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Chlorophyll b information


Chlorophyll b
Structure of β-Chlorophyll
Names
IUPAC name
Chlorophyll b
Systematic IUPAC name
Magnesium [methyl (3S,4S,21R)-14-ethyl-13-formyl-4,8,18-trimethyl-20-oxo-3-(3-oxo-3-{[(2E,7R,11R)-3,7,11,15-tetramethyl-2-hexadecen-1-yl]oxy}propyl)-9-vinyl-21-phorbinecarboxylatato(2-)-κ2N,N′]
Other names
β-Chlorophyll
Identifiers
CAS Number
  • 519-62-0 ☒N
3D model (JSmol)
  • Interactive image
ChemSpider
  • 16739843 checkY
ECHA InfoCard 100.007.522 Edit this at Wikidata
EC Number
  • 208-272-4
E number E140 (colours)
PubChem CID
  • 6450186
  • 11593175 (from spinach)
UNII
  • 5712ZB110R ☒N
CompTox Dashboard (EPA)
  • DTXSID70889349 Edit this at Wikidata
InChI
  • InChI=1S/C55H71N4O6.Mg/c1-12-38-35(8)42-27-43-36(9)40(23-24-48(61)65-26-25-34(7)22-16-21-33(6)20-15-19-32(5)18-14-17-31(3)4)52(58-43)50-51(55(63)64-11)54(62)49-37(10)44(59-53(49)50)28-46-39(13-2)41(30-60)47(57-46)29-45(38)56-42;/h12,25,27-33,36,40,51H,1,13-24,26H2,2-11H3,(H-,56,57,58,59,60,62);/q-1;+2/p-1/b34-25+;/t32-,33-,36+,40+,51-;/m1./s1 checkY
    Key: NSMUHPMZFPKNMZ-VBYMZDBQSA-M checkY
  • InChI=1S/C55H72N4O6.Mg/c1-12-38-35(8)42-27-43-36(9)40(23-24-48(61)65-26-25-34(7)22-16-21-33(6)20-15-19-32(5)18-14-17-31(3)4)52(58-43)50-51(55(63)64-11)54(62)49-37(10)44(59-53(49)50)28-46-39(13-2)41(30-60)47(57-46)29-45(38)56-42;/h12,25,27-33,36,40,51H,1,13-24,26H2,2-11H3,(H2,56,57,58,59,60,62);/q;+2/p-2/b34-25+;/t32-,33-,36+,40+,51-;/m1./s1
    Key: MSLKMRUEVOYOOZ-VBYMZDBQSA-L
SMILES
  • CCC1=C(C2=NC1=CC3=C(C4=C([C@@H](C(=C4[N-]3)C5=NC(=CC6=NC(=C2)C(=C6C)C=C)[C@H]([C@@H]5CCC(=O)OC/C=C(\C)/CCC[C@H](C)CCC[C@H](C)CCCC(C)C)C)C(=O)OC)[O-])C)C=O.[Mg+2]
Properties
Chemical formula
C55H70MgN4O6
Molar mass 907.492 g·mol−1
Appearance Green
Odor Odorless
Melting point ~ 125 °C (257 °F; 398 K)[1]
Solubility in water
Insoluble[1]
Solubility Very soluble in ethanol, ether, pyridine
Soluble in methanol[1]
Absorbance See text
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references
The absorption spectrum of both the chlorophyll a and the chlorophyll b pigments. The use of both together enhances the size of the absorption of light for producing energy.

Chlorophyll b is a form of chlorophyll. Chlorophyll b helps in photosynthesis by absorbing light energy. It is more soluble than chlorophyll a in polar solvents because of its carbonyl group. Its color is green, and it primarily absorbs blue light.[2]

In land plants, the light-harvesting antennae around photosystem II contain the majority of chlorophyll b. Hence, in shade-adapted chloroplasts, which have an increased ratio of photosystem II to photosystem I, there is a higher ratio of chlorophyll b to chlorophyll a.[3] This is adaptive, as increasing chlorophyll b increases the range of wavelengths absorbed by the shade chloroplasts.

Structure of chlorophyll b molecule showing the long hydrocarbon tail
  1. ^ a b c Lide, David R., ed. (2009). CRC Handbook of Chemistry and Physics (90th ed.). Boca Raton, Florida: CRC Press. ISBN 978-1-4200-9084-0.
  2. ^ "Photosynthesis pigments". Archived from the original on 2012-09-05. Retrieved 2011-01-13.
  3. ^ Kitajima, Kaoru; Hogan, Kevin P (2003). "Increases of chlorophyll a/b ratios during acclimation of tropical woody seedlings to nitrogen limitation and high light". Plant, Cell & Environment. 26 (6): 857–865. doi:10.1046/j.1365-3040.2003.01017.x. PMID 12803613.

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morphology. They are usually green due to the dominance of pigments chlorophyll a and chlorophyll b. The chloroplast may be discoid, plate-like, reticulate, cup-shaped...

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chlorophyll. Chlorophylls have a fifth, ketone-containing ring unlike the chlorins. Diverse chlorophylls exists, such as chlorophyll a, chlorophyll b...

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chlorophyll that gives plants their green color. All land plants and green algae possess two forms of this pigment: chlorophyll a and chlorophyll b....

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Prochlorococcus

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genes. Although there had been several earlier records of very small chlorophyll-b-containing cyanobacteria in the ocean, Prochlorococcus was discovered...

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is a special pair of chlorophyll molecules. Each PSII has about 8 LHCII. These contain about 14 chlorophyll a and chlorophyll b molecules, as well as...

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Photosynthesis

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Normalized difference vegetation index

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Photosynthetically active radiation

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of their pigments, they form colorful mats of green, red and purple. Chlorophyll, the most abundant plant pigment, is most efficient in capturing red...

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Chlorophyll synthase

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chlorophyll that gives plants their green color. All land plants and green algae possess two forms of this pigment: chlorophyll a and chlorophyll b....

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Prochlorophyta

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poor tropical waters and use a unique photosynthetic pigment, divinyl-chlorophyll, to absorb light and acquire energy. Prochlorophyta lack red and blue...

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