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Phosphorous acid information


Phosphorous acid
Wireframe model of phosphorous acid
Wireframe model of phosphorous acid
Ball and stick model of phosphorous acid
Ball and stick model of phosphorous acid
Names
IUPAC name
Phosphonic acid
Systematic IUPAC name
Phosphorous acid
Other names
Dihydroxyphosphine oxide

Dihydroxy(oxo)-λ5-phosphane
Dihydroxy-λ5-phosphanone
Orthophosphorous acid
Oxo-λ5-phosphanediol
Oxo-λ5-phosphonous acid

Metaphosphoroic acid
Identifiers
CAS Number
  • 13598-36-2 checkY
3D model (JSmol)
  • HP(O)(OH)2: Interactive image
  • P(OH)3: Interactive image
ChEBI
  • CHEBI:44976 checkY
ChEMBL
  • ChEMBL1235291
ChemSpider
  • 10449259 checkY
ECHA InfoCard 100.033.682 Edit this at Wikidata
EC Number
  • 237-066-7
Gmelin Reference
1619
KEGG
  • C06701 checkY
PubChem CID
  • 107909
RTECS number
  • SZ6400000
UNII
  • 35V6A8JW8E checkY
UN number 2834
CompTox Dashboard (EPA)
  • DTXSID2049715 Edit this at Wikidata
InChI
  • InChI=1S/H3O3P/c1-4(2)3/h4H,(H2,1,2,3) checkY
    Key: ABLZXFCXXLZCGV-UHFFFAOYSA-N checkY
  • InChI=1/H3O3P/c1-4(2)3/h4H,(H2,1,2,3)
    Key: ABLZXFCXXLZCGV-UHFFFAOYAF
SMILES
  • HP(O)(OH)2: OP(=O)O
  • P(OH)3: OP(O)O
Properties
Chemical formula
H3PO3
Molar mass 81.99 g/mol
Appearance white solid
deliquescent
Density 1.651 g/cm3 (21 °C)
Melting point 73.6 °C (164.5 °F; 346.8 K)
Boiling point 200 °C (392 °F; 473 K) (decomposes)
Solubility in water
310 g/100 mL
Solubility soluble in ethanol
Acidity (pKa) 1.1, 6.7
Magnetic susceptibility (χ)
−42.5·10−6 cm3/mol
Structure
Molecular shape
pseudo-tetrahedral
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
skin irritant
GHS labelling:[1]
Pictograms
GHS05: CorrosiveGHS07: Exclamation mark
Signal word
Danger
Hazard statements
H302, H314
Precautionary statements
P260, P264, P270, P280, P301+P312, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P330, P363, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
3
0
1
Safety data sheet (SDS) Sigma-Aldrich
Related compounds
Related compounds
H3PO4 (i.e., PO(OH)3)
H3PO2 (i.e., H2PO(OH))
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

Phosphorous acid (or phosphonic acid) is the compound described by the formula H3PO3. This acid is diprotic (readily ionizes two protons), not triprotic as might be suggested by this formula. Phosphorous acid is an intermediate in the preparation of other phosphorus compounds. Organic derivatives of phosphorous acid, compounds with the formula RPO3H2, are called phosphonic acids.

  1. ^ "Phosphorous acid". pubchem.ncbi.nlm.nih.gov.

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Phosphorous acid

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Phosphorous acid (or phosphonic acid) is the compound described by the formula H3PO3. This acid is diprotic (readily ionizes two protons), not triprotic...

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Phosphorous

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phosphorous acid, phosphorous anhydride) A common misspelling of the element name phosphorus Phosphorus All pages with titles containing Phosphorous Phosphorus...

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Hypophosphorous acid

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Anhydrous acid cannot be obtained by simple evaporation of the water, as the acid readily oxidises to phosphorous acid and phosphoric acid and also disproportionates...

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Hypophosphoric acid

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phosphorous acid/phosphoric acid mixed anhydride. The two phosphorus atoms are in the +3 and +5 oxidation states, respectively. Hypophosphoric acid can...

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Phosphorus

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commercially important, and three of them, hypophosphorous acid, phosphorous acid, and phosphoric acid, are particularly important. The PN molecule is considered...

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Acid strength

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Typical examples of weak acids include acetic acid and phosphorous acid. An acid such as oxalic acid ( HOOC − COOH {\displaystyle {\ce {HOOC-COOH}}} ) is...

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Phosphorus trioxide

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adamantane. It is formally the anhydride of phosphorous acid, H3PO3, but cannot be obtained by the dehydration of the acid. A white solid that melts at room temperature...

