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Chloroauric acid information


Chloroauric acid
Names
Other names
  • Hydrogen tetrachloroaurate
  • Hydrogen tetrachloroaurate(III)
  • Chlorauric acid
  • Tetrachloroauric(III) acid
  • Aurochloric acid
  • Aurate(1−), tetrachloro-, hydrogen, (SP-4-1)-
  • Hydrogen aurichloride
  • brown gold chloride
Identifiers
CAS Number
  • 16903-35-8 checkY
  • 16961-25-4 (trihydrate) checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 26171 checkY
ECHA InfoCard 100.037.211 Edit this at Wikidata
EC Number
  • 240-948-4
PubChem CID
  • 28133
UNII
  • 8H372EGX3V checkY
  • 31KV0KH4AY (trihydrate) checkY
CompTox Dashboard (EPA)
  • DTXSID90156444 Edit this at Wikidata
InChI
  • InChI=1S/Au.4ClH/h;4*1H/q+3;;;;/p-3 checkY
    Key: VDLSFRRYNGEBEJ-UHFFFAOYSA-K checkY
  • InChI=1/Au.4ClH.Na/h;4*1H;/q+3;;;;;+1/p-4/rAuCl4.Na/c2-1(3,4)5;/q-1;+1
    Key: IXPWAPCEBHEFOV-ACHCXQQJAP
  • InChI=1/Au.4ClH/h;4*1H/q+3;;;;/p-3/rAuCl4/c2-1(3,4)5/q-1/p+1
    Key: VDLSFRRYNGEBEJ-ZXMCYSOYAI
SMILES
  • [H+].Cl[Au-](Cl)(Cl)Cl
Properties
Chemical formula
H[AuCl4]
Molar mass
  • 339.785 g/mol (anhydrous)
  • 393.833 g/mol (trihydrate)
  • 411.85 g/mol (tetrahydrate)
Appearance orange-yellow needle-like hygroscopic crystals
Density 3.9 g/cm3 (anhydrous)
2.89 g/cm3 (tetrahydrate)
Melting point 254 °C (489 °F; 527 K) (decomposes)
Solubility in water
350 g of H[AuCl4] in 100 g of H2O
Solubility soluble in alcohol, ester, ether, ketone
log P 2.67510 [1]
Conjugate base Tetrachloroaurate(III)
Structure
Crystal structure
monoclinic
Hazards
GHS labelling:
Pictograms
GHS05: CorrosiveGHS07: Exclamation markGHS08: Health hazardGHS09: Environmental hazard
Signal word
Danger
Hazard statements
H302, H314, H317, H373, H411
Precautionary statements
P260, P261, P264, P272, P280, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P333+P313, P363, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
3
0
1
Safety data sheet (SDS) JT Baker
Related compounds
Other anions
Tetrabromoauric acid
Related compounds
Gold(III) chloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Chloroauric acid is an inorganic compound with the chemical formula H[AuCl4]. It forms hydrates H[AuCl4nH2O. Both the trihydrate and tetrahydrate are known. Both are orange-yellow solids consisting of the planar [AuCl4] anion. Often chloroauric acid is handled as a solution, such as those obtained by dissolution of gold in aqua regia. These solutions can be converted to other gold complexes or reduced to metallic gold or gold nanoparticles.

  1. ^ "hydrogen tetrachloroaurate(iii)_msds".

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Chloroauric acid

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Chloroauric acid is an inorganic compound with the chemical formula H[AuCl4]. It forms hydrates H[AuCl4]·nH2O. Both the trihydrate and tetrahydrate are...

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Aqua regia

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(red fume): 2 NO + O2 → 2 NO2 Aqua regia is primarily used to produce chloroauric acid, the electrolyte in the Wohlwill process for refining the highest purity...

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Nitric acid

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used in combination with hydrochloric acid as aqua regia to dissolve noble metals such as gold (as chloroauric acid). These salts can be used to purify...

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Wohlwill process

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electrolyte of chloroauric acid. Gold and other metals are dissolved at the anode, and pure gold (coming through the chloroauric acid by ion transfer)...

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Nitratoauric acid

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is produced by the addition of ammonium nitrate to a solution of chloroauric acid. The hydrolysis of this compound produces fulminating gold. "Gold Nitrate"...

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Gold compounds

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ions are removed from the equilibrium by hydrochloric acid, forming AuCl−4 ions, or chloroauric acid, thereby enabling further oxidation. 2 Au + 6 H 2 SeO...

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Tetrabromoauric acid

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Tetrabromoauric acid is an inorganic compound with the formula H[AuBr4]. It is the bromide analog of chloroauric acid. It is generated analogously, by...

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Colloidal gold

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the gold ions to gold metal. The gold ions usually come from chloroauric acid, a potent acid. Because of the high toxicity and hazard of reagents used to...

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Purple of Cassius

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with a solution of tin(II) chloride. The tin(II) chloride reduces the chloroauric acid from the dissolution of gold in aqua regia to a colloid of elemental...

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Miller process

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because it does not tie up the large amount of gold in the form of chloroauric acid which the Wohlwill process permanently requires for the electrolyte...

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Gold chloride

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Gold(III) chloride (gold trichloride, digold hexachloride), Au2Cl6 Chloroauric acid, HAuCl4 (brown gold chloride); or its sodium salt, sodium tetrachloroaurate...

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Gold parting

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the cathode (or titanium as a starter cathode) and chloroauric acid (gold chloride-hydrochloric acid) as the electrolyte; this is made by dissolving gold...

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Gold

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ions are removed from the equilibrium by hydrochloric acid, forming AuCl−4 ions, or chloroauric acid, thereby enabling further oxidation: 2 Au + 6 H 2 SeO...

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Mining

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Chemical Society. The new method "converts gold-containing ore into chloroauric acid and extracts it using an industrial solvent. The container molecules...

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Brown gold

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made out of cocoa beans Brown coal, lignite Colored gold Old gold Chloroauric acid Golden brown Golden brown (colour) Brown (disambiguation) Gold (disambiguation)...

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Organogold chemistry

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simple complexes, including gold(I) chloride, gold(III) chloride, and chloroauric acid, have been employed as complexes. These gold sources, however, quickly...

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Gold nanocage

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over 150 nm. They are created by reacting silver nanoparticles with chloroauric acid (HAuCl4) in boiling water. Whereas gold nanoparticles absorb light...

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