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Trithionate information


Trithionate
Names
IUPAC name
2,2,4,4-tetraoxido-1,5-dioxy-2,3,4-trisulfy-[5]catenate(2−)
Identifiers
CAS Number
  • 15579-17-6
3D model (JSmol)
  • Interactive image
3DMet
  • B01514
ChEBI
  • CHEBI:15987
ChemSpider
  • 477
Gmelin Reference
142337
KEGG
  • C01861
PubChem CID
  • 491
CompTox Dashboard (EPA)
  • DTXSID20165968 Edit this at Wikidata
InChI
  • InChI=1S/H2O6S3/c1-8(2,3)7-9(4,5)6/h(H,1,2,3)(H,4,5,6)/p-2
    Key: KRURGYOKPVLRHQ-UHFFFAOYSA-L
SMILES
  • [O-][S+2]([O-])([O-])S[S+2]([O-])([O-])[O-]
Properties
Chemical formula
O6S3−2
Molar mass 192.18 g·mol−1
Conjugate acid Trithionic acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Trithionate is an oxyanion of sulfur with the chemical formula S
3
O2−
6
. It is the conjugate base of trithionic acid.[1] Dilute sodium hydroxide hydrolyzes S
4
N
4
as follows, yielding sodium thiosulfate and sodium trithionate:

2 S
4
N
4
+ 6 NaOH + 9 H
2
O
Na
2
S
2
O
3
+ 2 Na
2
S
3
O
6
+ 8 NH
3

Certain sulfate-reducing bacteria have been known to use the compound in respiration.[2]

  1. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
  2. ^ Oltmann, L. F.; Stouthamer, A. H. (1975-10-27). "Reduction of tetrathionate, trithionate and thiosulphate, and oxidation of sulphide in proteus mirabilis". Archives of Microbiology. 105 (2): 135–142. Bibcode:1975ArMic.105..135O. doi:10.1007/BF00447128. ISSN 0302-8933. PMID 1106343. S2CID 1615795.

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Trithionate

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Trithionate is an oxyanion of sulfur with the chemical formula S 3O2− 6. It is the conjugate base of trithionic acid. Dilute sodium hydroxide hydrolyzes...

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Trithionate hydrolase

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In enzymology, a trithionate hydrolase (EC 3.12.1.1) is an enzyme that catalyzes the chemical reaction trithionate + H2O ⇌ {\displaystyle \rightleftharpoons...

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Hydrogensulfite reductase

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reductase (EC 1.8.99.3) is an enzyme that catalyzes the chemical reaction trithionate + acceptor + 2 H2O + OH- ⇌ {\displaystyle \rightleftharpoons } 3 bisulfite...

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Polythionates

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Many members of the polythionates have been characterized: dithionate, trithionate, tetrathionate, pentathionate, etc. These salts are often generated by...

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Sulfate

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Peroxydisulfate S2O2−7 Pyrosulfate S2O2−6 Dithionate S2O2−5 Metabisulfite S2O2−4 Dithionite S2O2−3 Thiosulfate S3O2−6 Trithionate S4O2−6 Tetrathionate...

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Tetrasulfur tetranitride

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(S4N4)n-μ-(−Cu−Cl−)n Dilute NaOH hydrolyzes S4N4 as follows, yielding thiosulfate and trithionate: 2 S4N4 + 6 OH− + 9 H2O → S2O2−3 + 2 S3O2−6 + 8 NH3 More concentrated...

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Sulfur oxoacid

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terminal central S atoms) Polythionates, O 3S(S x−2)SO2− 3. Example trithionate, tetrathionate, pentathionate, hexathionate, heptathionate, octathionate...

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List of enzymes

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Phosphonoacetate hydrolase EC 3.11.1.3: Phosphonopyruvate hydrolase EC 3.12.1.1: Trithionate hydrolase EC 3.13.1.1: UDP-sulfoquinovose synthase EC 3.13.1.3:...

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Dicarbonate

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Tricarbonate Peroxodicarbonate Oxalate Pyrosulfate Peroxydisulfate Dithionate Trithionate Tetrathionate Pyrophosphate Polyphosphate Plácido García; Helge Willner;...

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Sulfoxylic acid

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pentafluorobenzene. The reaction of sulfoxylic acid with sulfite yields trithionate (S 3O2− 6) and with thiosulfate yields pentathionate (S 5O2− 6). Salts...

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Annwoodia

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isolated Annwoodia aquaesulis grown on thiosulfate, tetrathionate or trithionate has high growth yields, which are broadly similar to those of Thermithiobacillus...

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Trithionic acid

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07E-016 Pa (8.05E-019 mm Hg) Acidity (pKa) -6.94 Conjugate base Hydrogen trithionate Refractive index (nD) 1.700 Pharmacology Pharmacokinetics: Biological...

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Thiosulfate dehydrogenase

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and Partial Purification of the 'Thiosulphate-oxidizing Enzyme' and 'Trithionate Hydrolyase' from Thiobacillus tepidarius". Microbiology. 134 (4): 877–885...

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Thermithiobacillus tepidarius

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reduced inorganic sulfur compounds (thiosulfate, polythionates from trithionate to octathionate pace pentathionate, sulfide) and elementary sulfur, but...

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