Miyaura borylation, also known as the Miyaura borylation reaction, is a named reaction in organic chemistry that allows for the generation of boronates from vinyl or aryl halides with the cross-coupling of bis(pinacolato)diboron in basic conditions with a catalyst such as PdCl2(dppf). The resulting borylated products can be used as coupling partners for the Suzuki reaction.[1]
^Ishiyama, Tatsuo; Murata, Miki; Miyaura, Norio (1 November 1995). "Palladium(0)-Catalyzed Cross-Coupling Reaction of Alkoxydiboron with Haloarenes: A Direct Procedure for Arylboronic Esters". The Journal of Organic Chemistry. 60 (23): 7508–7510. doi:10.1021/jo00128a024.
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Miyauraborylation, also known as the Miyauraborylation reaction, is a named reaction in organic chemistry that allows for the generation of boronates...
reaction is sometimes telescoped with the related Miyauraborylation; the combination is the Suzuki–Miyaura reaction. It is widely used to synthesize polyolefins...
Metal-catalyzed C–H borylation reactions are transition metal catalyzed organic reactions that produce an organoboron compound through functionalization...
acids to cyclic and acyclic enones. The Miyaura-Ishiyama borylation reaction is also known as the Miyauraborylation reaction. In this reaction, a catalytic...
triflates with diboronyl esters in a coupling reaction known as the Miyauraborylation reaction. An alternative to esters in this method is the use of diboronic...
step conversion of an aryl halide to a phenol (the first step is a Miyauraborylation). Sodium perborate monohydrate is quickly hydrolyzed into hydrogen...
in the Pd-catalyzed borylation of aryl and heteroaryl chlorides. 3-Sulfonate variants of sSPhos have been used in Suzuki-Miyaura couplings in aqueous...
synthesis of hindered tertiary boronic esters under in situ lithiation–borylation conditions". Chemical Communications. 52 (30): 5289–5292. doi:10.1039/C6CC00536E...
installation of adjacent tertiary benzylic stereocentres using lithiation–borylation–protodeboronation methodology. Application to the synthesis of bifluranol...
of benzoyl peroxide (2 mol %) as an initiator:. Alternatively similar borylation can be achieved using transition metal carbonyl complexes including dimanganese...
reagents. One common cyclic organoboron reagent is 9-BBN. Metal-catalyzed borylation reactions produce an organoboron compound from aliphatic or aromatic C-H...
Matzger, A. J.; Sanford, M. S. "Catalyst-Controlled Selectivity in the C–H Borylation of Methane and Ethane," Science 2016, 351, 1421–1424. Camasso, N. M.;...
addition reaction with 1,4-benzoquinone yielded a syn-cyclohexadiene moiety. Borylation of this material followed macrocyclization under Suzuki–Miyuara cross-coupling...
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