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Trifluoromethyl hypofluorite information


Trifluoromethyl hypofluorite
  Carbon, C
  Oxygen, O
  Fluorine, F
Names
Preferred IUPAC name
Trifluoromethyl hypofluorite
Identifiers
CAS Number
  • 373-91-1 ☒N
3D model (JSmol)
  • Interactive image
ChemSpider
  • 71322
ECHA InfoCard 100.006.157 Edit this at Wikidata
PubChem CID
  • 78989
CompTox Dashboard (EPA)
  • DTXSID4073174 Edit this at Wikidata
InChI
  • InChI=1S/CF4O/c2-1(3,4)6-5
    Key: SMBZJSVIKJMSFP-UHFFFAOYSA-N
  • InChI=1/CF4O/c2-1(3,4)6-5
    Key: SMBZJSVIKJMSFP-UHFFFAOYAC
SMILES
  • FC(F)(F)OF
Properties
Chemical formula
CF3OF
Molar mass 104.004012 g/mol
Appearance Colourless gas
Melting point −213 °C (−351.4 °F; 60.1 K)
Boiling point −95 °C (−139 °F; 178 K)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Toxic
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N (what is checkY☒N ?)
Infobox references

Trifluoromethyl hypofluorite is an organofluorine compound with the chemical formula CF3OF. It exists as a colorless gas at room temperature and is highly toxic.[1] It is a rare example of a hypofluorite (compound with an O−F bond). It can be seen as a similar chemical compound to methanol where every hydrogen atom is replaced by a fluorine atom. It is a trifluoromethyl ester of hypofluorous acid. It is prepared by the reaction of fluorine gas with carbon monoxide:

2 F2 + CO → CF3OF

The gas hydrolyzes only slowly at neutral pH.

  1. ^ Cady, G (1966). "Trifluoromethyl Hypofluorite". Inorganic Syntheses. Vol. 8. p. 168. doi:10.1002/9780470132395.ch43. ISBN 978-0-470-13167-1.

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Trifluoromethyl hypofluorite

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Trifluoromethyl hypofluorite is an organofluorine compound with the chemical formula CF3OF. It exists as a colorless gas at room temperature and is highly...

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Hypofluorous acid

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reagent. Hypofluorites are formally derivatives of OF−, which is the conjugate base of hypofluorous acid. One example is trifluoromethyl hypofluorite (CF3OF)...

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Radical fluorination

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perfluorination reactions. The O–F bond of hypofluorites is relatively weak. For trifluoromethyl hypofluorite (CF3OF), it has been estimated to be 43.5 kcal/mol...

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List of gases

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boiling point. Fluoroamine Trifluoromethyl trifluoroethyl trioxide CF3OOOCF2CF3 boils between 10 and 20° Bis-trifluoromethyl carbonate boils between −10...

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List of compounds with carbon number 1

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peroxynitrate 50311-48-3 CF4 carbon tetrafluoride 75-73-0 CF4O trifluoromethyl hypofluorite 373-91-1 CF5N pentafluoromethylamine 335-01-3 CF5N3 pentafluoroguanidine...

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Fluorine compounds

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base, the hypofluorite anion (OF− ), can form certain stable compounds, like lithium hypofluorite (LiOF) and trifluoromethyl hypofluorite (CF 3OF). Fluorous...

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