Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
Acetone oxime (acetoxime) is the organic compound with the formula (CH3)2CNOH. It is the simplest example of a ketoxime. It is a white crystalline solid that is soluble in water, ethanol, ether, chloroform, and ligroin. It is used as a reagent in organic synthesis.[2]
Acetone oxime (acetoxime) was first prepared and named in 1882 by the German chemist Victor Meyer and his Swiss student Alois Janny.[3]
^Sigma-Aldrich Chemical Catalogue "Acetone Oxime". Retrieved 2 September 2016.
^Steven M. Weinreb, Kristina Borstnik "Acetone Oxime" e-EROS Encyclopedia of Reagents for Organic Synthesis, 2007. doi:10.1002/047084289X.rn00765
^Meyer, Victor; Janny, Alois (1882). "Ueber die Einwirkung von Hydroxylamin auf Aceton" [On the effect of hydroxylamine on acetone]. Berichte der Deutschen Chemischen Gesellschaft (in German). 15: 1324–1326. doi:10.1002/cber.188201501285. From p. 1324: "Die Substanz, welche wir, wegen ihrer nahen Beziehungen zur Acetoximsäure, und da sie keine sauren Eigenschaften besitzt, vorläufig Acetoxim nennen wollen, …" (The substance, which we – on account of its close relations to acetoximic acid, and since it possesses no acid properties – will, for the present, name "acetoxime," … )
Acetoneoxime (acetoxime) is the organic compound with the formula (CH3)2CNOH. It is the simplest example of a ketoxime. It is a white crystalline solid...
In organic chemistry, an oxime is an organic compound belonging to the imines, with the general formula RR’C=N−OH, where R is an organic side-chain and...
oxime + acetone ⇌ {\displaystyle \rightleftharpoons } pyruvate + acetoneoxime Thus, the two substrates of this enzyme are pyruvate oxime and acetone...
The molecular formula C3H7NO may refer to: Acetoneoxime (acetoxime) 1-Amino-2-propanone Dimethylformamide Isoxazolidine Methylacetamide Oxazolidine Propionamide...
Acetone imine, or 2-propanimine is an organic compound and an imine with the chemical formula (CH3)2CNH. It is a volatile and flammable liquid at room...
accounting for solvent molecules and substituents. The rearrangement of acetoneoxime in the Beckmann solution involved three acetic acid molecules and one...
example, it is obtained by O-methylation of acetoneoxime followed by hydrolysis of the O-methylated oxime: (CH3)2CNOCH3 + H2O → (CH3)2CO + H2NOCH3 The...
(which contains a carbon–oxygen double bond C=O). The simplest ketone is acetone (where R and R' is methyl), with the formula (CH3)2CO. Many ketones are...
enone), i.e. CID:53982926 (7). (2-chloroethyl)dimethylamine (CDMA) & acetoneoxime are reacted together to give dimethylaminoacetoxime (DMA acetoxime)...
cyclohexanone supply is converted to cyclohexanone oxime. In the presence of sulfuric acid catalyst, the oxime rearranges to caprolactam, a precursor to nylon...
reagent, and reduction of the oxime gives CID:154108204 (6). A reductive amination of the primary amino group with acetone then completed the synthesis...
Galli, C. (2009). "Nitroxyl radicals". Chemistry of Hydroxylamines, Oximes and Hydroxamic Acids. Vol. 2. John Wiley & Sons. pp. 705–750. ISBN 978-0-470-51261-6...
made into film at Pottsville. In addition to internal use, AdvanSix sells acetone, phenol, and alpha-methylstyrene from the cumene process. They sell cyclohexanol...
also prepared by transcyanohydrin reactions starting, for example, with acetone cyanohydrin as a source of HCN. Nitriles can be prepared by the dehydration...
can be deprotonated. For example, the acidity of the methyl groups in acetone ((CH3)2CO) is about 1020 times more acidic than methane. The resulting...
Methyl ethyl ketone peroxide, benzoyl peroxide and to a smaller degree acetone peroxide are used as initiators for radical polymerization of some thermosets...
within a carbonyl compound decreases. The pKa values of acetaldehyde and acetone are 16.7 and 19 respectively, Infrared spectroscopy: the C=O double bond...
laboratory by treating sodium chloroacetate with sodium nitrite. Oxidation of oximes or primary amines. Reduction of β-nitro alcohols or nitroalkenes. By decarboxylation...
pyridine, acetone or t-BuOH. KMnO4 reacts with many functional groups, such as secondary alcohols, 1,2-diols, aldehydes, alkenes, oximes, sulfides and...
laboratory it can be prepared by the dehydration of benzamide or benzaldehyde oxime or by the Rosenmund–von Braun reaction using cuprous cyanide or NaCN/DMSO...
commonly used to clean circuit boards and in some nail varnish removers (acetone is also used). Coffee beans and tea leaves are decaffeinated with this...
sometimes called a formal or the methylenedioxy group. The acetal formed from acetone is sometimes called an acetonide. Used in a more general sense, the term...
Solubility in water 0.08 mg/L Solubility in other solvents DMSO: 12 g/100 g Acetone 0.615 g/100 g Methanol: 0.09 g/100 g Pharmacology ATCvet code QP53BC02...
gives cyclohexanone, which is converted on a large scale in industry to the oxime, a precursor to caprolactam. As a laboratory exercise, this oxidation can...
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