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Zirconium iodate information


Zirconium iodate
Identifiers
CAS Number
  • anhydrous: 22446-84-0 checkY
  • trihydrate: 19665-10-2 checkY
3D model (JSmol)
  • anhydrous: Interactive image
  • trihydrate: Interactive image
InChI
  • InChI=1S/4HIO3.Zr/c4*2-1(3)4;/h4*(H,2,3,4);/q;;;;+4/p-4
    Key: HONKFXPQYSOIMS-UHFFFAOYSA-J
SMILES
  • anhydrous: [O-]I(=O)=O.[O-]I(=O)=O.[O-]I(=O)=O.[O-]I(=O)=O.[Zr+4]
  • trihydrate: [O-]I(=O)=O.[O-]I(=O)=O.[O-]I(=O)=O.[O-]I(=O)=O.[Zr+4].O.O.O
Properties
Chemical formula
I4O12Zr
Molar mass 790.830 g·mol−1
Appearance white solid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Zirconium iodate is an inorganic compound with the chemical formula Zr(IO3)4. It can be prepared by reacting sodium iodate and zirconium sulfate tetrahydrate in an aqueous solution. The resulting precipitate is dried and refluxed in concentrated nitric acid.[1] Zirconium iodate trihydrate can be obtained by reacting hydrated zirconium oxide and iodine pentoxide (1.4~3.3% concentration) in water.[2] Its basic salt Zr(OH)n(IO3)4−n is known.[3]

  1. ^ A. C. Larson, D. T. Cromer (1961-02-10). "The crystal structure of Zr(IO3)4". Acta Crystallographica. 14 (2): 128–132. Bibcode:1961AcCry..14..128L. doi:10.1107/S0365110X6100053X. Archived from the original on 2018-06-04. Retrieved 2021-06-01.
  2. ^ "Passage de la nappe du Jotun aux arcs de Bergen". Bulletin de la Société Géologique de France. S7-XXII (3): 290–291. 1980. doi:10.2113/gssgfbull.s7-xxii.3.290. ISSN 0037-9409.
  3. ^ Gysler, A.; Lindigkeit, J.; Lütjering, G. (1979), "Correlation Between Microstructure and Fatigue Fracture", Strength of Metals and Alloys, Elsevier, pp. 1113–1118, doi:10.1016/b978-1-4832-8412-5.50185-5, ISBN 978-1-4832-8412-5, retrieved 2024-03-20

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Zirconium iodate

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Zirconium iodate is an inorganic compound with the chemical formula Zr(IO3)4. It can be prepared by reacting sodium iodate and zirconium sulfate tetrahydrate...

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Iodine

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'violet'. Iodine occurs in many oxidation states, including iodide (I−), iodate (IO− 3), and the various periodate anions. As the heaviest essential mineral...

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List of inorganic compounds

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ZrO2·nH2O Zirconium boride – ZrB2 Zirconium carbide – ZrC Zirconium(IV) chloride – ZrCl4 Zirconium(IV) oxide – ZrO2 Zirconium hydroxide – Zr(OH)4 Zirconium orthosilicate...

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Francium compounds

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additionally coprecipitate with many other caesium salts, including the iodate, the picrate, the tartrate (also rubidium tartrate), the chloroplatinate...

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Nuclear fission product

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than stable nuclei of the same mass as the fission product (e.g. stable zirconium-90 is 56% neutrons compared to unstable strontium-90 at 58%). The initial...

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Francium

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additionally coprecipitate with many other caesium salts, including the iodate, the picrate, the tartrate (also rubidium tartrate), the chloroplatinate...

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Iodine compounds

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iodide and iodate: Iodous acid and iodite are even less stable and exist only as a fleeting intermediate in the oxidation of iodide to iodate, if at all...

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Solubility table

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sulfate NH4HSO4 100 Ammonium hydrogen tartrate NH4HC4H4O6 1.88 2.7 Ammonium iodate NH4IO3 2.6 14.5 Ammonium iodide NH4I 155 163 172 182 191 200 209 219 229...

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Tranquillityite

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(Fe2+)8Ti3Zr2 Si3O24. It is mostly composed of iron, oxygen, silicon, zirconium and titanium with smaller fractions of yttrium and calcium. It is named...

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List of CAS numbers by chemical compound

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AgF2 silver difluoride 7783–95–1 AgI silver iodide 7783–96–2 AgIO3 silver iodate 7783–97–3 AgMnO4 silver permanganate 7783–98–4 AgN3 silver azide 13863–88–2...

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Astatine

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thought to be capable of forming cations in salts with oxyanions such as iodate or dichromate; this is based on the observation that, in acidic solutions...

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Oxidation state

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Knud; Wolff, Thomas (1981). "Laser flash photolysis and pulse radiolysis of iodate and periodate in aqueous solution. Properties of iodine(VI)". J. Chem. Soc...

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Glossary of chemical formulae

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iodide 7783-96-2 AgIO silver hypoiodite AgIO2 silver iodite AgIO3 silver iodate 7783-97-3 AgIO4 silver periodate AgMnO4 silver permanganate 7783-98-4 AgN3...

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Radium

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the most insoluble known sulfate), chromate (RaCrO4), carbonate (RaCO3), iodate (Ra(IO3)2), tetrafluoroberyllate (RaBeF4), and nitrate (Ra(NO3)2). With...

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Neptunium

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underway regarding alloys of neptunium with uranium, americium, plutonium, zirconium, and iron, so as to recycle long-lived waste isotopes such as neptunium-237...

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Americium

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compounds. For example, trivalent americium forms insoluble fluoride, oxalate, iodate, hydroxide, phosphate and other salts. Compounds of americium in oxidation...

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Actinide

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to uranium(IV) and thorium(IV). Fluorides, phosphates, hypophosphates, iodates and phenylarsonates of protactinium(IV) are insoluble in water and dilute...

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Halogen

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produced is by mixing sulfur dioxide with nitrate ores, which contain some iodates. Iodine is also extracted from natural gas fields. Even though astatine...

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List of aqueous ions by element

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TeO(OH)−3, TeO2(OH)3−2 tellurate 53 Iodine −1 +5 +7 iodide         I(OH)6+   iodate periodate 54 Xenon +8 XeO4−6 55 Caesium +1 Cs+ 56 Barium +2 Ba2+ Ba(OH)+...

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