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Orpiment information


Orpiment
Orpiment crystal from Twin Creeks Mine, Potosi District, Humboldt County, Nevada, United States (Size: 3.3 cm × 2.1 cm × 2.1 cm)
General
CategorySulfide mineral
Formula
(repeating unit)
As2S3
IMA symbolOrp[1]
Strunz classification2.FA.30
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupP21/n
Unit cella = 11.475(5), b = 9.577(4)
c = 4.256(2) [Å], β = 90.45(5)°; Z = 4
Identification
ColorLemon-yellow to golden or brownish yellow
Crystal habitCommonly in foliated columnar or fibrous aggregates; may be reniform or botryoidal; also granular or powdery; rarely as prismatic crystals
TwinningOn {100}
CleavagePerfect on {010}, imperfect on {100};
TenacitySectile
Mohs scale hardness1.5–2
LusterResinous, pearly on cleavage surface
StreakPale lemon-yellow
DiaphaneityTransparent
Specific gravity3.49
Optical propertiesBiaxial (−)
Refractive indexnα = 2.400 nβ = 2.810 nγ = 3.020
Birefringenceδ = 0.620
PleochroismIn reflected light, strong, white to pale gray with reddish tint; in transmitted light, Y = yellow, Z = greenish yellow
2V angleMeasured: 30° to 76°, Calculated: 62°
Dispersionr > v, strong
References[2][3][4]

Orpiment, also known as ″yellow arsenic blende″ is a deep-colored, orange-yellow arsenic sulfide mineral with formula As
2
S
3
. It is found in volcanic fumaroles, low-temperature hydrothermal veins, and hot springs and may be formed through sublimation.

Orpiment takes its name from the Latin auripigmentum (aurum, "gold" + pigmentum, "pigment"), due to its deep-yellow color. Orpiment once was widely used in artworks, medicine, and other applications. Because of its toxicity and instability, its usage has declined.

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (2005). "Orpiment" (PDF). Handbook of Mineralogy. Mineral Data Publishing. Retrieved 14 March 2022.
  3. ^ Orpiment, Mindat.org, retrieved 26 May 2022
  4. ^ Orpiment, WebMineral.com, retrieved 26 May 2022

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Orpiment

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Orpiment, also known as ″yellow arsenic blende″ is a deep-colored, orange-yellow arsenic sulfide mineral with formula As 2S 3. It is found in volcanic...

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Realgar

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compact, or powdery form, often in association with the related mineral, orpiment (As2S3). It is orange-red in color, melts at 320 °C, and burns with a bluish...

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Yellow

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in France has a painting of a yellow horse 17,000 years old. Ochre and orpiment pigments were used to represent gold and skin color in Egyptian tombs,...

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Arsenic blende

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ore minerals — orpiment and realgar,: 135, 239, 438  in composition — arsenic sulfides. Both of these minerals, realgar and orpiment, have been mined...

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Shades of yellow

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Paul A Dictionary of Color New York:1930 McGraw-Hill Page 201 (See under Orpiment [a synonym of the color name Royal Yellow] ); color sample of Royal Yellow:...

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Arsenic

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'the orpiment', based on Persian zar ("gold") from the word زرنيخ zarnikh, meaning "yellow" (literally "gold-colored") and hence "(yellow) orpiment". It...

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Rembrandt

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lake, azurite, ultramarine, yellow lake and lead-tin-yellow. Synthetic orpiment was shown in the shadows of the sleeve of the jewish groom. This toxic...

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Arsenic trisulfide

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yellow solid that is insoluble in water. It also occurs as the mineral orpiment (Latin: auripigmentum), which has been used as a pigment called King's...

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Arsenolite

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Commonly found as small octahedra it is white, but impurities of realgar or orpiment may give it a pink or yellow hue. It can be associated with its dimorph...

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Chemical depilatory

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discovered a chemical depilatory made from a mixture of lime and water and orpiment (arsenic trisulfide). "Hair Preparations", Ullmann's Encyclopedia of Industrial...

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Stibnite

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Stibnite occurs in hydrothermal deposits and is associated with realgar, orpiment, cinnabar, galena, pyrite, marcasite, arsenopyrite, cervantite, stibiconite...

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Pnictogen

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Greek Theophrastus recognized the arsenic minerals called realgar and orpiment. Elemental arsenic was discovered in the 13th century by Albertus Magnus...

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Arsenic sulfide

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Arsenic sulfide may refer to: Arsenic trisulfide, As2S3, the mineral orpiment Arsenic pentasulfide, As2S5, similar structure to phosphorus pentasulfide...

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Arsenopyrite

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and arsenic vapor. With 46% arsenic content, arsenopyrite, along with orpiment, is a principal ore of arsenic. When deposits of arsenopyrite become exposed...

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Champagne Pool

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siliceous geothermal fluid is oversaturated with metalloid compounds such as orpiment (As2S3) and stibnite (Sb2S3), which precipitate and form orange subaqueous...

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Nonmetal

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substances like salts, atramenta (iron sulfate), alums, vitriol, arsenic, orpiment, sulfur, and similar substances that were not metallic bodies. The term...

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Titian

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yellow, ochres, and azurite, he also used the rare pigments realgar and orpiment. Titian's wife, Cecilia, was a barber's daughter from his hometown village...

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List of mineral symbols

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Orl Otjisumeite Otj Oxynatromicrolite Onmic Offretite Off Omeiite Ome Orpiment Orp Ottemannite Ott Oxyphlogopite Ophl Oftedalite Oft Ominelite Omi Orschallite...

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List of alchemical substances

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silver till it liquefies and then cooling. King's yellow – formed by mixing orpiment with white arsenic. Lapis solaris (Bologna stone) – barium sulfide – 1603...

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Tempera

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pigments used by medieval painters, such as cinnabar (contains mercury), orpiment (contains arsenic), or lead white (contains lead) are highly toxic. Most...

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Toxic heavy metal

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recent examples (chromium and cadmium). Arsenic, as realgar (As 4S 4) and orpiment (As 2S 3), was known in ancient times. Strabo (64–50 BCE – c. AD 24?),...

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Hair removal

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paste consisted of an admixture of slaked lime, water, wood-ash and yellow orpiment (arsenic trisulfide); In rural India and Iran, where this mixture is called...

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Twin Creeks gold mine

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part of Twin Creek, was first identified in the 1980s. A rare specimen of orpiment discovered in the mine was donated to the Smithsonian. In 1911, the Battle...

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List of minerals

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Omphacite Oneillite Oosterboschite Oppenheimerite Ordóñezite Oregonite Orpiment Orthoclase Osarizawaite Osmium Osumilite Otavite Ottrelite Otwayite Varieties...

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Illuminated manuscript

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including: Ochre, an earth pigment that occurs as the mineral limonite; and Orpiment, chemically arsenic trisulfide, As2S3. Green Verdigris, chemically cupric...

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Sistine Madonna

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usual pigments of the renaissance period such as malachite mixed with orpiment in the green drapery on top of the painting, natural ultramarine mixed...

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Book of Kells

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it is a Mediterranean text and the pigments used in making it include orpiment, a yellow made from arsenic sulphide, exported from Italy, where it is...

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Reverse glass painting

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Orpiment Cinnabar Lead white Iron oxide earths Azurite Malachite Ultramarine blue Calm shell white Lead red Natural dyes...

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