Isotope fractionation describes fractionation processes that affect the relative abundance of isotopes, phenomena which are taken advantage of in isotope geochemistry and other fields. Normally, the focus is on stable isotopes of the same element. Isotopic fractionation can be measured by isotope analysis, using isotope-ratio mass spectrometry or cavity ring-down spectroscopy to measure ratios of isotopes, an important tool to understand geochemical and biological systems. For example, biochemical processes cause changes in ratios of stable carbon isotopes incorporated into biomass.
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Isotopefractionation describes fractionation processes that affect the relative abundance of isotopes, phenomena which are taken advantage of in isotope...
expression stable-isotope ratio is preferably used to refer to isotopes whose relative abundances are affected by isotopefractionation in nature. This...
T in K Different researchers have also used other fractionation factors like dolomite fractionation factor. While measuring samples of unknown composition...
Fractionation is a separation process in which a certain quantity of a mixture (of gasses, solids, liquids, enzymes, or isotopes, or a suspension) is divided...
natural radioactivity. For most stable isotopes, the magnitude of fractionation from kinetic and equilibrium fractionation is very small; for this reason, enrichments...
and conditions that favor this fractionation. The table below summarizes the reported fractionations of oxygen isotopes from MSO in different organisms...
particular to describe isotopic enrichment or depletion as material moves between reservoirs in an equilibrium process. Rayleigh fractionation holds particular...
The isotopicfractionation of a natural process can be calculated from measured isotope abundances. The calculated value is called a "fractionation factor...
as polar ice or calcite in ocean core samples, measured with the isotopefractionation. The ratio is linked to ancient ocean temperature which in turn...
3-phosphoglyceraldehyde. Isotopefractionation due to Rubisco (form I) carboxylation alone is predicted to be a 28‰ depletion, on average. However, fractionation values...
Equilibrium isotopefractionation is the partial separation of isotopes between two or more substances in chemical equilibrium. Equilibrium fractionation is strongest...
49 (indium). A 2021 study has shown at high ionic strengths, Cd isotopefractionation mainly depends on its complexation with carboxylic sites. At low...
Kinetic fractionation is an isotopicfractionation process that separates stable isotopes from each other by their mass during unidirectional processes...
began, can generally be accounted for by mass fractionation (see the article on mass-independent fractionation) plus a limited number of nuclear decay and...
Martin J.; Jolis, Ester M.; Freda, Carmela (2016-08-04). "Boron isotopefractionation in magma via crustal carbonate dissolution". Scientific Reports...
S; Canfield, Donald E; Rethmeier, J̈org (August 1998). "Sulfur isotopefractionation during bacterial reduction and disproportionation of thiosulfate...
partial separation of isotopes between different pools is termed isotopefractionation, and is mathematically described by fractionation factors α or ε (which...
oil is also affected by the isotopefractionation from phase-change. However, the behavior of oil gas-liquid fractionation differs from water as the vapor...
carbonates shows little isotopicfractionation, while carbon in materials originated by photosynthesis is depleted of the heavier isotopes. In addition, there...
underwent hydrodynamic escape, which accounts for the noble gas isotopefractionation present in their atmospheres. Irwin, Patrick G. J. (2006). Giant...
be re-extracted. Calcium isotopefractionation during mineral formation has led to several applications of calcium isotopes. In particular, the 1997 observation...
minimal fractionation in evaporitic sulfate in association with magmatically derived sulfides can be seen in the rock record. This fractionation shows possible...
therefore isotopic effects cannot be described with the classical equilibrium fractionation equations or with steady-state kinetic fractionation equations...
adulteration. The combined use of isotope ratio mass spectrometry and SNIF-NMR (Site-Specific Natural IsotopeFractionation-Nuclear Magnetic Resonance) allows...