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Potassium oxide information


Potassium oxide
Potassium Oxide spacefilling model
Names
IUPAC name
potassium oxide
Systematic IUPAC name
potassium oxidopotassium
Other names
potash, dipotassium oxide
Identifiers
CAS Number
  • 12136-45-7 checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:88321
ChemSpider
  • 23354117 checkY
ECHA InfoCard 100.032.012 Edit this at Wikidata
EC Number
  • 235-227-6
MeSH Potassium+oxide
PubChem CID
  • 25520
UNII
  • 58D606078H checkY
UN number 2033
CompTox Dashboard (EPA)
  • DTXSID3049754 Edit this at Wikidata
InChI
  • InChI=1S/2K.O ☒N
    Key: NOTVAPJNGZMVSD-UHFFFAOYSA-N ☒N
SMILES
  • O([K])[K]
Properties
Chemical formula
K2O
Molar mass 94.196 g·mol−1
Appearance Pale yellow solid
Odor Odorless
Density 2.32 g/cm3 (20 °C)[1]
2.13 g/cm3 (24 °C)[2]
Melting point 740 °C (1,360 °F; 1,010 K)[2]
Solubility in water
Reacts[1] forming KOH
Solubility Soluble in diethyl ether[2]
Structure
Crystal structure
Antifluorite cubic, cF12[3]
Space group
Fm3m, No. 225[3]
Lattice constant
a = 6.436 Å[3]
α = 90°, β = 90°, γ = 90°
Coordination geometry
Tetrahedral (K+)
Cubic (O2−)
Thermochemistry
Heat capacity (C)
83.62 J/mol·K[4]
Std molar
entropy (S298)
94.03 J/mol·K[4]
Std enthalpy of
formation fH298)
−363.17 kJ/mol[1][4]
Gibbs free energy fG)
−322.1 kJ/mol[1]
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Corrosive, reacts violently with water
GHS labelling:
Pictograms
GHS05: Corrosive
Signal word
Danger
Hazard statements
H314
Precautionary statements
P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazard W: Reacts with water in an unusual or dangerous manner. E.g. sodium, sulfuric acid
3
0
1
W
Safety data sheet (SDS) ICSC 0769
Related compounds
Other anions
Potassium sulfide
Potassium selenide
Potassium telluride
Potassium polonide
Other cations
Lithium oxide
Sodium oxide
Rubidium oxide
Caesium oxide
Related potassium oxides
Potassium peroxide
Potassium superoxide
Potassium ozonide
Related compounds
Potassium hydroxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

Potassium oxide (K2O) is an ionic compound of potassium and oxygen. It is a base. This pale yellow solid is the simplest oxide of potassium. It is a highly reactive compound that is rarely encountered. Some industrial materials, such as fertilizers and cements, are assayed assuming the percent composition that would be equivalent to K2O.

  1. ^ a b c d Anatolievich, Kiper Ruslan. "potassium oxide". chemister.ru. Retrieved 2014-07-04.
  2. ^ a b c Lide, David R., ed. (2009). CRC Handbook of Chemistry and Physics (90th ed.). Boca Raton, Florida: CRC Press. ISBN 978-1-4200-9084-0.
  3. ^ a b c Wyckoff, Ralph W.G. (1935). The Structure of Crystals (2nd ed.). Reinhold Publishing Corp. p. 25. {{cite book}}: |work= ignored (help)
  4. ^ a b c Dipotassium oxide in Linstrom, Peter J.; Mallard, William G. (eds.); NIST Chemistry WebBook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg (MD) (retrieved 2014-07-04)

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Potassium oxide

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Potassium oxide (K2O) is an ionic compound of potassium and oxygen. It is a base. This pale yellow solid is the simplest oxide of potassium. It is a highly...

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Potassium peroxide

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the air, along with potassium oxide (K2O) and potassium superoxide (KO2). Potassium peroxide reacts with water to form potassium hydroxide and oxygen:...

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Ethylene oxide

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Ethylene oxide was first reported in 1859 by the French chemist Charles-Adolphe Wurtz, who prepared it by treating 2-chloroethanol with potassium hydroxide:...

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Potassium superoxide

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Potassium superoxide is an inorganic compound with the formula KO2. It is a yellow paramagnetic solid that decomposes in moist air. It is a rare example...

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Potassium hydroxide

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KOH attacks oxides. Thus, SiO2 is attacked by KOH to give soluble potassium silicates. KOH reacts with carbon dioxide to give potassium bicarbonate:...

