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Ammonium bifluoride information


Ammonium bifluoride
Space fill model of the ammonium cation
Space fill model of the ammonium cation
Space fill model of the bifluoride anion
Space fill model of the bifluoride anion
Sample of Ammonium bifluoride
Names
IUPAC name
Ammonium bifluoride
Other names
  • Ammonium acid fluoride
  • Ammonium hydrofluoride
  • Ammonium difluoride
  • Ammonium hydrogendifluoride
  • Ammonium hydrogen difluoride
Identifiers
CAS Number
  • 1341-49-7 checkY
3D model (JSmol)
  • Interactive image
  • Interactive image
ChemSpider
  • 21241205 ☒N
ECHA InfoCard 100.014.252 Edit this at Wikidata
EC Number
  • 215-676-4
PubChem CID
  • 14935
UNII
  • C2M215358O
UN number 1727
CompTox Dashboard (EPA)
  • DTXSID9029645 Edit this at Wikidata
InChI
  • InChI=1S/F2H.H3N/c1-3-2;/h;1H3/q-1;/p+1 ☒N
    Key: XIONBZYFLSJNBW-UHFFFAOYSA-O ☒N
  • InChI=1/2FH.H3N/h2*1H;1H3
    Key: KVBCYCWRDBDGBG-UHFFFAOYAG
SMILES
  • [NH4+].F[H-]F
  • [F-].F.[NH4+]
Properties
Chemical formula
[NH4][HF2]
Molar mass 57.044 g·mol−1
Appearance Colourless crystals
Density 1.50 g cm−3
Melting point 126 °C (259 °F; 399 K)
Boiling point 240 °C (464 °F; 513 K)(decomposes)
Solubility in water
63g/(100 ml) (20 °C)
Solubility in alcohol slightly soluble
Refractive index (nD)
1.390
Structure
Crystal structure
Cubic, related to the CsCl structure
Coordination geometry
[NH4]+ cation: tetrahedral
[HF2] anion: linear
Hazards
GHS labelling:
Pictograms
GHS05: CorrosiveGHS06: Toxic[1]
Hazard statements
H301, H314[1]
Precautionary statements
P280, P301+P310, P305+P351+P338, P310[1]
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
3
0
0
Related compounds
Other cations
potassium bifluoride
Related compounds
ammonium fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

Ammonium bifluoride is the inorganic compound with the formula [NH4][HF2] or [NH4]F·HF. It is produced from ammonia and hydrogen fluoride. This colourless salt is a glass-etchant and an intermediate in a once-contemplated route to hydrofluoric acid.

  1. ^ a b c Sigma-Aldrich Co., Ammonium bifluoride. Retrieved on 2013-07-20.

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Ammonium bifluoride

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Ammonium bifluoride is the inorganic compound with the formula [NH4][HF2] or [NH4]F·HF. It is produced from ammonia and hydrogen fluoride. This colourless...

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Bifluoride

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bond (symmetrical hydrogen bond). Salts, such as potassium bifluoride and ammonium bifluoride are produced by treating fluoride salts with hydrofluoric...

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Potassium bifluoride

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electrolysis of K[HF2] was first used by Henri Moissan in 1886. Ammonium bifluoride Bifluoride anion Westrum, Edgar F. Jr.; Pitzer, Kenneth S. (June 1949)...

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Ammonium fluoride

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gas (in excess) through the salt, ammonium fluoride absorbs the gas to form the addition compound ammonium bifluoride. The reaction occurring is: NH4F...

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Laundry sour

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fabrics. Most such sours are fluoride-based, including ammonium silicofluoride, ammonium bifluoride, and hydrofluosilicic acid; glycolic acid is also used...

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Fluoride

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doi:10.1177/00220345990780091201. PMID 10512392. S2CID 32650790. "Ammonium bifluoride in the glass industry - Chimex Ltd". Wikimedia Commons has media...

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MXenes

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that contain a fluoride ion (F−), such as hydrofluoric acid (HF), ammonium bifluoride (NH4HF2), and a mixture of hydrochloric acid (HCl) and lithium fluoride...

