Benzylidene compounds are, formally speaking, derivatives of benzylidene, although few are prepared from the carbene. Benzylidene acetal is a protecting group in synthetic organic chemistry of the form PhCH(OR)2. For example, 4,6-O-benzylidene-glucopyranose is a glucose derivative. Benzylidene is an archaic term for compounds of the type PhCHX2 and PhCH= substituents (Ph = C6H5). For example, dibenzylideneacetone is (PhCH=CH)2CO. Benzal chloride, PhCHCl2, is alternatively named benzylidene chloride.
Benzylidene is the molecule C6H5CH. It is a triplet carbene (CAS RN 3101-08-4). It is generated by irradiation of phenyldiazomethane.[1]
^Platz, Matthew S. (1995). "Comparison of Phenylcarbene and Phenylnitrene". Accounts of Chemical Research. 28 (12): 487–92. doi:10.1021/ar00060a004.
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Benzylidenecompounds are, formally speaking, derivatives of benzylidene, although few are prepared from the carbene. Benzylidene acetal is a protecting...
organic chemistry, a benzylidene acetal is the functional group with the structural formula C6H5CH(OR)2 (R = alkyl, aryl). Benzylidene acetals are used as...
refers to compounds of type R1R2C(OR)(NR'2) (R,R' ≠ H) also known as a hemiaminal ether or Aminal, a.k.a. aminoacetal. S,S-acetal refers to compounds of type...
(Z)-configurations. The molecule contains a benzofuran element associated with a benzylidene linked in position 2. In aurone, a chalcone-like group is closed into...
Benzal chloride is an organic compound with the formula C6H5CHCl2. This colourless liquid is a lachrymator and is used as a building block in organic synthesis...
the scope of condensation reactions to construct new, complex organic compounds. Benzylideneacetone is used as a flavouring ingredient in food and perfumes...
groups codependently as an acetal. Common in this situation are the benzylidene, isopropylidene and cyclohexylidene or cyclopentylidene acetals. An exceptional...
acid. With diols, including many sugars, benzaldehyde condenses to form benzylidene acetals. Benzaldehyde is commonly employed to confer almond flavor to...
Alcohols, chemical compounds with at least one hydroxyl group Triols, chemical compounds with three hydroxyl groups Polyols, chemical compounds with multiple...
Ph3CCl·AlCl3 Ph3CCl·AlCl3 + HCl → Ph3CH It can also be synthesized from benzylidene chloride, which is prepared from benzaldehyde and phosphorus pentachloride...
formulation (inorganic compounds or organic molecules) as: Mineral sunscreens (also referred to as physical), which use only inorganic compounds (zinc oxide and/or...
Plinabulin Names IUPAC name (3Z,6Z)-3-Benzylidene-6-{[5-(2-methyl-2-propanyl)-1H-imidazol-4-yl]methylene}-2,5-piperazinedione Identifiers CAS Number 714272-27-2 Y...
the second-generation catalyst. In the Hoveyda–Grubbs catalysts, the benzylidene ligands have a chelating ortho-isopropoxy group attached to the benzene...
The benzylidene derivatives serve as synthetic intermediates for 6-Alkyl-3-benzyltropanes and have not been assayed for biological activity. Compounds 237a...
dicamphor sulfonic acid) is an organic compound which is added to many sunscreens to filter out UVA rays. It is a benzylidene camphor derivative, many of which...
a partial list of molecules that contain 9 carbon atoms. Carbon number List of compounds with carbon number 8 List of compounds with carbon number 10...
and Co Inc. US 3647858, Conn JB, Hinkley DF, "Process for preparing 1-benzylidene-3-indenyl acetic acids", issued 7 March 1972, assigned to Merck and Co...
; Akiyama, M.; Sato, S.; Ogasawara, K. (1983). "A Facile Cleavage of Benzylidene Acetals with Diisobutylaluminum Hydride" (pdf). Chemistry Letters. 12...
receptor modulator ponesimod in humans". Xenobiotica; the Fate of Foreign Compounds in Biological Systems. 45 (2): 139–149. doi:10.3109/00498254.2014.955832...
promising inhibitors are 2,6-dihydroxipyridine-4-carboxylic acid and 3-benzylidene-2,6-dioxo-1,2,3,6-tetrahydropyridine-4-carboxylic acid. Union enthalpy...
12.059 Unprecedented regio and stereocontrol in Povarov reaction of benzylidene-(3-nitrophenyl)amine Paul J. Stevenson and Isla Graham Arkivoc AM-717D...
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