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Vinylene carbonate information


Vinylene carbonate
Names
Preferred IUPAC name
2H-1,3-Dioxol-2-one
Other names
1,3-Dioxolene-2-one
Vinyl carbonate
Identifiers
CAS Number
  • 872-36-6 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 12812
ECHA InfoCard 100.011.659 Edit this at Wikidata
EC Number
  • 212-825-5
PubChem CID
  • 13385
UNII
  • 1X0ZZF9WFV checkY
CompTox Dashboard (EPA)
  • DTXSID1074888 Edit this at Wikidata
InChI
  • InChI=1S/C3H2O3/c4-3-5-1-2-6-3/h1-2H
    Key: VAYTZRYEBVHVLE-UHFFFAOYSA-N
SMILES
  • C1=COC(=O)O1
Properties
Chemical formula
C3H2O3
Molar mass 86.05 g·mol−1
Appearance colourless liquid[1]
Density 1.35
Melting point 22 °C (72 °F; 295 K)
Boiling point 178 °C (352 °F; 451 K)[2]
Hazards
GHS labelling:
Pictograms
GHS05: CorrosiveGHS06: ToxicGHS07: Exclamation markGHS08: Health hazardGHS09: Environmental hazard
Signal word
Danger
Hazard statements
H302, H311, H315, H317, H318, H373, H411
Precautionary statements
P260, P261, P264, P270, P272, P273, P280, P301+P312, P302+P352, P305+P351+P338, P310, P312, P314, P321, P322, P330, P332+P313, P333+P313, P361, P362, P363, P391, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Vinylene carbonate (VC) or 1,3-dioxol-2-one, is the simplest unsaturated cyclic carbonic acid ester. Vinylene carbonate can also be thought of as the cyclic carbonate of the hypothetical (Z)-ethene-1,2-diol. The activated double bond in this five-membered oxygen-containing heterocycle makes the molecule a reactive monomer for homopolymerization and copolymerization and a dienophile in Diels-Alder reactions. Below room temperature vinylene carbonate is a colorless stable solid.

  1. ^ Sigma-Aldrich Co., product no. {{{id}}}.
  2. ^ Haynes, W. M., ed. (2016). CRC Handbook of Chemistry and Physics (96th ed.). Boca Raton, Florida: CRC Press/Taylor & Francis. p. 3-228. ISBN 978-1482260960.

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