Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
Trimethylsilyl iodide (iodotrimethylsilane or TMSI) is an organosilicon compound with the chemical formula (CH3)3SiI. It is a colorless, volatile liquid at room temperature.
^ abcdMichael E. Jung, Michael J. Martinelli, George A. Olah, G. K. Surya Prakash, Jinbo Hu (October 15, 2005). "Iodotrimethylsilane". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.ri043.pub2. ISBN 978-0471936237. {{cite book}}: |journal= ignored (help)CS1 maint: multiple names: authors list (link)
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Trimethylsilyliodide (iodotrimethylsilane or TMSI) is an organosilicon compound with the chemical formula (CH3)3SiI. It is a colorless, volatile liquid...
Subscriber Identity, data sent between a mobile phone and its network Trimethylsilyliodide, a chemical compound This disambiguation page lists articles associated...
the parent acid. Hydrolysis can be effected with a solution of trimethylsilyliodide in hot acetonitrile followed by aqueous workup. Olah, George A.;...
pentachloride, phosphorus pentoxide, triethylamine, sodium hydroxide, trimethylsilyliodide among others. The Beckmann fragmentation is another reaction that...
temperature Ozone N-Bromosuccinimide (NBS) N-Iodosuccinimide (NIS) Trimethylsilyliodide (Me3SiI) in dichloromethane at ambient temperature (selectivity...
N-methyl-N-(trimethylsilyl)trifluoroacetamide (MSTFA). Treatment of this intermediate with trimethylsilyliodide gives the allylic iodide (3). Displacement...
conjugated vinyl iodide 28 was produced in an unexpected dehydrogenation. The ketone was converted into cyanohydrin 29 with trimethylsilyl cyanide, potassium...
removes a proton from the 8 position; treatment of that anion with trimethylsilyliodide leads to the silylated intermediate (4). A second round of LDA then...
of the desired products. To remedy this, the bromide was replaced with iodide through lithium-halogen exchange and quenching by using 1,2-diiodoethane...
are deoxygenated by strongly reducing silyl reagents such as N,N'-bis(trimethylsilyl)-4,4'-bipyridinylidene. Phosphorus occurs in nature as oxides, so to...
the trimethylsilyl enol ether 29, which was subsequently oxidized in a Rubottom oxidation using m-chloroperbezoic acid to give the trimethylsilyl protected...
Frankland prepared the first organozinc compound, diethylzinc, by heating ethyl iodide in the presence of zinc metal. This reaction produced a volatile colorless...
HC#C-C#CH + 2 KCl + 2 H2O}}} The bis(trimethylsilyl)-protected derivative may be prepared by the Hay coupling of (trimethylsilyl)acetylene: 2 Me 3 Si − C ≡ CH...
with methyl lithium to give trimethylsilyl lithium: (CH3)6Si2 + CH3Li → (CH3)3SiLi + (CH3)4Si Similarly, tris(trimethylsilyl)silyl lithium is derived from...
occurs at around 200 °C. Alternative methods are the hydrolysis of tris(trimethylsilyl)phosphine, or of metal phosphides such as aluminium phosphide, or calcium...
Dimethylcalcium is obtained by metathesis reaction of calcium bis(trimethylsilyl)amide and methyllithium in diethyl ether: C a [ N { S i ( C H 3 ) 3...
a related process, trimethylsilyl chloride, lithium and nitrogen react in the presence of a catalyst to give tris(trimethylsilyl)amine, which can be...
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