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Sodium bifluoride

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Sodium bifluoride is the inorganic compound with the formula Na[HF2]. It is a salt of sodium cation (Na+) and bifluoride anion ([HF2]−). It is a white...

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Difluoride

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difluoride The bifluorides contain the two fluorine atoms in a covalently bound HF2− polyatomic ion rather than as F− anions. Ammonium bifluoride Potassium...

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Beryllium

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voluntary consensus standard, ASTM D7202. The procedure uses dilute ammonium bifluoride for dissolution and fluorescence detection with beryllium bound to...

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Ammonium hexafluorozirconate

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Ammonium hexafluorozirconate is a complex inorganic compound of nitrogen, hydrogen, fluorine, and zirconium with the chemical formula (NH4)2ZrF6. Ammonium...

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Fluoride toxicity

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Other sources include glass-etching or chrome-cleaning agents like ammonium bifluoride or hydrofluoric acid, industrial exposure to fluxes used to promote...

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ABF

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high school Bergen County Academies in New Jersey, United States Ammonium bifluoride Amorphous brazing foil Applications-By-Forms, a component of CA-OpenIngres...

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Magnesium fluoride

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hydrogen fluoride such as can be obtained from the breakdown of ammonium bifluoride: MgO + [NH4]HF2 → MgF2 + NH3 + H2O Related metathesis reactions are...

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Beryllium oxide

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dissolves easily in hot aqueous ammonium bifluoride (NH4HF2) or a solution of hot concentrated sulfuric acid (H2SO4) and ammonium sulfate ((NH4)2SO4). BeO crystallizes...

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Zirconium tetrafluoride

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4 HF → ZrF4 + 2 H2 Zirconium dioxide reacts at 200 °C with solid ammonium bifluoride to give the heptafluorozirconate salt, which can be converted to...

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Beryllium fluoride

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ores generates impure Be(OH)2. This material reacts with ammonium bifluoride to give ammonium tetrafluoroberyllate: Be(OH)2 + 2 (NH4)HF2 → (NH4)2BeF4 +...

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ZBLAN

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substitution. Further experimental work led to major advances. First, ammonium bifluoride processing replaced the initial preparation method based on heat...

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Ammonium fluorosilicate

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Ammonium fluorosilicate (also known as ammonium hexafluorosilicate, ammonium fluosilicate or ammonium silicofluoride) has the formula (NH4)2SiF6. It is...

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Scandium fluoride

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extraction from the ore thortveitite by the reaction of Sc2O3 with ammonium bifluoride at high temperature: Sc2O3 + 6 NH4HF2 → 2 ScF3 + 6 NH4F + 3 H2O The...

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Hydrogen fluoride

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fluorine, F2, by electrolysis of a solution of HF and potassium bifluoride. The potassium bifluoride is needed because anhydrous HF does not conduct electricity...

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Tetramethylammonium fluoride

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with a metal atom. Most other soluble salts of fluoride are in fact bifluorides, HF2–. Historically, there have been two main approaches to prepare...

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Ammonium hexafluorotitanate

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Ammonium hexafluorotitanate is the inorganic compound with the chemical formula (NH4)2[TiF6]. A colorless salt, the compound consists of ammonium ions...

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Potassium heptafluorotantalate

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method involves the reaction of tantalum oxide with potassium bifluoride or ammonium bifluoride according to the following equation: Ta2O5 + 4 KHF2 + 6 HF...

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Lithium fluoride

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absorb hydrogen fluoride to form a bifluoride salt. Fluorine is produced by the electrolysis of molten potassium bifluoride. This electrolysis proceeds more...

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Nitrogen pentafluoride

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with CsF in HF solvent at 20 °C. However, a variant, tetrafluoroammonium bifluoride (NF4HF2·nHF), was produced. At room temperature it was a milky liquid...

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List of inorganic compounds

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Ammonia – NH3 Ammonium azide – [NH4]N3 Ammonium bicarbonate – [NH4]HCO3 Ammonium bisulfate – [NH4]HSO4 Ammonium bromide – NH4Br Ammonium chromate – [NH4]2CrO4...

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