Periodinanes also known as λ5-iodanes are organoiodine compounds with iodine in the +5 oxidation state. These compounds are described as hypervalent because the iodine center has more than 8 valence electrons.
Periodinanes also known as λ5-iodanes are organoiodine compounds with iodine in the +5 oxidation state. These compounds are described as hypervalent because...
solution of chromium trioxide in aqueous sulfuric acid. The Dess–Martin periodinane is a mild oxidant for the conversion of alcohols to aldehydes or ketones...
oxidations, and hypervalent iodine compounds, such as the Dess–Martin periodinane. One disadvantage to the use of PCC is its toxicity, which it shares...
or a Cr(VI) compound. Milder conditions make use of the Dess–Martin periodinane or the Moffatt–Swern methods. Many other methods have been developed...
oxidation methods such as pyridinium chlorochromate (PCC) and Dess–Martin periodinane is that secondary alcohols are oxidized much faster than primary alcohols...
the hypervalent organoiodine compounds (i.e., IBX acid, Dess–Martin periodinane), although these often also oxidize the α position. A Lux-Flood acid...
applications ranging from organic synthesis to cloud seeding Dess–Martin periodinane chemical reagent used to oxidize primary alcohols to aldehydes and secondary...
his doctoral student Daniel Benjamin Dess, he invented the Dess–Martin periodinane that is used for selective oxidation of alcohols. He is also known for...
bidentate ligand and a tridentate analog, co-invented the Dess–Martin periodinane, creator of the Martin sulfurane Emil Wolfgang Menzel Jr. (Ph.D. 1958)...
memory-dependent prefetcher, part of some CPU architectures Dess–Martin periodinane, a chemical reagent used to oxidise alcohols Dot matrix printer, a type...
and explosive, but acetylation tempers it to the stabler Dess-Martin periodinane. Aliphatic hypoiodites can be synthesized through a variant on the Williamson...
compounds are useful reagents in organic chemistry (e.g. Dess–Martin periodinane) Tetra-, penta- and hexavalent phosphorus, silicon, and sulfur compounds...
the furanone is oxidized to 3-isopropylfuran-2,5-dione by Dess–Martin periodinane, followed by acetic acid reflux with beta-alanine. The white powdered...
to be used as the terminal oxidant. Compared to chromium-, DMSO-, or periodinane-mediated oxidations, this proves safe, environmentally-friendly, practical...
alcohol 8 which is subsequently oxidized to ketone 9 with Dess-Martin periodinane. Cyanophosphorylation with diethyl phosphorocyanidate (DEPC) modifies...
Organofluorine compounds Organochlorine compounds Organobromine compounds Iodanes Periodinanes Alex G. Fallis, Pierre E. Tessier, "2-Iodoxybenzoic acid (IBX)1" Encyclopedia...
Oxidation of the alcohol to the ketone 6 takes place with Dess-Martin periodinane in dichloromethane. The final step to 2-quinuclidonium tetrafluoroborate...
allowing the oxidation of the C4 alcohol to ketone 3.8 with the Dess-Martin periodinane. Diethylaluminum cyanide reacted in a conjugate addition to the enone...
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