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Sulfur diimide information


Sulfur diimide
Names
IUPAC name
diimino-λ4-sulfane
Other names
4-Diazathia-1,2-diene
Identifiers
3D model (JSmol)
  • Interactive image
ChemSpider
  • 298618
PubChem CID
  • 336934
InChI
  • InChI=1S/H2N2S/c1-3-2/h1-2H
    Key: HQFYRKYAKZRZCJ-UHFFFAOYSA-N
SMILES
  • N=S=N
Properties
Chemical formula
H2N2S
Molar mass 62.09 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Sulfur diimides are chemical compounds of the formula S(NR)2. Structurally, they are the diimine of sulfur dioxide. The parent member, S(NH)2, is of only theoretical interest. Other derivatives where R is an organic group are stable and useful reagents.

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Sulfur diimide

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Sulfur diimides are chemical compounds of the formula S(NR)2. Structurally, they are the diimine of sulfur dioxide. The parent member, S(NH)2, is of only...

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Sulfur dichloride

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nitrides related to S4N4. Treatment of SCl2 with primary amines gives sulfur diimides. One example is di-t-butylsulfurdiimide. SCl2 hydrolyzes with release...

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Carbodiimide

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developed for the chemical probing of RNA structure in biochemistry. Sulfur diimide - the sulfur analogue Nomenclature of Organic Chemistry: IUPAC Recommendations...

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Inorganic imide

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nitrogen atom to other atoms, respectively (as in heptasulfur imide S7NH, sulfur diimide S(=NH)2 and nitroxyl O=NH). Organic imides have the functional groups...

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Heterocumulene

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element, but may have other parts to them. This class includes ketene, sulfur diimide, sulfine, and dicyclohexylcarbodiimide. Some heterocumulenes can act...

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Sulfinylamine

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formally speaking, derivatives of HN=S=O, i.e. analogues of sulfur dioxide and of sulfur diimide. A common example is N-sulfinylaniline. Sulfinyl amines are...

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Hydrazide

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fragmentation. 2,4,6-Triisopropylbenzenesulfonylhydrazide is a useful source of diimide. Acylhydrazines are derivatives of carboxylic acids, although they are...

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Cyanamide

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The N≡C–NH2 form dominates, but in a few reactions (e.g. silylation) the diimide form appears to be important. Cyanamide dimerizes to give 2-cyanoguanidine...

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Functional group

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such as in the case of amides. Compounds that contain sulfur exhibit unique chemistry due to sulfur's ability to form more bonds than oxygen, its lighter...

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Dithiocarbamate

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give a dithiocarbamic acid: RNH2 + CS2 → R(H)NCS2H In the presence of diimides or pyridine, these acids convert to isothiocyanates: R(H)NCS2H + C(=NR')2...

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Azo compound

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alkyl groups). IUPAC defines azo compounds as: "Derivatives of diazene (diimide), HN=NH, wherein both hydrogens are substituted by hydrocarbyl groups,...

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Hydrogen bond

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weaker hydrogen bonds, hydrogen atoms tend to bond to elements such as sulfur (S) or chlorine (Cl); even carbon (C) can serve as a donor, particularly...

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Hydrazine

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metribuzin, paclobutrazol, diclobutrazole, propiconazole, hydrazine sulfate, diimide, triadimefon, and dibenzoylhydrazine. Hydrazine compounds can be effective...

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Pnictogen

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the nitrogen or phosphorus atoms have the −2 oxidation state. Likewise, diimide, which has two nitrogen atoms double-bonded to each other, and its organic...

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Imidogen

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without resorting to a full spectrum synthesis with a 3D model atmosphere. Diimide (dimer) List of interstellar and circumstellar molecules IUPAC Red Book...

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