The Gibbs rotational ensemble represents the possible states of a mechanical system in thermal and rotational equilibrium at temperature and angular velocity .[1] The Jaynes procedure can be used to obtain this ensemble.[2] An ensemble is the set of microstates corresponding to a given macrostate.
The Gibbs rotational ensemble assigns a probability to a given microstate characterized by energy and angular momentum for a given temperature and rotational velocity .[1][3]
where is the partition function
^ abGibbs, Josiah Willard (2010) [1902]. Elementary Principles in Statistical Mechanics: Developed with Especial Reference to the Rational Foundation of Thermodynamics. Cambridge: Cambridge University Press. doi:10.1017/CBO9780511686948. ISBN 9781108017022.
^Thomson, Mitchell; Dyer, Charles C. (2012-03-29). "Black Hole Statistical Mechanics and The Angular Velocity Ensemble". arXiv:1203.6542 [gr-qc].
^Jaynes, Edwin Thompson; Heims, S.P. (1962). "Theory of Gyromagnetic Effects and Some Related Magnetic Phenomena". Reviews of Modern Physics. 34 (2): 143–165. Bibcode:1962RvMP...34..143H. doi:10.1103/RevModPhys.34.143.
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(link) Reguera, D.; Rubí, J.M. (2001), "Nonequilibrium translational-rotational effects in nucleation", The Journal of Chemical Physics, 115 (15): 7100–7106...
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written by Madeline Twomey, Ben Weisman and Elaine Wise, recorded by Georgia Gibbs, 1951. "Oklahoma Porch Song" – Brad Fielder, 2009. "Oklahoma Promise" –...
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advent of quantum mechanics. It leads to a difficulty known as the Gibbs paradox. Gibbs showed that in the equation Z = ξN, the entropy of a classical ideal...