In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing reduction and oxidation respectively. It was named after Walther Nernst, a German physical chemist who formulated the equation.[1][2]
^Orna, Mary Virginia; Stock, John (1989). Electrochemistry, past and present. Columbus, OH: American Chemical Society. ISBN 978-0-8412-1572-6. OCLC 19124885.
^Wahl (2005). "A Short History of Electrochemistry". Galvanotechtnik. 96 (8): 1820–1828.
In electrochemistry, the Nernstequation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction...
1920 Nobel Prize in Chemistry. He is also known for developing the Nernstequation in 1887. He studied physics and mathematics at the universities of...
respect to the standard hydrogen electrode (SHE) as calculated by the Nernstequation. The "H" stands for hydrogen, although other standards may be used...
chemical reaction producing the voltage. He constructed an equation, known as Nernstequation, which related the voltage of a cell to its properties. In...
global combined equation no longer contains electrons. The E h {\displaystyle E_{h}} and pH of a solution are related by the Nernstequation as commonly represented...
lower for more concentrated solutions. As the general form of the Nernstequation at equilibrium is the following: E cell = E cell ⊖ − R T z F ln K...
the equilibrium constant and reaction quotient for that reaction (Nernstequation), where ΔrG, Gibbs free energy change per mole of reaction, ΔrG°, Gibbs...
as well ". The Tafel equation can be also written as: where n is the number of electrons exchanged, like in the Nernstequation, k is the rate constant...
Functional equation Functional equation (L-function) Constitutive equation Laws of science Defining equation (physical chemistry) List of equations in classical...
since }}\ln 10\approx 2.303\end{aligned}}} which is the Nernstequation. Goldman's equation seeks to determine the voltage Em across a membrane. A Cartesian...
measure pH, respond to activity. The electrode potential, E, follows the Nernstequation for the hydrogen ion, which can be expressed as: E = E 0 + R T F ln...
in many fundamental equations in the physical sciences, such as the ideal gas law, the Arrhenius equation, and the Nernstequation. The gas constant is...
{\displaystyle \lim _{T\to 0}\Delta S=0} The above equation is a modern statement of the theorem. Nernst often used a form that avoided the concept of entropy...
This equation resembles the Nernstequation, but has a term for each permeant ion. Also, z has been inserted into the equation, causing the intracellular...
important equations that can determine membrane potential differences based on ion concentrations are the NernstEquation and the Goldman Equation. Neurons...
voltage is also important in plasmas and electrolyte solutions (e.g. the Nernstequation); in both cases it provides a measure of how much the spatial distribution...
concentration, the applied standard potential can be identified using the Nernstequation. There are three main shapes for voltammograms. The first shape is...
charged. Actual half-cell potentials must be calculated by using the Nernstequation as the solutes are unlikely to be in their standard states: E half-cell...
E_{{\ce {Hg2Cl2/Hg, Cl-}}}^{0}=+0.27\ {\ce {V}}.\\\end{cases}}} The Nernstequation for the balanced reaction is: E cell = E 1 2 cathode − E 1 2 anode...
from the cell was reduced as predicted using the Nernstequation for the model. The Nernstequation essentially says how much the voltage drops as more...
the difference of the electrode potentials as calculated using the Nernstequation. Applying additional voltage, referred to as overpotential, can increase...
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