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Molybdenum bronze information


In chemistry, molybdenum bronze is a generic name for certain mixed oxides of molybdenum with the generic formula A
x
Mo
y
O
z
where A may be hydrogen, an alkali metal cation (such as Li+, Na+, K+), and Tl+. These compounds form deeply coloured plate-like crystals with a metallic sheen, hence their name. These bronzes derive their metallic character from partially occupied 4d bands.[1] The oxidation states in K0.28MoO3 are K+1, O2−, and Mo+5.72. MoO3 is an insulator, with an unfilled 4d band.

These compounds have been much studied since the 1980s due to their markedly anisotropic electrical properties, reflecting their layered structure. The electrical resistivity can vary considerably depending on the direction, in some cases by 200:1 or more. They are generally non-stoichiometric compounds. Some are metals and some are semiconductors.

  1. ^ Cite error: The named reference Onoda was invoked but never defined (see the help page).

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Molybdenum bronze

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In chemistry, molybdenum bronze is a generic name for certain mixed oxides of molybdenum with the generic formula A xMo yO z where A may be hydrogen, an...

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Sodium tungsten bronze

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stability of the tungsten(V) cation that is formed. A similar family of molybdenum bronzes may have been discovered in 1885 by Alfred Stavenhagen and E. Engels...

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List of named alloys

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Chromel (chromium) Cupronickel (bronze, copper) Ferronickel (iron) German silver (copper, zinc) Hastelloy (molybdenum, chromium, sometimes tungsten) Inconel...

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Tungsten

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few species of bacteria and archaea. However, tungsten interferes with molybdenum and copper metabolism and is somewhat toxic to most forms of animal life...

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Galvanic series

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Steel 304 (passive) Silicon bronze Stainless Steel 316 (active) Monel 400 Phosphor bronze Admiralty brass Cupronickel Molybdenum Red brass Brass plating Yellow...

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Kajaran

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active sulfur. Molybdenum compounds decompose under high pressure to form an in-situ deposited layer of molybdenum disulfide. Molybdenum dithiocarbamates...

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Coinage metals

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antimony, carbon, cobalt, copper, gold, hafnium, iron, lead, magnesium, molybdenum, nickel, niobium, palladium, platinum, rhenium, silver, tantalum, tin...

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Plain bearing

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rulon, PEEK, urethane, and vespel (a high-performance polyimide). MDS (molybdenum disulfide) PEEK (polyether ether ketone) Igus, iglidur: Specially developed...

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arsenic, bismuth, cadmium, chromium, cobalt, indium, iron, manganese, molybdenum, nickel, niobium, rhenium, selenium, tantalum, tellurium, tin, titanium...

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Period 5 element

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lead that has no stable isotopes (along with promethium), as well as molybdenum and iodine, two of the heaviest elements with a known biological role...

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Sintering

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for materials with extremely high melting points, such as tungsten and molybdenum. The study of sintering in metallurgical powder-related processes is known...

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Sulfidation

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minerals. A large scale application of sulfidation is the conversion of molybdenum oxides to the corresponding sulfides. This conversion is a step in the...

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List of blade materials

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Getrag F23 transmission

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oxidize in air and water. The first tin alloy used on a large scale was bronze, made of 1⁄8 tin and 7⁄8 copper (12.5% and 87.5% respectively), from as...

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Steel

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steel. Common alloying elements include: manganese, nickel, chromium, molybdenum, boron, titanium, vanadium, tungsten, cobalt, and niobium. Additional...

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Galling

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like grease and oil, low-friction coatings and thin-film deposits like molybdenum disulfide or titanium nitride, and increasing the surface hardness of...

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Minoan eruption

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addition, a stalagmite from Turkey shows bromine peaks at 1621 ± 25 BCE, molybdenum at 1617 ± 25 BCE and sulfur at 1589 ± 25 BCE. The authors interpreted...

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Materials science

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with greater than 10% by weight alloying content of chromium. Nickel and molybdenum are typically also added in stainless steels. Other significant metallic...

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Brazing

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require flux for copper. Can be also used with silver, tungsten, and molybdenum. Copper-rich alloys prone to stress cracking by ammonia. Ag-Cu-P Like...

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