Chemical reaction which breaks carbon-chlorine bonds via a reductant
In organochlorine chemistry, reductive dechlorination describes any chemical reaction which cleaves the covalent bond between carbon and chlorine via reductants, to release chloride ions. Many modalities have been implemented, depending on the application. Reductive dechlorination is often applied to remediation of chlorinated pesticides or dry cleaning solvents. It is also used occasionally in the synthesis of organic compounds, e.g. as pharmaceuticals.
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In organochlorine chemistry, reductivedechlorination describes any chemical reaction which cleaves the covalent bond between carbon and chlorine via reductants...
[citation needed] In bacteria, PCBs may be dechlorinated through reductivedechlorination, or oxidized by dioxygenase enzyme.[citation needed] In eukaryotes...
reducing metals such as iron powder. Bioremediation usually entails reductivedechlorination under anaerobic conditions by Dehalococcoides spp. Under aerobic...
Dimethyl sulfoxide (DMSO) reduction to Dimethyl sulfide (DMS) Reductivedechlorination TMAO is a chemical commonly produced by fish, and when reduced...
nanoparticles on Shewanella oneidensis with catalytic activity towards reductivedechlorination of polychlorinated biphenyls". Environmental Microbiology. 7 (3):...
process, two enzymes perform the dechlorination reactions–PCE reductive dehydrogenase (PCE-RDase) and TCE reductive dehydrogenase (TCE-RDase). The PCE-RDase...
management. Increased temperature around the warm well can enhance reductivedechlorination of chlorinated ethenes. Although low temperature in cold well can...
Dehalococcoides Containing Vinyl Chloride Reductive Dehalogenase Genes During an Enhanced ReductiveDechlorination Field Demonstration". Environmental Science...
Chem. Comm. 1991, 398-400. Hawari, J. Regioselectivity of dechlorination: reductivedechlorination of polychlorobiphenyls by polymethylhydrosiloxane-alkali...
DSM 11544). It grows by coupling the oxidation of lactate to the reductivedechlorination of 3-chloro-4-hydroxybenzoate. Sanford RA, Cole JR, Löffler FE...
PMID 16704344. Holliger, C.; Wohlfarth, G.; Diekert, G. (1998). "Reductivedechlorination in the energy metabolism of anaerobic bacteria" (PDF). FEMS Microbiology...
Bank (HSDB) lists reductivedechlorination and incineration for field disposal of small quantities of endrin. In reductivedechlorination, endrin's chlorine...
majority of reductive dehalogenase activities lie within the extracellular and membranous components of D. ethenogenes, indicating that dechlorination processes...
attacked at their CF2 carbon by growing –CH2CF2∙ radical. After reductivedechlorination or debromination with tri-n-butyltin hydride they become a reversed...
anaerobic, motile, short curved rod that grows by coupling the reductivedechlorination of 2-chlorophenol to the oxidation of acetate. Sun, B.; Cole, J...
Majone, Mauro (2007). "Relevance of side reactions in anaerobic reductivedechlorination microcosms amended with different electron donors". Water Research...
cycle Chlorine gas poisoning Industrial gas Polymer degradation Reductivedechlorination van Helmont, Joannis Baptistae (1682). Opera omnia [All Works]...
important role in mortality reduction in these countries. Vietnam has enjoyed declining malaria cases and a 97% mortality reduction after switching in 1991...
energy, which is also the first stage of the degradation pathway, reductivedechlorination. Once the PCBs are dechlorinated to a certain degree, usually lower...
"Identification of a Bacterium That Specifically Catalyzes the ReductiveDechlorination of Polychlorinated Biphenyls with Doubly Flanked Chlorines". Applied...
"Desulfitobacterium sp. strain PCE1, an anaerobic bacterium that can grow by reductivedechlorination of tetrachloroethene or ortho-chlorinated phenols". Archives of...
aromatic hydrocarbons are most often degraded through a process of reductivedechlorination under anaerobic conditions. Polychlorinated biphenyls (PCBs) are...
that changes the chemistry of chloramines is used, it falls under reductivedechlorination. Other techniques use physical—not chemical—methods for removing...
degrade TCE. Dehalococcoides sp. degrade trichloroethylene by reductivedechlorination under anaerobic conditions. Under aerobic conditions, Pseudomonas...
tetrachloroethene reductive dehalogenase (EC 1.97.1.8) is an enzyme that catalyzes the chemical reaction. This is a member of reductive dehalogenase enzyme...
"Identification of a Bacterium That Specifically Catalyzes the ReductiveDechlorination of Polychlorinated Biphenyls with Doubly Flanked Chlorines". Applied...
catalysis of reductive dehalogenation of chlorinated compounds is dependent on the presence and expression of genes coding for reductive dehalogenase...
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