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Zinc phosphate information


Zinc phosphate
Zinc phosphate
Names
IUPAC name
Zinc phosphate
Identifiers
CAS Number
  • 7779-90-0 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 22927 checkY
ECHA InfoCard 100.029.040 Edit this at Wikidata
PubChem CID
  • 24519
RTECS number
  • TD0590000
UNII
  • 1E2MCT2M62 checkY
CompTox Dashboard (EPA)
  • DTXSID3064807 Edit this at Wikidata
InChI
  • InChI=1S/2H3O4P.3Zn/c2*1-5(2,3)4;;;/h2*(H3,1,2,3,4);;;/q;;3*+2/p-6 checkY
    Key: LRXTYHSAJDENHV-UHFFFAOYSA-H checkY
  • InChI=1/2H3O4P.3Zn/c2*1-5(2,3)4;;;/h2*(H3,1,2,3,4);;;/q;;3*+2/p-6
    Key: LRXTYHSAJDENHV-CYFPFDDLAR
SMILES
  • [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])(=O)[O-].[O-]P([O-])([O-])=O
Properties
Chemical formula
H4O12P2Zn3
Molar mass 454.11 g·mol−1
Appearance white solid
Density 3.998 g/cm3
Melting point 900 °C (1,650 °F; 1,170 K)
Boiling point 158 °C (316 °F; 431 K)
Solubility in water
insoluble
Magnetic susceptibility (χ)
−141.0·10−6

cm3/mol

Refractive index (nD)
1.595
Structure
Crystal structure
monoclinic
Thermochemistry
Std enthalpy of
formation fH298)
− 2891.2 ± 3.3
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
0
0
Flash point Non-flammable
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Zinc phosphate is an inorganic compound with the formula Zn3(PO4)2. This white powder is widely used as a corrosion resistant coating on metal surfaces either as part of an electroplating process or applied as a primer pigment (see also red lead). It has largely displaced toxic materials based on lead or chromium, and by 2006 it had become the most commonly used corrosion inhibitor.[1][2] Zinc phosphate coats better on a crystalline structure than bare metal, so a seeding agent is often used as a pre-treatment. One common agent is sodium pyrophosphate.[3]

  1. ^ Kalendov´a, A.; Kalenda, P.; Vesel´y, D. (2006). "Comparison of the efficiency of inorganic nonmetal pigments with zinc powder in anticorrosion paints". Progress in Organic Coatings. 57. Elsevier: 1–10. doi:10.1016/j.porgcoat.2006.05.015.
  2. ^ Etzrodt, G. (2012). "Pigments, Inorganic 5. Anticorrosive Pigments". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.n20_n04. ISBN 978-3527306732.
  3. ^ Menke, Joseph T. "Zinc Phosphate Coatings on NonFerrous Substrates -- Part I". PFOnline. Retrieved 2006-08-07.

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Zinc phosphate

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dentistry. A major component of zinc phosphate cement produced by this reaction is hopeite, Zn3(PO4)2·4H2O. ZnO decomposes into zinc vapor and oxygen at around...

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phyllon 'leaf', and phosphate) is a rare mineral with the chemical formula Zn2Fe(PO4)2·4H2O, composed of hydrated zinc phosphate. It is highly prized...

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protein with magnesium, zinc, and citrate–collectively referred to as colloidal calcium phosphate (CCP). Various calcium phosphate minerals are used in the...

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Another, cheaper way of protecting rebars is coating them with zinc phosphate. Zinc phosphate slowly reacts with calcium cations and the hydroxyl anions present...

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Diammonium phosphate (DAP; IUPAC name diammonium hydrogen phosphate; chemical formula (NH4)2(HPO4) is one of a series of water-soluble ammonium phosphate salts...

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Xu, Ruren (July 2004). "(C6H17N3)[Zn4(PO4)2(HPO3)2]: a new layered zinc phosphate–phosphite templated by 1-(2-Aminoethyl) piperazine". Journal of Solid...

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and pollution; and, material substitution and replacement to reduce zinc phosphate in its production. In 2016 SCAAP was awarded with the Better Plants...

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intumescent systems. Zinc borate has synergistic effect with zinc phosphate or barium borate as a corrosion inhibitor pigment. Zinc borate acts as a broad-spectrum...

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Paint. A pigment with anticorrosive properties is zinc phosphate. Compounds derived from tannic acid or zinc salts of organonitrogens (e.g. Alcophor 827) can...

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products includes rust prevention and restoration paint, and are based on zinc phosphate as the active ingredient. Their products include interior and exterior...

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H+ ions gives the phosphate ion PO3−4. Removal of one or two protons gives dihydrogen phosphate ion H2PO−4, and the hydrogen phosphate ion HPO2−4, respectively...

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decomposition of zinc ammonium phosphate. 2 ZnNH4PO4 → Zn2P2O7 + 2 NH3 + H2O It can also be obtained from the reaction between sodium carbonate, zinc oxide, and...

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Fertilizer

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currently fed as a result of synthetic nitrogen fertilizer use. The use of phosphate fertilizers has also increased from 9 million tonnes per year in 1960...

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include: Zinc oxide cement—self setting and hardens when in contact with saliva. Example brands: Cavit, Coltosol. Zinc phosphate cement Zinc polycarboxylate...

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most changes; it was originally manganese-activated zinc phosphate, then a silver-activated cadmium-zinc sulfide, then the europium(III) activated phosphors...

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chlorate Zn(ClO 3) 2, zinc sulfate ZnSO 4 (known as "white vitriol"), zinc phosphate Zn 3(PO 4) 2 (used as primer pigment), zinc molybdate ZnMoO 4 (used...

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running surfaces such as crane rail. Hot-dip galvanizing Jewelling Phosphate conversion coating Quench polish quench F. Porter. Zinc Handbook. 1991. v t e...

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which was used widely in metal primer formulations, was zinc chromate, now replaced by zinc phosphate. A wash primer was formulated to replace the dangerous...

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Galvannealed

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