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Monopotassium phosphite information


Monopotassium phosphite
Ball-and-stick model of the component ions
Ball-and-stick model of the component ions
Names
IUPAC name
Potassium hydrogen phosphonate
Other names
Potassium dihydrogen phosphite; Mono potassium phosphite; Monopotassium dihydrogen phosphite; Potassium phosphite monobasic
Identifiers
CAS Number
  • 13977-65-6 checkY
3D model (JSmol)
  • Interactive image
ECHA InfoCard 100.116.175 Edit this at Wikidata
PubChem CID
  • 23701737
UNII
  • 59RSS63D8J checkY
CompTox Dashboard (EPA)
  • DTXSID20884521 Edit this at Wikidata
InChI
  • InChI=1S/K.H2O3P/c;1-4(2)3/h;1-2H/q+1;-1
    Key: BZHCGFBZBPVRFE-UHFFFAOYSA-N
SMILES
  • OP(O)[O-].[K+]
Properties
Chemical formula
H2KO3P
Molar mass 120.085 g·mol−1
Appearance white crystals
Density 2.14 g/cm3
Solubility in water
2200 g/L
Solubility soluble in ethanol
Structure
Crystal structure
monoclinic
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Monopotassium phosphite is an inorganic compound with the formula KH2PO3. A compositionally related compound has the formula H3PO3.2(KH2PO3). Both are white solids that consist of salts of the phosphite anion H2PO3, the conjugate base of phosphorous acid.[1]

Phosphites of potassium are used as fungicides (in a loose sense) in agriculture to combat water mold infection. Confusingly, they have also been marketed as fertilizers to avoid a regulatory burden. While perfectly capable to supply potassium to the plant, the phosphorus in phosphite form is unavailable to plants, and may even inhibit the uptake of the normal phosphate form if used in excess.[2]

  1. ^ J. Loub (1991). "Crystal Chemistry of Inorganic Phosphites". Acta Crystallogr. B47: 468–473. doi:10.1107/S0108768191002380.
  2. ^ Thao; Yamakawa (2008). "Phosphite (phosphorous acid): Fungicide, fertilizer or bio-stimulator?". Soil Science and Plant Nutrition. 55 (2): 228–234. doi:10.1111/j.1747-0765.2009.00365.x. S2CID 95723306.

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Monopotassium phosphite

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Monopotassium phosphite is an inorganic compound with the formula KH2PO3. A compositionally related compound has the formula H3PO3.2(KH2PO3). Both are...

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Phosphite anion

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them as fungicides. A major form of inorganic phosphite used in agriculture is monopotassium phosphite. This compound does serve as a potassium fertilizer...

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Glossary of chemical formulae

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7773-03-7 KHSO4 potassium bisulfate 7646-93-7 KH2PO3 monopotassium phosphite KH2PO4 monopotassium phosphate KI potassium iodide 7681-11-0 KIO potassium...

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Boranophosphate

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Boranophosphates are salts with an anion consisting of borane (BH3) and phosphite groups. One of the simplest examples is [(CH3O)2OPBH3]−, prepared by base...

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