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Fungicide

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myclobutanil propiconazole dimethomorph polyoxins acibenzolar fosetyl-Al phosphorous acid Some of the most common fungal crop pathogens are known to suffer from...

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Phosphorus pentoxide

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point group. It is closely related to the corresponding anhydride of phosphorous acid, P4O6. The latter lacks terminal oxo groups. Its density is 2.30 g/cm3...

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Phosphite anion

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are reducing in character. The IUPAC recommended name for phosphorous acid is phosphonic acid. Correspondingly, the IUPAC-recommended name for the HPO2−...

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Phosphonate

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often prepared from) phosphorous acid. Phosphonate salts are the result of deprotonation of phosphonic acids, which are diprotic acids: RPO(OH)2 + NaOH →...

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Arsenous acid

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arsenous acid solutions consists of a single signal consistent with the molecule's high symmetry. In contrast, the nominally related phosphorous acid H3PO3...

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ATMP

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synthesized from the Mannich-type reaction of ammonia, formaldehyde, and phosphorous acid, in a manner similar to the Kabachnik–Fields reaction. ATMP has good...

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Phosphorus trichloride

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(POCl3). PCl3 reacts vigorously with water to form phosphorous acid (H3PO3) and hydrochloric acid: PCl3 + 3 H2O → H3PO3 + 3 HCl Phosphorus trichloride...

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Ester

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organyl isothiocyanates are not classified as esters by the IUPAC Phosphorous acid forms two types of esters: phosphite esters, e.g. triethyl phosphite...

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Phosphoric acid

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Phosphoric acid (orthophosphoric acid, monophosphoric acid or phosphoric(V) acid) is a colorless, odorless phosphorus-containing solid, and inorganic...

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Acid dissociation constant

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atom. This rule can help assign molecular structure: for example, phosphorous acid, having molecular formula H3PO3, has a pKa near 2, which suggested...

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Phosphite ester

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P(OR)3. They can be considered as esters of an unobserved tautomer phosphorous acid, H3PO3, with the simplest example being trimethylphosphite, P(OCH3)3...

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Diethylphosphite

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phosphonate form, (C2H5O)2P(O)H, a property it shares with its parent acid phosphorous acid. Nonetheless many of its reactions appear to proceed via the minor...

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Etidronic acid

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in a tertiary amine, or by reaction of an acetic acid/acetic anhydride mixture with phosphorous acid. Fischer J, Ganellin CR (2006). Analogue-based Drug...

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Orthocarbonic acid

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Orthocarbonic acid, carbon hydroxide, methanetetrol is the name given to a hypothetical compound with the chemical formula H4CO4 or C(OH)4. Its molecular...

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Hydroxide

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the elements in lower oxidation states are complicated. For example, phosphorous acid H3PO3 predominantly has the structure OP(H)(OH)2, in equilibrium with...

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Aminomethylphosphonic acid

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Biochemistry 31: 991-997 Backgrounder: Glyphosate does not degrade to phosphorous acid in the environment. Monsanto. 2005 Pesticide Residues in Food - 1997...

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Trimethyl phosphite

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Trimethyl phosphite is an organophosphorus compound with the formula P(OCH3)3, often abbreviated P(OMe)3. It is a colorless liquid with a highly pungent...

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Phosphorus tribromide

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and alcohols. PBr3 + 3 H2O → H3PO3 + 3 HBr In reactions that produce phosphorous acid as a by-product, when working up by distillation be aware that this...

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Phosphorus oxoacid

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hypophosphites or phosphinates. Phosphorous acid (or phosphonic acid), H 3PO 3 (or HPO(OH) 2), a diprotic acid (with only two acidic hydrogens). Its salts and...

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Oxyacid

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form (e.g., phosphorous acid P(OH)3 exists almost entirely as phosphonic acid HP(=O)(OH)2). Nevertheless, perchloric acid (HClO4), sulfuric acid (H2SO4),...

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Monopotassium phosphite

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consist of salts of the phosphite anion H2PO3−, the conjugate base of phosphorous acid. Phosphites of potassium are used as fungicides (in a loose sense)...

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Disodium hydrogen phosphite

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pentahydrate. A derivative of phosphorous acid (HP(O)(OH)2), it contains the anion HPO32−. Its common name suggests that it contains an acidic hydrogen atom, as in...

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Acidic oxide

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dioxide is the anhydride of silicic acid: H4SiO4 → 2 H2O + SiO2 Phosphorus(III) oxide reacts to form phosphorous acid in water: P4O6 + 6 H2O → 4 H3PO3 Phosphorus(V)...

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