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Photochlorination information


Reaction scheme of the photochlorination of the methyl group of toluene

Photochlorination is a chlorination reaction that is initiated by light. Usually a C-H bond is converted to a C-Cl bond. Photochlorination is carried out on an industrial scale. The process is exothermic and proceeds as a chain reaction initiated by the homolytic cleavage of molecular chlorine into chlorine radicals by ultraviolet radiation. Many chlorinated solvents are produced in this way.

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Photochlorination

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Photochlorination is a chlorination reaction that is initiated by light. Usually a C-H bond is converted to a C-Cl bond. Photochlorination is carried out...

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Hexachlorocyclohexane

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chlorination of benzene under radical addition conditions (Cl2, hν (photochlorination) or Cl2, Δ, high P) yields hexachlorocyclohexane isomers after three...

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Oxalyl chloride

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Oxalyl chloride is produced commercially from ethylene carbonate. Photochlorination gives the perchloroethylene carbonate C2Cl4O2CO and hydrogen chloride...

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Organic photochemistry

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photoredox catalysis are some aminotrifluoromethylation reactions. Photochlorination is one of the largest implementations of photochemistry to organic...

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Ethylene carbonate

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Oxalyl chloride is produced commercially from ethylene carbonate. Photochlorination gives the tetrachloroethylene carbonate: C2H4O2CO + 4 Cl2 → C2Cl4O2CO...

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Vinylene carbonate

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stage, monochlorethylene carbonate is produced in a UV-initiated photochlorination reaction with chlorine or sulfuryl chloride at 60-70 °C in bulk. In...

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Nitrapyrin

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N2O emissions from the soil. Nitrapyrin is commonly produced by the photochlorination of 2-methylpyridine: CH3-C5H4N + 4Cl2 → CCl3-ClC5H3N + 4 HCl Nitrapyrin...

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Isobenzan

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5-Dihydrofuran was found. The target compound is then synthesized by photochlorination of the precursor. Isobenzan, International Programme on Chemical Safety...

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