect single atoms with better time resolution.[8] RIMS has proved useful in the investigation of radioactive isotopes (such as for studying rare fleeting isotopes produced in high-energy collisions), trace analysis (such as for discovering impurities in highly pure materials), atomic spectroscopy (such as for detecting low-content materials in biological samples), and for applications in which high levels of sensitivity and elemental selectivity are desired.
^ abFassett, J.D.; Travis, J.C. (1988). "Analytical applications of resonance ionization mass spectrometry (RIMS)". Spectrochimica Acta Part B: Atomic Spectroscopy. 43 (12): 1409–1422. doi:10.1016/0584-8547(88)80180-0. ISSN 0584-8547.
^Fassett, J. D.; Travis, J. C.; Moore, L. J.; Lytle, F. E. (1983-04-01). "Atomic ion formation and measurement with resonance ionization mass spectrometry". Analytical Chemistry. 55 (4): 765–770. doi:10.1021/ac00255a040. ISSN 0003-2700.
^Köster, U. (2002). "Resonance ionization laser ion sources". Nuclear Physics A. 701 (1–4): 441–451. Bibcode:2002NuPhA.701..441K. doi:10.1016/s0375-9474(01)01625-6.
^Hurst, G. S.; Kutschera, W.; Oeschger, H.; Korschinck, G.; Donahue, D. S.; Litherland, A. E.; Ledingham, K.; Henning, W. (1987). "Detection of Single Atoms by Resonance Ionization Spectroscopy [and Discussion]" (PDF). Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences. 323 (1569): 155–170. doi:10.1098/rsta.1987.0079. ISSN 1364-503X.
^Wendt, K.; Blaum, K.; Bushaw, B. A.; Grüning, C.; Horn, R.; Huber, G.; Kratz, J. V.; Kunz, P.; Müller, P. (1999-07-01). "Recent developments in and applications of resonance ionization mass spectrometry". Fresenius' Journal of Analytical Chemistry. 364 (5): 471–477. doi:10.1007/s002160051370. ISSN 0937-0633.
^Dass, Chhabil (2007). "Chapter 7: Inorganic Mass Spectrometry". In Desiderio, Dominic M.; Nibbering, Nico M. (eds.). Fundamentals of Contemporary Mass Spectrometry (1st ed.). John Wiley & Sons, Inc. pp. 273–275. ISBN 978-0471682295.
^Young, J. P.; Shaw, R. W.; Smith, D. H. (2008). "Resonance ionization mass spectrometry". Analytical Chemistry. 61 (22): 1271A–1279A. doi:10.1021/ac00197a002. ISSN 0003-2700.
and 24 Related for: Resonance ionization information
Resonanceionization is a process in optical physics used to excite a specific atom (or molecule) beyond its ionization potential to form an ion using...
radiation detectors such as the Geiger-Müller counter or the ionization chamber. The ionization process is widely used in a variety of equipment in fundamental...
almost to the ionization potential of the element. The element can then be ionized to an autoionising state or non-resonant ionization state. The technique...
important in laser ionization experiments. Laser spectroscopic experiments often involve ionization through a photon energy resonance at an intermediate...
multi-photon ionization (MPI), several photons of energy below the ionization threshold may actually combine their energies to ionize an atom. Resonance-enhanced...
Chemical ionization (CI) is a soft ionization technique used in mass spectrometry. This was first introduced by Burnaby Munson and Frank H. Field in 1966...
Electron ionization (EI, formerly known as electron impact ionization and electron bombardment ionization) is an ionization method in which energetic electrons...
electrospray ionization (ESI) and Koichi Tanaka for the development of soft laser desorption (SLD) and their application to the ionization of biological...
with the gas in the volume they can cause ionization if their kinetic energy is larger than the ionization energy of the atoms or molecules. The ions...
Magnetic resonance imaging (MRI) is a medical imaging technique used in radiology to form pictures of the anatomy and the physiological processes inside...
Magnetic resonance imaging of the brain uses magnetic resonance imaging (MRI) to produce high quality two-dimensional or three-dimensional images of the...
; Labotka, Theodore C. (2001-02-05). "Development of Laser-Based ResonanceIonization Techniques for 81-Kr and 85-Kr Measurements in the Geosciences" (PDF)...
University of Tennessee, Institute of ResonanceIonization Spectroscopy, founder, director 1985–1988 Resonanceionization for analytical spectroscopy, 1976...
Above-threshold ionization (ATI) is an extension of multi-photon ionization where even more photons are absorbed than actually would be necessary to ionize the atom...
Electron capture ionization is the ionization of a gas phase atom or molecule by attachment of an electron to create an ion of the form A − {\displaystyle...
generations. However, the development of laser-based techniques such as ResonanceIonization Spectroscopy has allowed relatively easy access to these Rydberg...
the ionization cross sections of atoms and molecules, by photoionization, electron ionization and other methods. As examples, several Fano resonances in...
nanometers). Roughly, this corresponds to both the first ionization energy of oxygen, and the ionization energy of hydrogen, both about 14 eV. In some Environmental...
Thonnard; L. D. MeKay; T. C. Labotka (2001). Development of Laser-Based ResonanceIonization Techniques for 81-Kr and 85-Kr Measurements in the Geosciences (PDF)...
single element chain of interest. At CERN, this device is called the ResonanceIonization Laser Ion Source (RILIS). Currently over 60% of all experiments opt...
Electron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a method for studying materials that have unpaired electrons. The...