Motifs for complexation of tri- and tetradentate tripodal ligands
Tripodal ligands are tri- and tetradentate ligands. They are popular in research in the areas of coordination chemistry and homogeneous catalysis. Because the ligands are polydentate, they do not readily dissociate from the metal centre. Many tripodal ligands have C3 symmetry.
such as RC(CH2PPh2)3 are also tripodal. Many kinds of donor groups have been incorporated into the arms of tripodalligands, including amido (R2N−), and...
Common forms are linear (also called sequential), ring or tripodal. A tetrapodal ligand that is also tetradentate has four legs with donor atoms and...
complexes there are two enantiomers, mirror images of each other. Tripodalligand Cotton, F. Albert; Wilkinson, Geoffrey (1966). Advanced Inorganic Chemistry...
While many scorpionate ligands are of the Tp class, many other scorpionate ligands are known. For example, the Tm and tripodal phosphine classes have...
The trispyrazolylborate ligand, abbreviated Tp−, is an anionic tridentate and tripodalligand. Trispyrazolylborate refers specifically to the anion [HB(C3N2H3)3]−...
alkyne metathesis catalysts The so-called "canopy catalysts" containing tripodalligands are particularly active and easy to prepare. Thorough experimental...
Triethanolamine, or TEOA, is an organic compound with the chemical formula N(CH2CH2OH)3. It is a colourless, viscous liquid. It is both a tertiary amine...
TmMe anion is a tridentate, tripodalligand topologically similar to the more common Tp ligands, but the two classes of ligands differ in several ways. TmMe...
hexadentate ligand in coordination chemistry is a ligand that combines with a central metal atom with six bonds. One example of a hexadentate ligand that can...
oxidation of triethanolamine. The conjugate base of NTA is a tripodal tetradentate trianionic ligand, forming coordination compounds with a variety of metal...
forms the complex [Zn(terpy)Cl2]. Another example would involve a tripodalligand such as Tris(2-aminoethyl)amine. Square pyramidal 5-coordinate Zinc...
Solution Properties of the Lanthanide Complexes of a New Heptadentate TripodalLigand: A Route to Gadolinium Complexes with an Improved Relaxation Efficiency"...
ligand's topology and the geometry of the metal center. For octahedral metals, the linear tetradentate trien can bind via three geometries. Tripodal tetradentate...
the ligands and the catalytic activity of their complexes, with C3 symmetric ligands often being better for asymmetric catalysis. Suitable tripodal compounds...
the Hydrolysis and Condensation of Titanium Alkoxides Complexed by TripodalLigands". Journal of the Chemical Society, Dalton Transactions (16): 2425–2428...
property of the terbium nitrate supramolecular complex with an amide-type tripodalligand]. Acta Chimica Sinica (in Chinese). 64 (5): 444–448. Curzon A.E.; Chlebek...
Studies of Uranium(III) and Lanthanum(III) Complexes with a Neutral Tripodal N-Donor Ligand Suggesting the Presence of a U−N Back-Bonding Interaction". Inorganic...
highly conserved sequence in roughly three quarters of all ORs that is a tripodal metal ion binding site, and Suslick has proposed that the ORs are in fact...
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