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Tetraethylammonium cyanide information


Tetraethylammonium cyanide
Identifiers
CAS Number
  • 13435-20-6 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 2283045
ECHA InfoCard 100.033.228 Edit this at Wikidata
EC Number
  • 236-566-2
PubChem CID
  • 3014735
CompTox Dashboard (EPA)
  • DTXSID70158668
InChI
  • InChI=1S/C8H20N.CN/c1-5-9(6-2,7-3)8-4;1-2/h5-8H2,1-4H3;/q+1;-1
    Key: PCZOZSATUTWXIC-UHFFFAOYSA-N
SMILES
  • CC[N+](CC)(CC)CC.[C-]#N
Properties
Chemical formula
C9H20N2
Molar mass 156.273 g·mol−1
Appearance white solid
Melting point 254 °C (489 °F; 527 K)
Hazards
GHS labelling:
Pictograms
GHS06: ToxicGHS09: Environmental hazard
Signal word
Danger
Hazard statements
H300, H310, H330, H410
Precautionary statements
P260, P262, P264, P270, P271, P273, P280, P284, P301+P310, P302+P350, P304+P340, P310, P320, P321, P322, P330, P361, P363, P391, P403+P233, P405, P501
Related compounds
Other anions
Tetraethylammonium chloride
Tetraethylammonium bromide
Tetraethylammonium iodide
Other cations
Tetramethylammonium cyanide
Ammonium cyanide
Guanidinium cyanide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Tetraethylammonium cyanide is the organic compound with the formula (C2H5)4NCN. It is a "quat salt" of cyanide. It is a colorless, deliquescent solid that is soluble in polar organic media. It is used in the synthesis of cyanometallates.[1]

Tetraethylammonium cyanide is prepared by ion exchange from tetraethylammonium bromide. The corresponding tetraphenylarsonium salt is prepared similarly.[2]

  1. ^ Entley, William R.; Treadway, Christopher R.; Wilson, Scott R.; Girolami, Gregory S. (1997). "The Hexacyanotitanate Ion: Synthesis and Crystal Structure of [NEt4]3[TiIII(CN)6]·4MeCN". Journal of the American Chemical Society. 119 (27): 6251–6258. doi:10.1021/ja962773m.
  2. ^ Dieck, R. L.; Peterson, E. J.; Galliart, A.; Brown, T. M.; Moeller, T. (1976). "Tetraethylammonium, Tetraphenylarsonium, and Ammonium Cyanates and Cyanides". Inorganic Syntheses. Vol. 16. pp. 131–137. doi:10.1002/9780470132470.ch36. ISBN 9780470132470.

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Tetraethylammonium cyanide

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Tetraethylammonium cyanide is the organic compound with the formula (C2H5)4NCN. It is a "quat salt" of cyanide. It is a colorless, deliquescent solid that...

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Tetraethylammonium

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Na+Br_{(aq)}- + Et4N+[ClO4]_{(s)}-}}} Other examples include tetraethylammonium cyanide (Et4NCN), and trichlorostannate (Et4NSnCl3). In some cases, salts...

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Cuprate

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Mahoui, A.; Lapasset, J.; Moret, J.; Saint Grégoire, P. (1996). "Tetraethylammonium Tetramethylammonium Tetrachlorocuprate(II), [(C2H5)4N][(CH3)4N][CuCl4]"...

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Onium ion

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R4N+ or NR+4 tetrafluoroammonium, NF+4 tetramethylammonium, (CH3)4N+ tetraethylammonium, (CH3CH2)4N+ tetrapropylammonium, (CH3(CH2)2)4N+ tetrabutylammonium...

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Tetraphenylarsonium chloride

Last Update:

; Brown, T. M.; Moeller, T. (1976). "Tetraethylammonium, Tetraphenylarsonium, and Ammonium Cyanates and Cyanides". Inorganic Syntheses. Vol. 16. pp. 131–137...

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Ethylene oxide

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results in a 2-substituted 1,3-dioxolane (yield: 70–85%, catalyst: tetraethylammonium bromide). Catalytic hydroformylation of ethylene oxide gives hydroxypropanal...

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Nickel compounds

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[W2Ni3(CO)16]2− [Mo<Ni4(CO)14]2− can form salts with bulky cations like tetraethylammonium. The brown [NiCo3(CO)11]− changes to red [Ni2Co4(CO)14]2−. With oxygen...

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List of compounds with carbon number 8

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2497-06-5 C8H20BrN tetraethylammonium bromide 71-91-0 C8H20Br4FeN tetraethylammonium tetrabromoferrate 21279-19-6 C8H20Cl4FeN tetraethylammonium tetrachloroferrate...

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GABA analogue

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Enhancers: D-Glucuronic acid HOTTooltip Hydroxyacid-oxoacid transhydrogenase Cyanide Phenanthroline ADHTooltip Alcohol dehydrogenase Cimetidine Ethanol Fomepizole...

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Tetrodotoxin

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oral LD50 of potassium cyanide for mice is 8,500 μg per kg, demonstrating that even orally, TTX is more poisonous than cyanide. TTX is even more dangerous...

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Difluorophosphate

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Rika (2012). "The Crystal to Plastic Crystal Phase Transition of Tetraethylammonium Difluorophosphate and Tetrafluoroborate". Chemistry Letters. 41 (4):...

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Pethidine

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produced in a two-step synthesis. The first step is reaction of benzyl cyanide and chlormethine in the presence of sodium amide to form a piperidine ring...

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Oxalate chloride

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subunits, Mo bound bidentate oxalate ligands and terminal or bridging cyanide ligands. Structural characterization of (Et4N)3[(C2O4)(CN)MoFe3S4Cl3] and...

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Lamotrigine

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1980. 2,3-Dichlorobenzoyl chloride is treated with cuprous cyanide to form an acyl cyanide. This is then reacted with the nitrate salt of aminoguanidine...

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