Atranes are a class of tricyclic molecules with three five-membered rings. It is a heterocyclic structure similar to the propellanes. It has a transannular dative bond from a nitrogen at one bridgehead to a Lewis acidic atom such as silicon or boron at the other bridgehead.[1] The name "atrane" was first proposed by Mikhail Grigorievich Voronkov [ru].[1]
^ abVoronkov, Mikhail G.; Baryshok, Viktor P. "Atranes - a new generation of biologically active substances" (in Russian) Vestnik Rossiiskoi Akademii Nauk 2010, volume 80, 985-992.
Atranes are a class of tricyclic molecules with three five-membered rings. It is a heterocyclic structure similar to the propellanes. It has a transannular...
non-bonding molecular groups in a large ring or macrocycle. See for example atranes. IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997)...
of a transannular P-N bond. The product exemplifies the structure of an atrane. The conjugate acid [HP(MeNCH2CH2)3N]+ of the base has a pKa of 32.9 in...
stannatrane (IUPAC: 1-aza-5-stannabicyclo[3.3.3]undecane) is a tin-based atrane belonging to the larger class of organostannanes. Though the term stannatrane...
and French anthropologist Atran, an organisation in the Ability webcomic Atrane, a heterocyclic organic compound Atrans, the Roman name for Trojane, a town...
/12 on the feast of (the month) Alsasa nac atranes zila /13 cal sel eita la acnašv/14ers when the atranes of the magistrate (was??) (the) great acnasvers...
1-(4-Chlorophenyl)silatrane is an extremely toxic organosilicon compound which was developed by M&T Chemicals as a single-dose rodenticide. It was never...
4517–4527. doi:10.1021/ic302819j. PMID 23517123. Verkade, J. G. (1993). "Atranes: New Examples with Unexpected Properties". Acc. Chem. Res. 26 (9): 483...
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