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Grain boundary information


Micrograph of a polycrystalline metal; grain boundaries evidenced by acid etching.
Differently-oriented crystallites in a polycrystalline material

In materials science, a grain boundary is the interface between two grains, or crystallites, in a polycrystalline material. Grain boundaries are two-dimensional defects in the crystal structure, and tend to decrease the electrical and thermal conductivity of the material. Most grain boundaries are preferred sites for the onset of corrosion[1] and for the precipitation of new phases from the solid. They are also important to many of the mechanisms of creep.[2] On the other hand, grain boundaries disrupt the motion of dislocations through a material, so reducing crystallite size is a common way to improve mechanical strength, as described by the Hall–Petch relationship.

  1. ^ Lehockey, E. M.; Palumbo, G.; Lin, P.; Brennenstuhl, A. M. (1997-05-15). "On the relationship between grain boundary character distribution and intergranular corrosion". Scripta Materialia. 36 (10): 1211–1218. doi:10.1016/S1359-6462(97)00018-3. ISSN 1359-6462.
  2. ^ Raj, R.; Ashby, M. F. (1971-04-01). "On grain boundary sliding and diffusional creep". Metallurgical Transactions. 2 (4): 1113–1127. Bibcode:1971MT......2.1113R. doi:10.1007/BF02664244. ISSN 1543-1916. S2CID 135851757.

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Grain boundary

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science, grain-boundary strengthening (or Hall–Petch strengthening) is a method of strengthening materials by changing their average crystallite (grain) size...

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Crystallite

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known as grain boundaries. Crystallite size in monodisperse microstructures is usually approximated from X-ray diffraction patterns and grain size by other...

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area of grain boundary. The term is commonly used in metallurgy but is also used in reference to ceramics and minerals. The behaviors of grain growth is...

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Sintering

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diffusion from grain boundary – atom from grain boundary diffuses through lattice grain boundary diffusion – atoms diffuse along grain boundary plastic deformation...

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Intergranular corrosion

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otherwise corrosion-resistant alloys, when the grain boundaries are depleted, known as grain boundary depletion, of the corrosion-inhibiting elements...

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Intergranular fracture

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occurs when a crack propagates along the grain boundaries of a material, usually when these grain boundaries are weakened. The more commonly seen transgranular...

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Coble creep

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and a sliding of the grain boundaries. Robert L. Coble first reported his theory of how materials creep across grain boundaries and at high temperatures...

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Strengthening mechanisms of materials

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creating physical barriers from second phase precipitates forming along grain boundaries. There are five main strengthening mechanisms for metals, each is a...

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Crystal structure

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Microstructural defects: Pores and crystallites tend to have straight grain boundaries following higher density planes. Cleavage: This typically occurs preferentially...

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Superalloy

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which reduces the grain boundary energy and results in better grain boundary cohesion and ductility. Another form of grain boundary strengthening is achieved...

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grain boundaries. The other process involves differences in stored strain energy between neighboring grains, resulting in migration of existing grain...

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deformation mechanisms processes include: § Fracturing § Cataclastic flow § Grain boundary sliding § Diffusive mass transfer § Dislocation creep § Dynamic recrystallization...

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Effective diffusion coefficient

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weighted average of the grain boundary diffusion coefficient and the lattice diffusion coefficient. Diffusion along both the grain boundary and in the lattice...

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Grain boundary diffusion coefficient

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The grain boundary diffusion coefficient is the diffusion coefficient of a diffusant along a grain boundary in a polycrystalline solid. It is a physical...

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Nanocrystalline material

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because an increase in grain boundary area results in increased grain boundary sliding. Chandross & Argibay modeled grain boundary sliding as viscous flow...

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Corrosion

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form in the grain boundaries of stainless alloys. This chemical reaction robs the material of chromium in the zone near the grain boundary, making those...

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Crystal

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and a grain boundary. Like a grain boundary, a twin boundary has different crystal orientations on its two sides. But unlike a grain boundary, the orientations...

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Paleostress inversion

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and local grain boundary bulging, and measuring recrystallized grain size. The nucleation process is triggered at boundaries of existing grains only when...

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Asthenosphere

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possible mechanism for producing mechanical weakness is grain boundary sliding, where grains slide slightly past each other under stress, lubricated by...

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Graphene

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the defects, such as grain-boundaries (GB) and vacancies, present in the system and the average grain-size. Graphene grain boundaries typically contain heptagon-pentagon...

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Fracture toughness

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elastic-plastic zone boundary, and then link back to the main crack tip. This is usually a mixture of cleavages of grains, and ductile fracture of grains known as...

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SAE 304 stainless steel

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chromium carbide results in reduced corrosion resistance along the grain boundary leaving the stainless steel susceptible to unanticipated corrosion in...

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