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Basic oxide

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hydroxide: Na2O + H2O → 2 NaOH Potassium oxide reacts with water to produce potassium hydroxide: K2O + H2O → 2 KOH Rubidium oxide reacts with water to produce...

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Potash

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K2O equivalent, although fertilizer never contains potassium oxide, per se, because potassium oxide is caustic and hygroscopic. At the beginning of 2008...

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Potassium

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well studied: potassium oxide (K2O), potassium peroxide (K2O2), potassium superoxide (KO2) and potassium ozonide (KO3). The binary potassium-oxygen compounds...

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Ceramic flux

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used in clay bodies are potassium oxide and sodium oxide which are found in feldspars. A predominant flux in glazes is calcium oxide which is usually obtained...

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List of alkali metal oxides

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Potassium oxide (K2O) is a pale yellow solid that decomposes at 350 °C. Rubidium oxide (Rb2O) is a yellow solid that melts at 500 °C. Caesium oxide (Cs2O)...

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Monoxide

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instance, in the compound K2O, potassium (K) is a metal and therefore its proper name is potassium oxide, rather than potassium monoxide. Among monoxides,...

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Potassium nitrate

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with minimal water and using only the hot solution, then the use of potassium oxide (in the form of wood ashes) to remove calcium and magnesium by precipitation...

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Lead glass

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modern crystal glass, in which barium oxide, zinc oxide, or potassium oxide are employed instead of lead oxide. In the European Union, labelling of "crystal"...

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Sodium oxide

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Sodium oxide is a chemical compound with the formula Na2O. It is used in ceramics and glasses. It is a white solid but the compound is rarely encountered...

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List of inorganic compounds

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oxide – MgO Potassium oxide – K2O Rubidium oxide – Rb2O Sodium oxide – Na2O Strontium oxide – SrO Tellurium dioxide – TeO2 Uranium(IV) oxide – UO2 (only...

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Potassium bitartrate

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for wool, as a metal processing agent that prevents oxidation, as an intermediate for other potassium tartrates, as a cleaning agent when mixed with a weak...

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Potassium permanganate

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Potassium permanganate is an inorganic compound with the chemical formula KMnO4. It is a purplish-black crystalline salt, that dissolves in water as K+...

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Potassium ferrate

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Edmond Frémy (1814 – 1894) later discovered that fusion of potassium hydroxide and iron(III) oxide in air produced a compound that was soluble in water: 8...

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Perlite

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aluminium oxide: Al2O3 3–4% sodium oxide: Na2O 3–5% potassium oxide: K2O 0.5-2% iron oxide: Fe2O3 0.2–0.7% magnesium oxide: MgO 0.5–1.5% calcium oxide: CaO...

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Potassium nitrite

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O2}}} Potassium nitrite can be obtained by the reduction of potassium nitrate. The production of potassium nitrite by absorption of nitrogen oxides in potassium...

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Potassium sulfide

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water, a reaction that affords potassium hydrosulfide (KSH) and potassium hydroxide (KOH). Most commonly, the term potassium sulfide refers loosely to this...

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Potassium cyanide

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(NaAu(CN2)). Potassium cyanide is a potent inhibitor of cellular respiration, acting on mitochondrial cytochrome c oxidase, hence blocking oxidative phosphorylation...

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Potassium ferrocyanide

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obtained commercially from gasworks spent oxide (purification of city gas from hydrogen cyanide). Treatment of potassium ferrocyanide with nitric acid gives...

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Potassium hypomanganate

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+5 oxidation state. It is an intermediate in the production of potassium permanganate and the industrially most important Mn(V) compound. Potassium hypomanganate...

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Potassium dichromate

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Potassium dichromate, K2Cr2O7, is a common inorganic chemical reagent, most commonly used as an oxidizing agent in various laboratory and industrial applications...

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Silicon dioxide

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will neutralise basic metal oxides (e.g. sodium oxide, potassium oxide, lead(II) oxide, zinc oxide, or mixtures of oxides, forming silicates and glasses...

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Dehydrogenation

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dehydrogenation catalysts are based on iron(III) oxide, promoted by several percent potassium oxide or potassium carbonate. C6H5CH2CH3 → C6H5CH=CH2 + H2 The...

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Nitric oxide

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Nitric oxide (nitrogen oxide or nitrogen monoxide) is a colorless gas with the formula NO. It is one of the principal oxides of nitrogen. Nitric oxide is...

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Lamprophyre

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silica-undersaturated mafic or ultramafic rocks with high magnesium oxide, >3% potassium oxide, high sodium oxide, and high nickel and chromium. Lamprophyres occur throughout...

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