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Polyvinyl alcohol information


Polyvinyl alcohol
Names
Other names
PVOH; Poly(Ethenol), Ethenol, homopolymer; PVA; Polyviol; Vinol; Alvyl; Alcotex; Covol; Gelvatol; Lemol; Mowiol; Mowiflex, Alcotex, Elvanol, Gelvatol, Lemol, Nelfilcon A, Polyviol und Rhodoviol
Identifiers
CAS Number
  • 9002-89-5 checkY
ChEMBL
  • ChEMBL76101 ☒N
ChemSpider
  • none
ECHA InfoCard 100.121.648 Edit this at Wikidata
E number E1203 (additional chemicals)
KEGG
  • C00980 ☒N
RTECS number
  • TR8100000
UNII
  • 1E30GE2EF7 checkY
CompTox Dashboard (EPA)
  • DTXSID4031930 Edit this at Wikidata
Properties
Chemical formula
(C2H4O)x
Density 1.19–1.31 g/cm3
Melting point 200 °C (392 °F; 473 K)
log P 0.26 [1]
Refractive index (nD)
1.477 @ 632 nm[2]
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 0: Exposure under fire conditions would offer no hazard beyond that of ordinary combustible material. E.g. sodium chlorideFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
0
1
0
Flash point 79.44 °C (174.99 °F; 352.59 K)
Lethal dose or concentration (LD, LC):
LD50 (median dose)
14,700 mg/kg (mouse)
Safety data sheet (SDS) External MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

Polyvinyl alcohol (PVOH, PVA, or PVAl) is a water-soluble synthetic polymer. It has the idealized formula [CH2CH(OH)]n. It is used in papermaking, textile warp sizing, as a thickener and emulsion stabilizer in polyvinyl acetate (PVAc) adhesive formulations, in a variety of coatings, and 3D printing. It is colourless (white) and odorless. It is commonly supplied as beads or as solutions in water.[3][4] Without an externally added crosslinking agent, PVA solution can be gelled through repeated freezing-thawing, yielding highly strong, ultrapure, biocompatible hydrogels which have been used for a variety of applications such as vascular stents, cartilages, contact lenses, etc.[5]

Although polyvinyl alcohol is often referred to by the acronym PVA, more generally PVA refers to polyvinyl acetate, which is commonly used as a wood adhesive, sealer and water soluble plastic.

  1. ^ "Poly(vinyl alcohol)". ChemSrc.
  2. ^ Schnepf MJ, Mayer M, Kuttner C, et al. (July 2017). "Nanorattles with tailored electric field enhancement". Nanoscale. 9 (27): 9376–9385. doi:10.1039/C7NR02952G. hdl:10067/1447970151162165141. PMID 28656183.
  3. ^ Cite error: The named reference Ullmann was invoked but never defined (see the help page).
  4. ^ Tang X, Alavi S (2011). "Recent Advances in Starch, Polyvinyl Alcohol Based Polymer Blends, Nanocomposites and Their Biodegradability". Carbohydrate Polymers. 85: 7–16. doi:10.1016/j.carbpol.2011.01.030.
  5. ^ Adelnia, Hossein; Ensandoost, Reza; Shebbrin Moonshi, Shehzahdi; et al. (2022-02-05). "Freeze/thawed polyvinyl alcohol hydrogels: Present, past and future". European Polymer Journal. 164: 110974. doi:10.1016/j.eurpolymj.2021.110974. hdl:10072/417476. ISSN 0014-3057. S2CID 245576810.

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Polyvinyl alcohol

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Polyvinyl alcohol (PVOH, PVA, or PVAl) is a water-soluble synthetic polymer. It has the idealized formula [CH2CH(OH)]n. It is used in papermaking, textile...

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contain polyvinyl alcohol as a protective colloid. In alkaline conditions, boron compounds such as boric acid or borax cause the polyvinyl alcohol to cross-link...

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Vinyl alcohol

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hydrolysis kinetics. Because of the instability of vinyl alcohol, the thermoplastic polyvinyl alcohol (PVA or PVOH) is made indirectly by polymerization of...

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to many surfaces, toughness and flexibility. It is prepared from polyvinyl alcohol by reaction with butyraldehyde. The major application is laminated...

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This colorless liquid is the precursor to polyvinyl acetate, ethene-vinyl acetate copolymers, polyvinyl alcohol, and other important industrial polymers...

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Isopropyl alcohol is miscible in water, ethanol, and chloroform, as it is an organic polar molecule. It dissolves ethyl cellulose, polyvinyl butyral, many...

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commonly used in explosives and propellants. Polyvinyl nitrate was first synthesized by submersing polyvinyl alcohol (PVA) in a solution of concentrated sulfuric...

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exception from the usual rules, polyvinyl alcohol, (CH2CHOH)n, is produced by hydrolysis of polyvinyl acetate. Vinyl alcohol is not sufficiently stable to...

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Gypsum concrete

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and small amounts of various additives. Additives listed include polyvinyl alcohol, an extender such as sodium citrate or fly ash, a surfactant such...

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Formvar

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thermoplastic resins that are polyvinyl formals, which are polymers formed from polyvinyl alcohol and formaldehyde as copolymers with polyvinyl acetate. They are...

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silicone polymers), can be made by cross-linking polyvinyl alcohol with borax. Making flubber from polyvinyl acetate-based glues, such as Elmer's Glue, and...

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Polyvinyl chloride (alternatively: poly(vinyl chloride), colloquial: vinyl or polyvinyl; abbreviated: PVC) is the world's third-most widely produced synthetic...

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agent; heat can be used to speed up the reaction. Besides povidone, polyvinyl alcohol, starch derivatives (e.g. dextrin forming cadexomer iodine), chitosan...

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Acetate

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production is consumed in the production of vinyl acetate, precursor to polyvinyl alcohol, which is a component of many paints. The second largest use of acetic...

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Hydrogel

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alginate, gelatin and fibrin. Common synthetic polymers include polyvinyl alcohol, polyethylene glycol, sodium polyacrylate, acrylate polymers and copolymers...

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Enterobacter cloacae

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Rajkumar P, Ramya V, and Mohisha Miriam LR (2021). "Biorefining Polyvinyl Alcohol (PVA) by Enterobacter cloacae and its Polyhydroxy Butyrate (PHB) Production...

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Fiberglass molding

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finished. The mold release agent is a special wax, and/or PVA (Polyvinyl alcohol). Polyvinyl alcohol, however, is said to have negative effects on the final...

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Vinylon

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fiber produced from reaction between polyvinyl alcohol (PVA) fiber and formaldehyde. Chemically it is polyvinyl formal (PVF). Vinylon was first developed...

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Hysterectomy

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radiographic control into the uterine artery. A mass of microspheres or polyvinyl alcohol (PVA) material (an embolus) is injected into the uterine arteries...

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Polyvinylpolypyrrolidone

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number code E1202 and is used as a stabiliser. Polyethylene glycol-polyvinyl alcohol "Povidones, Copovidones, and Crospovidones for Pharmaceutical Products"...

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Electrospinning

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Photograph of a meniscus of polyvinyl alcohol in aqueous solution showing a fibre being electrospun from a Taylor cone....

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Sporopollenin

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structure of pitch pine sporopollenin, finding it primarily composed of polyvinyl alcohol units alongside other aliphatic monomers, all crosslinked through...

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